Method of depositing nanoparticles on an array of nanowires

Patent metadata

Field	Value
Publication number	US-11047055-B2
Application number	US-201816025594-A
Country	US
Kind code	B2
Filing date	Jul 2, 2018
Priority date	Jul 7, 2017
Publication date	Jun 29, 2021
Grant date	Jun 29, 2021

Abstract

This disclosure provides systems, methods, and apparatus related to nanostructures. In one aspect, an array of nanowires is provided. The array of nanowires comprises a plurality of nanowires. End of nanowires of the plurality of nanowires are attached to a substrate. A liquid including a plurality of nanoparticles is deposited on the array of nanowires. The liquid is evaporated from the array of nanowires. Nanoparticles of the plurality of nanoparticles are deposited on the nanowires as a meniscus of the liquid recedes along lengths of the plurality of nanowires.

First claim

What is claimed is:

1. A method comprising:
(a) providing an array of nanowires, the array of nanowires comprising a plurality of nanowires, ends of nanowires of the plurality of nanowires being attached to a substrate;
(b) depositing a liquid on the array of nanowires in a drop-casting process, the liquid including a plurality of nanoparticles and including a plurality of first ligands, surfaces of nanoparticles of the plurality of nanoparticles having second ligands disposed thereon; and
(c) evaporating the liquid from the array of nanowires, the nanoparticles being deposited on the nanowires as a meniscus of the liquid recedes along lengths of the plurality of nanowires during evaporation of the liquid, a rate of the evaporating being controlled by a temperature at which the evaporating is performed and a vapor pressure of the liquid in a volume in which the evaporating is performed, the evaporating being performed at the temperature of about 10° C. to 50° C., the rate of the evaporating specified such that the nanoparticles are deposited on the nanowires with no aggregation of the nanoparticles.

2. The method of claim 1 , wherein lengths of the nanowires are about 1 micron to 50 microns.

3. The method of claim 1 , wherein an aspect ratio of the nanowires is about 2 to 50.

4. The method of claim 1 , wherein a distance between nanowires is at least about 100 nanometers.

5. The method of claim 1 , wherein a center-to-center spacing of the nanowires is about 500 nanometers to 3 microns.

6. The method of claim 1 , wherein the nanowires have a cross section selected from a group consisting of a square cross section, a triangular cross section, an oval cross section, and a circular cross section.

7. The method of claim 1 , wherein dimensions of cross sections of the nanowires are about 300 nanometers to 1.5 microns.

8. The method of claim 1 , wherein the nanowires comprise a semiconductor selected from a group consisting of silicon, gallium arsenide, and indium phosphide.

9. The method of claim 1 , wherein the nanoparticles comprise a metal.

10. The method of claim 1 , wherein the nanoparticles have a shape selected from a group consisting of a cube, a sphere, a rod, a pyramid, and an octahedron.

11. The method of claim 1 , wherein the nanoparticles have dimensions of about 2 nanometers to 30 nanometers.

12. The method of claim 1 , wherein the second ligands comprise hydrocarbon chains comprising about 10 to 18 carbon atoms.

13. The method of claim 1 , wherein the second ligands comprise functional groups selected from a group consisting of phosphine, amine, carboxylate, and thiol.

14. The method of claim 1 , wherein the liquid is selected from a group consisting of hexane, chloroform, and toluene.

15. The method of claim 1 , wherein a concentration of the plurality of nanoparticles in the liquid is about 0.1 milligrams per milliliter to 1 milligram per milliliter.

16. The method of claim 1 , wherein substantially all of the liquid is evaporated in operation (c) in about 15 seconds to 1 minute.

17. A method comprising:
(a) providing an array of nanowires, the array of nanowires comprising a plurality of nanowires, ends of nanowires of the plurality of nanowires being attached to a substrate, the nanowires and the substrate comprising silicon;
(b) depositing a liquid on the array of nanowires in a drop-casting process, the liquid including a plurality of nanoparticles and including a plurality of first ligands, surfaces of nanoparticles of the plurality of nanoparticles having second ligands disposed thereon, the liquid comprising hexane, the plurality of nanoparticles comprising Au 3 Cu; and
(c) evaporating the liquid from the array of nanowires, the nanoparticles being deposited on the nanowires as a meniscus of the liquid recedes along lengths of the plurality of nanowires during evaporation of the liquid, a rate of the evaporating being controlled by a temperature at which the evaporating is performed and a vapor pressure of the liquid in a volume in which the evaporating is performed, the evaporating being performed at the temperature of about 10° C. to 50° C., the rate of the evaporating specified such that the nanoparticles are deposited on the nanowires with no aggregation of the nanoparticles.

18. The method of claim 1 , wherein first ligands of the plurality of first ligands are the same composition as the second ligands.

19. The method of claim 1 , wherein first ligands of the plurality of first ligands are a different composition than the second ligands.

20. The method of claim 1 , wherein a concentration of the plurality of first ligands in the liquid is 0.01 milliliters to 0.02 milliliters per milliliter of the liquid.

Assignees

• Yang Peidong
• Kong Qiao
• Kim Dohyung
• Liu Chong
• Univ California

Inventors

• Yang Peidong
• Kong Qiao
• Kim Dohyung
• Liu Chong

Classifications

• C25B11/091 Primary

  consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds · CPC title

• C25B1/55 Primary

  Photoelectrolysis · CPC title

• B05D3/007

  After-treatment · CPC title