Production method for poly(vinyl alcohol)
US-2020157289-A1 · May 21, 2020 · US
US11046880B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11046880-B2 |
| Application number | US-201916649504-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 4, 2019 |
| Priority date | Feb 22, 2018 |
| Publication date | Jun 29, 2021 |
| Grant date | Jun 29, 2021 |
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An additive for oil well cement contains a vinyl alcohol polymer and has good fluid loss reducing performance. The additive for oil well cement is a saponified product of a copolymer of a vinyl ester monomer and a multifunctional monomer, and has a degree of saponification of 70 to 95 mol % and a viscosity-average degree of polymerization of 1000 to 10000.
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The invention claimed is: 1. An additive for oil well cement, comprising a vinyl alcohol polymer, wherein the vinyl alcohol polymer is a saponified product of a copolymer of a vinyl ester monomer and a multifunctional monomer, the vinyl alcohol polymer has a degree of saponification of 70 to 95 mol % and a viscosity-average degree of polymerization of 1000 to 10000, and a structural unit derived from the multifunctional monomer in the vinyl alcohol polymer is 0.001 to 0.0230 mol % per 100 mol % of a structural unit derived from the vinyl ester monomer. 2. The additive for oil well cement according to claim 1 , wherein the multifunctional monomer includes a carbonyl group or an amide group. 3. The additive for oil well cement according to claim 1 , wherein the multifunctional monomer is triallyl isocyanurate. 4. The additive for oil well cement according to claim 1 , wherein a content of the vinyl alcohol polymer having a particle size of 75 μm or less is 30 mass % or less, and a content of the vinyl alcohol polymer having a particle size of 500 μm or more is 10 mass % or less. 5. A cement slurry comprising 0.01 to 30% bwoc of the additive for oil well cement according to claim 1 .
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