Process for removing volatile contaminants

Patent metadata

Field	Value
Publication number	US-11046896-B2
Application number	US-201816218690-A
Country	US
Kind code	B2
Filing date	Dec 13, 2018
Priority date	Dec 19, 2017
Publication date	Jun 29, 2021
Grant date	Jun 29, 2021

Abstract

A process for cleansing a liquid of volatile contaminants can be accomplished by cross flowing a liquid through a contactor vessel. As the liquid cross flows through the horizontal contactor vessel, a radial flow pattern is induced in the liquid and the liquid is contacted with a cleansing gas. As the liquid moves through the contactor vessel, contaminants enter the cleansing cross current gas percolating through the liquid. The cross current gas may then be collected and cleansed of the contaminants it collected. The cleaned cleansing gas may then be recycled back into the contactor vessel.

First claim

The invention claimed is:

1. A process for removing volatile contaminants from a liquid comprising:
cross flowing a liquid through a contactor vessel comprising:
a longitudinal axis;
a bottom region;
a cleansing gas distribution grid within the bottom region of the contactor vessel that is disposed within a central area on a cross section of the contactor vessel parallel to the longitudinal axis of the contactor vessel; and
a gas outlet within an upper region of the contactor vessel; and

contacting the cross flowing liquid with a cross current cleansing gas;
inducing a radial flow pattern in the cross flowing liquid;
allowing the cleansing gas to leave the contactor vessel after percolating upwards through the cross flowing liquid; and
drying the cleansing gas leaving the contactor vessel by passing the cleansing gas through a gas drying vessel, wherein the gas drying vessel comprises:
a bottom region;
a wet gas distribution grid within the bottom region;
an upper outlet;
a conduit operatively connecting the gas outlet of the contactor vessel to the wet gas distribution grid; and

a conduit operatively connecting the upper outlet to the cleansing gas distribution grid.

2. The process of claim 1 , wherein the contactor vessel further comprises a periphery, and the radial flow pattern induced in the liquid comprises movement of the liquid towards the periphery of the contactor vessel.

3. The process of claim 1 , wherein contacting the cross flowing liquid with the cross current cleansing gas comprises introducing the cleansing gas at the bottom region of the contactor vessel along at least a portion of the longitudinal axis of the contactor vessel.

4. The process of claim 3 , wherein the cleansing gas is introduced on a cross section of the contactor vessel parallel to the longitudinal axis of the contactor vessel.

5. The process of claim 3 , wherein the cleansing gas is introduced from a central area on a cross section of the contactor vessel parallel to the longitudinal axis of the contactor vessel.

6. The process of claim 1 , wherein the cleansing gas is introduced from approximately fifty percent of a cross section of the contactor vessel parallel to the longitudinal axis of the contactor vessel.

7. The process of claim 1 , wherein the cleansing gas is introduced in the form of a plurality of bubbles.

8. The process of claim 1 , wherein drying the cleansing gas leaving the contactor vessel comprises percolating the cleansing gas leaving the contactor vessel through a salt solution held in the gas drying vessel.

9. The process of claim 8 , further comprising:
removing a portion of the salt solution from the drying vessel; and
adding fresh salt to the salt solution held in the drying vessel.

10. A horizontal cross flow contactor comprising:
a horizontal contactor vessel comprising:
a first end;
a second end opposite the first end;
a longitudinal axis; and
a bottom region;
wherein the horizontal contactor vessel is configured to permit a cross flow of liquid;

a liquid inlet at the first end of the horizontal contactor vessel;
a liquid outlet at the second end of the horizontal contactor vessel;
a cleansing gas distribution grid within the bottom region of the horizontal contactor vessel that is disposed within a central area on a cross section of the horizontal contactor vessel parallel to the longitudinal axis of the horizontal contactor vessel;
a gas outlet within an upper region of the horizontal contactor vessel; and
a gas drying vessel, the gas drying vessel comprising:
a bottom region;
a wet gas distribution grid within the bottom region;
an upper outlet;
a conduit operatively connecting the gas outlet of the horizontal contactor vessel to the wet gas distribution grid; and
a conduit operatively connecting the upper outlet to the cleansing gas distribution grid.

11. The horizontal cross flow contactor of claim 10 , wherein the cleansing gas distribution grid comprises a plurality of bayonet spargers arranged parallel to a least a portion of the longitudinal axis of the horizontal contactor vessel, each bayonet sparger of the plurality comprising:
a longitudinal axis;
a non-porous body; and
a porous portion substantially parallel with the longitudinal axis of the bayonet sparger.

12. The horizontal cross flow contactor of claim 11 , wherein the porous portions of the plurality of bayonet spargers comprise pores of approximately 5-100 microns in size.

13. The horizontal cross flow contactor of claim 10 , further comprising a crinkle wire mesh screen at the gas outlet.

14. The horizontal cross flow contactor of claim 10 , wherein the central area is approximately fifty percent of the cross section of the horizontal contactor vessel parallel to the longitudinal axis.

15. The horizontal cross flow contractor of claim 10 , further comprising:
a coalescer operatively connected to the liquid inlet at the first end of the horizontal contactor vessel; and
a filter operatively connected to the coalescer.

16. The horizontal cross flow contactor of claim 10 , further comprising a crinkle wire mesh screen at the upper outlet of the drying vessel.

17. The horizontal cross flow contractor of claim 10 , wherein the gas drying vessel further comprises longitudinal axis, and wherein the wet gas distribution grid comprises a plurality of spargers arranged parallel to a least a portion of the longitudinal axis of the gas drying vessel.

18. The horizontal cross flow contactor of claim 10 , further comprising a tote tank operatively connected to the gas drying vessel.

Assignees

• Exxonmobil Res & Eng Co
• Exxonmobil Res & Engineering Company

Inventors

• Falkiner Robert J
• Uppal Ashok
• Kariparampil Luke J
• Brunet Vincent A
• Fomo Alain D

Classifications

• B01D1/14 Primary

  with heated gases or vapours {or liquids} in contact with the liquid · CPC title

• B01D2257/80

  Water · CPC title

• B01D2257/708

  Volatile organic compounds V.O.C.'s · CPC title

• B01D53/78

  with gas-liquid contact · CPC title

• C10G33/00 Primary

  Dewatering or demulsification of hydrocarbon oils (by distillation C10G7/04) · CPC title