Cellulose based film structure and method for producing the same

Patent metadata

Field	Value
Publication number	US-11047091-B2
Application number	US-201716303172-A
Country	US
Kind code	B2
Filing date	Jul 4, 2017
Priority date	Jul 4, 2016
Publication date	Jun 29, 2021
Grant date	Jun 29, 2021

Abstract

According to an example aspect of the present invention, there is provided a cost-effective method of producing cellulose based films by introducing an intense water removal system to the process, and cellulose based films thereof having improved properties.

First claim

The invention claimed is:

1. A method for producing continuous cellulose nanofibril (CNF) or cellulose microfibril (CMF) film, wherein the method comprises the steps of:
casting a CNF or CMF material layer comprising a CNF or CMF material onto a metal belt, fabric or felt having total length of 10 to 150 m, wherein a bottom side of the CNF or CMF material layer is in contact with the metal belt, fabric or felt,
producing a strengthening layer on a top side of the CNF or CMF material layer before, after or simultaneously with the casting, wherein the top side is opposite the bottom side of the CNF or CMF material layer, wherein the strengthening layer comprises longer fibers than the CNF or CMF material and at least one filler material, and wherein the strengthening layer is thinner than the CNF or CMF layer,
removing at least 30% of the moisture of the CNF or CMF material, and
final drying and reeling of the formed film.

2. The method according to claim 1 , wherein the removing comprises one or more of the following steps (a) to (c):
(a) slurry temperature increment prior to CNF or CMF material contact with the metal belt, fabric or felt to reach a CNF or CMF slurry dryness of 5 to 30% and a temperature of 30 to 90° C.,
(b) water removal after the CNF or CMF material contact with the metal belt, fabric or felt to reach a CNF or CMF dryness of 20 to 50%, and
(c) applying heat to the metal belt from underneath the metal belt after the film contact with the metal belt in combination with applying impingement drying from above the metal belt after casting,

or any combination of (a), (b) and (c).

3. The method according to claim 2 , wherein a heating medium comprising steam is used in the removing.

4. The method according to claim 2 , wherein the impingement drying comprises at least a first blowing speed and a second blowing speed, wherein the first blowing speed is smaller than the second blowing speed.

5. The method according to claim 1 , further comprising producing the strengthening layer from fibers having length of 0.1 to 1 mm, and adjusting thickness of the strengthening layer to 5 to 30 μm.

6. The method according to claim 1 , wherein the CNF or CMF material layer is cast onto a metal belt, and wherein the surface of the metal belt has been roughened.

7. The method according to claim 6 , wherein the surface of the metal belt is roughened to a surface roughness value of Ra 1-3 μm, Rz 1-20 μm, before applying the coating layer comprising fluoropolymer particles, and polishing the applied coating to a surface roughness value of Ra 0.01-1 μm, Rz 0.1-8 μm.

8. The method according to claim 6 , wherein the adhesion between the film and the metal belt is adjusted to 0.5-5 N/m.

9. The method according to claim 6 , wherein the surface of the metal belt has been coated with a flexible material having controlled hydrophobicity and wearing resistant fillers.

10. The method according claim 1 , wherein the CNF or CMF film is produced at least with speed of 500 m/min.

11. A method for producing continuous cellulose nanofibril (CNF) or cellulose microfibril (CMF) film, wherein the method comprises:
casting a CNF or CMF material layer comprising a CNF or CMF material onto a metal belt, wherein the CNF or CMF material layer and the metal belt each comprise a top side and an opposed bottom side, and wherein the bottom side of the CNF or CMF material layer contacts the top side of metal belt,
removing moisture from the CNF or CMF material, wherein the removing comprises:
applying an amount of steam to the bottom side of the metal belt to transfer heat to the CNF or CMF material layer; and
drying the CNF or CMF material layer by directing an air flow to the top side of the CNF or CMF material layer.

12. The method of claim 11 , further comprising producing a strengthening layer on top of the CNF or CMF material layer before, after or simultaneously with the casting, wherein the strengthening layer comprises longer fibers than the CNF or CMF material and at least one filler material, and wherein the strengthening layer is thinner than the CNF or CMF layer.

Assignees

• Teknologian Tutkimuskeskus Vtt Oy

Inventors

• Pihko Riku
• Kunnari Vesa

Classifications

• D21H11/18 Primary

  Highly hydrated, swollen or fibrillatable fibres · CPC title

• B29C41/28

  by depositing flowable material on an endless belt · CPC title

• D21H27/10

  Packing paper (packaging materials of special type or form B65D65/38) · CPC title

• B32B2262/106

  Carbon fibres, e.g. graphite fibres · CPC title

• B32B5/26

  another layer {next to it} also being fibrous or filamentary {(relative arrangement of fibres or filaments of different layers B32B5/12)} · CPC title