Process and a system for hydrocarbon steam cracking

Patent metadata

Field	Value
Publication number	US-11046893-B2
Application number	US-201716339593-A
Country	US
Kind code	B2
Filing date	Oct 4, 2017
Priority date	Oct 7, 2016
Publication date	Jun 29, 2021
Grant date	Jun 29, 2021

Abstract

A process for steam cracking hydrocarbon feedstock in a steam cracking furnace, the process comprising superheating hydrocarbon feedstock using flue gas from a radiant section of the steam cracking furnace in hydrocarbon feedstock superheating means or the hydrocarbon feedstock superheater, superheating steam from the steam generator using the flue gas from the radiant section of the steam cracking furnace in second heat exchanging means or a second heat exchanger, steam cracking the super-heated hydrocarbon feedstock from the hydrocarbon feedstock superheating means or the hydrocarbon feedstock superheater into cracked gas in a fired tubular reactor, vaporizing the hydrocarbon feedstock, using hydrocarbon feedstock vaporizing means, wherein the hydrocarbon feedstock vaporizing means or the hydrocarbon feedstock vaporizer are heated with a heat transfer medium having a temperature less than or equal to 350° C. and feeding the vaporized hydrocarbon feedstock to the steam cracking furnace.

First claim

The invention claimed is:

1. A process for steam cracking hydrocarbon feedstock in a steam cracking furnace, the process comprising:
vaporizing the hydrocarbon feedstock, using hydrocarbon feedstock vaporizing means or the hydrocarbon feedstock vaporizer external of the steam cracking furnace, wherein the hydrocarbon feedstock vaporizing means are heated with a heat transfer medium having a temperature of less than or equal to 350° C.;
feeding the vaporized hydrocarbon feedstock to the hydrocarbon feedstock superheating means or the hydrocarbon feedstock superheater in the convection section of the steam cracking furnace;
superheating the vaporized hydrocarbon feedstock using flue gas from a radiant section of the steam cracking furnace in hydrocarbon feedstock superheating means or the hydrocarbon feedstock superheater in a convection section of the steam cracking furnace;
superheating steam from a steam generator using the flue gas from a radiant section of the steam cracking furnace in second heat exchanging means;
steam cracking the super-heated hydrocarbon feedstock into cracked gas in a fired tubular reactor in the radiant section of the steam cracking furnace;
wherein the vaporizing of the hydrocarbon feedstock comprises the steps of:
pressurizing the hydrocarbon feedstock using a hydrocarbon feedstock pump;
preheating the pressurized hydrocarbon feedstock in a first heat exchanger;
preheating boiled feed water for the steam generator using flue gas from the radiant section of the steam cracking furnace in a boiler feed water preheating means;
distilling the preheated hydrocarbon feedstock in a medium pressure distillation column connected to the first heat exchanger, wherein the medium pressure distillation column is operated at an absolute pressure in a range of 0.7 to 1.2 MPa;
wherein the vaporizing the hydrocarbon feedstock further comprises:
preheating fluid components of the hydrocarbon feedstock from the medium pressure distillation column through heat exchange in a second heat exchanger, and
distilling the hydrocarbon feedstock in a low pressure distillation column into at least one of a light distillate fraction and a middle distillate fraction and a heavy distillate fraction,
wherein the vaporizing the hydrocarbon feedstock comprises preheating in a multistage heat exchanging means; and
wherein flue gas enters the convection section at a temperature of 1173° C., wherein the heat is recovered by preheating the feedstock in a convection bank and preheating boiler feed water in convection bank and superheating the steam.

2. The process according to claim 1 , wherein the medium pressure distillation column is operated at an absolute pressure of 1.2 MPa, and wherein the temperature of the steam cracking furnace is 350° C.

3. The process according to claim 2 , wherein the pressure stripping steam has an absolute pressure of 2.0 MPa.

4. The process according to claim 3 , wherein the medium pressure stripping steam has a temperature of 350° C.

5. The process according to claim 4 , wherein the heat exchanger is heated using a heat transfer medium having a temperature of 350° C.

6. The process according to claim 1 , further comprising distilling the hydrocarbon stream in a low pressure distillation column using low pressure stripping steam having an absolute pressure of 0.1 MPa.

7. A process for steam cracking naphtha in a steam cracking furnace, the process consisting of the steps of: vaporizing the naphtha, using hydrocarbon feedstock vaporizing means or the hydrocarbon feedstock vaporizer external of the steam cracking furnace, wherein the hydrocarbon feedstock vaporizing means are heated with a heat transfer medium having a temperature less than or equal to 3500° C.; feeding the vaporized naphtha to the hydrocarbon feedstock superheating means or the hydrocarbon feedstock superheater in a convection section of the steam cracking furnace;
superheating the vaporized naphtha using flue gas from a radiant section of the steam cracking furnace in hydrocarbon feedstock superheating means or the hydrocarbon feedstock superheater in a convection section of the steam cracking furnace;
superheating steam from a steam generator using the flue gas from a radiant section of the steam cracking furnace in second heat exchanging means;
steam cracking the super-heated naphtha into cracked gas in a fired tubular reactor in the radiant section of the steam cracking furnace;
wherein the vaporizing of naphtha consists of:
pressurizing the naphtha using a hydrocarbon feedstock pump;
preheating the pressurized naphtha in a first heat exchanger; and
distilling the preheated naphtha in a medium pressure distillation column connected to the first heat exchanger, wherein the medium pressure distillation column is operated at an absolute pressure of 0.7 MPa;
distilling the distilled-preheated naphtha in the medium pressure distillation column using medium pressure stripping steam having an absolute pressure of 2.0 MPa;
preheating fluid components of the naphtha from the medium pressure distillation column through heat exchange in a second heat exchanger, and
distilling the fluid components in a low pressure distillation column into at least one of a light distillate fraction and a middle distillate fraction and a heavy distillate fraction;
distilling the fluid components in the low pressure distillation column using low pressure stripping steam having an absolute pressure of 0.1 MPa;
injecting steam in at least one steam injection inlets in hydrocarbon feedstock stream multistage heat exchanging means;
wherein the vaporizing the naphtha consists of preheating in the multistage heat exchanging means;
wherein the medium pressure stripping steam has a temperature of 180° C.; Wherein the heat exchanger is heated using a heat transfer medium having a temperature of 160° C.;
wherein the low pressure distillation column is operated at an absolute pressure of 0.1 MPa; wherein the preheating in the multistage heat exchanging means consists of:
preheating the naphtha in a first heat exchanger stage using low pressure steam;
preheating the naphtha in a second heat exchanger stage using medium pressure steam; and
preheating the naphtha in a third heat exchanger stage using high pressure steam.

8. The process according to claim 1 , wherein the feed is naphtha.

9. The process according to claim 2 , further comprising preheating boiled feed water for the steam generator using flue gas from the radiant section of the steam cracking furnace in a boiler feed water preheating means.

10. The process according to claim 3 , further comprising preheating boiled feed water for the steam generator using flue gas from the radiant section of the steam cracking furnace in a boiler feed water preheating means.

11. The process according to claim 4 , further comprising preheating boiled feed water for the steam generator using flue gas from the radiant section of the steam cracking furnace in a boiler feed water preheating means.

12. The process according to claim 5 , further comprising preheating boiled feed water for the steam generator using flue gas from the radiant section of the steam cracking furnace in a boiler feed water preheating means.

13. The process according to claim 1 , further comprising preheating boiled feed water for the steam generator using flue gas from the radiant section of the steam cracking furnace in a boiler feed water preheating means.

Assignees

• Sabic Global Technologies Bv

Inventors

• Van Willigenburg Joris

Classifications

• C10G7/00

  Distillation of hydrocarbon oils · CPC title

• C10G9/36 Primary

  with heated gases or vapours · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title

• C10G55/04

  including at least one thermal cracking step · CPC title

• B01J19/0013

  Controlling the temperature of the process · CPC title