Stainless steel for polymer fuel cell separator and method for preparing same

Patent metadata

Field	Value
Publication number	US-11047029-B2
Application number	US-201615017902-A
Country	US
Kind code	B2
Filing date	Feb 8, 2016
Priority date	Dec 29, 2008
Publication date	Jun 29, 2021
Grant date	Jun 29, 2021

Abstract

There are provided a ferrite stainless steel for a polymer fuel cell separator having excellent corrosion resistance and interfacial contact resistance under an operating environment of a polymer fuel cell, and a preparation method of the stainless steel. A stainless steel includes C: 0.02 wt % or less, N: 0.02 wt % or less, Si: 0.4 wt % or less, Mn: 0.2 wt % or less, P: 0.04 wt % or less, S: 0.02 wt % or less, Cr: 25.0 to 32.0 wt %, Cu: 0 to 2.0 wt %, Ni: 0.8 wt % or less, Ti: 0.5 wt % or less, Nb: 0.5 wt % or less, waste Fe and inevitably contained elements. A preparation method of the stainless steel having a second passive film formed on a surface thereof includes forming a first passive film on the surface of the stainless steel by bright-annealing or annealing-pickling the stainless steel; removing the first passive film by pickling the stainless steel in a 10 to 20 wt % sulfuric acid solution at a temperature of 50 to 75° C. for a predetermined time; water-washing the stainless steel; and forming the second passive film by performing a passivation treatment on the stainless steel in the mixture of a 10 to 20 wt % nitric acid and a 1 to 10 wt % fluorine acid at a temperature of 40 to 60° C. for the predetermined time. Accordingly, it is possible to prepare a stainless steel having reduced elution resistance and excellent corrosion resistance and to produce a stainless steel for a polymer fuel cell separator, which has low interfacial contact resistance and excellent long-term performance even under a fuel cell operating condition of 60 to 150° C. and various surface roughness conditions.

First claim

The invention claimed is:

1. A stainless steel for a polymer fuel cell separator, comprising C: 0.02 wt % or less, N: 0.02 wt % or less, Si: 0.4 wt % or less, Mn: less than 0.2 wt %, P: 0.04 wt % or less, S: 0.02 wt % or less, Cr: 25.0 to 32.0 wt %, Cu: 0 to 2.0 wt %, Ni: 0.8 wt % or less, Ti: 0.5 wt % or less, Nb: 0.5 wt % or less, at least one element selected from the group consisting of V: 0.1 to 1.5 wt %, W: 0.1 to 0.41 wt %, La: 0.0005 to 1.0 wt %, Zr: 0.0005 to 1.0 wt %, and B: 0.0005 to 1.0 wt %, and waste Fe and inevitably contained elements,
wherein Mo is not added to the stainless steel,
wherein a passive film formed on a surface of the stainless steel is formed to have a thickness of 2 to 4.5 nm, and
wherein the contact resistance of the stainless steel is 10 mΩcm 2 or less under an operating environment of 60 to 150° C.

2. The stainless steel of claim 1 , wherein the Cr/Fe oxide ratio of a passive film formed on a surface of the stainless steel is 1.5 or more in a region of 1.5 nm or less.

3. The stainless steel of claim 1 , wherein the Cr(OH) 3 /Cr oxide distribution of a passive film formed on a surface of the stainless steel has a ratio of 0 to 0.7 in a region of 1 nm.

4. The stainless steel of claim 1 , wherein the V is 0.39 to 1.5 wt %.

5. A stainless steel for a polymer fuel cell, comprising C: 0.02 wt % or less, N: 0.02 wt % or less, Si: 0.4 wt % or less, Mn: less than 0.2 wt %, P: 0.04 wt % or less, S: 0.02 wt % or less, Cr: 25.0 to 32.0 wt %, Cu: 0 to 2.0 wt %, Ni: 0.8 wt % or less, Ti: 0.5 wt % or less, Nb: 0.5 wt % or less, at least one element selected from the group consisting of V: 0.1 to 1.5 wt %, W: 0.1 to 0.41 wt %, La: 0.0005 to 1.0 wt %, Zr: 0.0005 to 1.0 wt %, and B: 0.0005 to 1.0 wt %, and waste Fe and inevitably contained elements,
wherein Mo is not added to the stainless steel,
wherein a passive film is formed on a surface of the stainless steel,
wherein the Cr/Fe oxide ratio of the passive film is 1.5 or more in a region of 1.5 nm or less, and
wherein the contact resistance of the stainless steel is 10 mΩcm 2 or less under an operating environment of 60 to 150° C.

6. The stainless steel of claim 5 , wherein the passive film is formed to have a thickness of 2 to 4.5 nm.

7. The stainless steel of claim 5 , wherein the Cr(OH) 3 /Cr oxide distribution of the passive film has a ratio of 0 to 0.7 in a region of 1 nm.

8. The stainless steel of claim 5 , wherein the V is 0.39 to 1.5 wt %.

9. A stainless steel for a polymer fuel cell separator, comprising C: 0.02 wt % or less, N: 0.02 wt % or less, Si: 0.4 wt % or less, Mn: less than 0.2 wt %, P: 0.04 wt % or less, S: 0.02 wt % or less, Cr: 25.0 to 32.0 wt %, Cu: 0 to 2.0 wt %, Ni: 0.8 wt % or less, Ti: 0.5 wt % or less, Nb: 0.5 wt % or less, at least one element selected from the group consisting of V: 0.1 to 1.5 wt %, W: 0.1 to 0.41 wt %, La: 0.0005 to 1.0 wt %, Zr: 0.0005 to 1.0 wt %, and B: 0.0005 to 1.0 wt %, and waste Fe and inevitably contained elements,
wherein Mo is not added to the stainless steel,
wherein a passive film is formed on a surface of the stainless steel,
wherein the Cr(OH) 3 /Cr oxide distribution of the passive film has a ratio of 0 to 0.7 in a region of 1 nm, and
wherein the contact resistance of the stainless steel is 10 mΩcm 2 or less under an operating environment of 60 to 150° C.

10. The stainless steel of claim 9 , wherein the passive film is formed to have a thickness of 2 to 4.5 nm.

11. The stainless steel of claim 9 , wherein the Cr/Fe oxide ratio of the passive film is 1.5 or more in a region of 1.5 nm or less.

12. The stainless steel of claim 9 , wherein the V is 0.39 to 1.5 wt %.

Assignees

• Posco

Inventors

• Kim Jonghee
• Jo Kihoon
• Kim Younghwan
• Lee Jeonghe
• Lee Yunyong
• Kim Jinsuk
• Seok Jongheon

Classifications

• Y02E60/50

  Fuel cells · CPC title

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• C23C22/43

  containing also hexavalent chromium compounds · CPC title

• C23C22/30

  containing also trivalent chromium · CPC title

• C22C38/18 Primary

  containing chromium · CPC title