Coating composition for enhancing light transmittance and coating layer formed therefrom

Patent metadata

Field	Value
Publication number	US-11046867-B2
Application number	US-201615158038-A
Country	US
Kind code	B2
Filing date	May 18, 2016
Priority date	May 19, 2015
Publication date	Jun 29, 2021
Grant date	Jun 29, 2021

Abstract

The present invention relates to a coating composition, which includes:
(A) a polysiloxane resin, including a unit derived from a siloxane monomer, a siloxane oligomer, or a combination thereof; and (B) inorganic particles, including first SiO 2 particles with a particle size ranging from 15 nm to 100 nm, and second SiO 2 particles with a particle size ranging from 3 nm to <15 nm.

The present invention further relates to a coating layer for enhancing light transmittance that is formed by the coating composition. According to the present invention, by using at least two types of inorganic particles with specific particle sizes to form a geometric stack, the space of pores can be increased, and therefore, the porosity of the coating layer can be increased, thereby reducing the optical refractive index of the coating layer and achieving an effect of enhancing light transmittance.

First claim

What is claimed is:

1. A coating composition for enhancing light transmittance, consisting essentially of:
(A) a polysiloxane resin derived from a siloxane monomer, a siloxane oligomer, or a combination thereof; and
(B) inorganic solid particles, comprising first SiO 2 particles with a particle size ranging from 16 nm to 50 nm, second SiO 2 particles with a particle size ranging from 5 nm to 15 nm, and TiO 2 particles with a particle size of less than 70 nm, wherein the weight ratio of the first SiO 2 particles to the second SiO 2 particles is 20:1 to 5:1, and the ratio of the weight of the polysiloxane resin to the total weight of the inorganic particles is 20:1 to 2:1, and wherein the ratio of the total weight of the first SiO 2 particles and the second SiO 2 particles to the weight of the TiO 2 particles is 15:1 to 1:1.

2. The coating composition according to claim 1 , wherein the siloxane monomer has a general formula of (R 1 ) n Si(OR 2 ) 4-n , wherein R 1 is each independently H, phenyl, C 1-6 alkyl, or a univalent organic group with amino, epoxy, vinyl, an isocyanate group, mercapto or (methyl)acryloyloxy at the end; R 2 is each independently C 1-3 alkyl; and n is an integer from 0 to 3.

3. The coating composition according to claim 2 , wherein R 1 is each independently H, methyl, ethyl, vinyl, N-(β-aminoethyl)-γ-aminopropyl, aminopropyl, γ-glycidoxy propyl, β-(3,4-epoxycyclohexyl)ethyl, 3-(methylacryloyloxy)propyl or mercaptopropyl; and R 2 is each independently methyl or ethyl.

4. The coating composition according to claim 1 , wherein the siloxane monomer is selected from the group consisting of the following compounds:
trimethylmethoxysilane, trimethylethoxysilane, dimethyldimethoxysilane, dimethyldiethoxysilane, methyltrimethoxysilane, methyltriethoxysilane, methyltripropoxysilane, tetraethoxysilane, vinyltrimethoxysilane, vinyltriethoxysilane, γ-glycidoxypropyltrimethoxysilane, γ-glycidoxypropyltriethoxysilane, γ-glycidoxypropylmethyldimethoxysilane, γ-glycidoxypropylmethyldiethoxysilane, β-(3,4-epoxycyclohexyl)ethyltrimethoxysilane, 3-(methylacryloyloxy)propyltrimethoxysilane, N-(β-aminoethyl)-γ-aminopropylmethyldimethoxysilane, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane, γ-aminopropylmethyldiethoxysilane, γ-aminopropyltriethoxysilane, g-aminopropyltrimethoxysilane, and γ-mercaptopropyltrimethoxysilane.

5. The coating composition according to claim 1 , wherein the siloxane oligomer has a structure of formula (I):(R 5 3 SiO 1/2 ) x (R 6 2 SiO 2/2 ) y (R 7 SiO 3/2 ) z : (I)
wherein, R 5 , R 6 , and Rare each independently C 1-3 alkyl, phenyl, —OH or C 1-3 alkoxy; each R 5 may be identical or different; each R 6 may be identical or different; each R 7 may be identical or different; x>0, y>0, and z≥0.

6. The coating composition according to claim 5 , wherein the siloxane oligomer is a compound having a structure of formula (II) or formula (III):

wherein each R 3 may be identical or different, and is independently methyl or phenyl; each R 4 may be identical or different, and is independently H, methyl or ethyl; and m is an integer from 2 to 20.

7. The coating composition according to claim 1 , wherein the polysiloxane resin further comprises a unit derived from a fluorine-containing siloxane monomer.

8. The coating composition according to claim 7 , wherein the fluorine-containing siloxane monomer has a general formula of
CF 3 (CF 2 ) a (CH 2 ) b Si(X) c (Y) 3-c or CH 3 (CF 2 ) a (CH 2 ) b Si(X) c (Y) 3-c , wherein a is 0 to 14, b is 1 to 5, c is 0 to 2, X is halogen, and Y is C 1-3 alkoxy.

9. The coating composition according to claim 8 , wherein the fluorine-containing siloxane monomer is trifluoromethyl-methyl triethoxysilane, dodecafluoroheptyl-propyl-trimethoxysilane, 1H,1H,2H,2H-perfluorooctyltriethoxysilane, C 6 F 13 CH 2 CH(CH 3 )C 3 H 6 Si(OCH 3 ) 3 , dodecafluoroheptylpropyl methyl dimethoxysilane, heptadecafluorodecyltrimethoxysilane, heptadecafluorodecyltriisopropoxysilane, or a combination thereof.

10. A coating layer for enhancing light transmittance, consisting essentially of:
(A) a polysiloxane resin derived from a siloxane monomer, a siloxane oligomer, or a combination thereof; and
(B) inorganic solid particles, comprising first SiO 2 particles with a particle size ranging from 16 nm to 50 nm, second SiO 2 particles with a particle size ranging from 5 nm to 15 nm, and TiO 2 particles with a particle size of less than 70 nm, wherein the weight ratio of the first SiO 2 particles to the second SiO 2 particles is 20:1 to 5:1, and the ratio of the weight of the polysiloxane resin to the total weight of the inorganic particles is 20:1 to 2:1, and wherein the ratio of the total weight of the first SiO 2 particles and the second SiO 2 particles to the weight of the TiO 2 particles is 15:1 to 1:1.

11. The coating layer according to claim 10 having a thickness in the range from 50 nm to 500 nm.

12. The coating layer according to claim 11 having a thickness in the range from 120 nm to 180 nm.

13. The coating layer according to claim 11 , wherein the coating layer has a light transmittance that is enhanced as compared with a light transmittance of the coating layer comprising the first SiO 2 particles or the second SiO 2 particles only.

14. The coating composition according to claim 1 , wherein the coating composition can be heated to form a coating layer having a light transmittance that is enhanced as compared with a light transmittance of the coating layer comprising the first SiO 2 particles or the second SiO 2 particles only.

15. The coating composition according to claim 1 , wherein the polysiloxane resin consists of units selected from the group consisting of siloxane monomer, siloxane oligomer and a combination thereof.

16. The coating layer according to claim 10 , wherein the polysiloxane resin consists of units selected from the group consisting of siloxane monomer, siloxane oligomer and a combination thereof.

Assignees

• Eternal Mat Co Ltd

Inventors

• Lin Sheng Wei
• Yeh Mao Jung
• Wu Chien Chen

Classifications

• G02B1/11

  Anti-reflection coatings · CPC title

• C08K2201/011

  Nanostructured additives · CPC title

• G02B2207/107

  Porous materials, e.g. for reducing the refractive index · CPC title

• C08K2003/2241

  Titanium dioxide · CPC title

• C09D183/08 Primary

  containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen · CPC title