Membrane permeation treatment with adjustment of the temperature of the first retentate as a function of the CH4 concentration in the third and/or fourth permeate

Patent metadata

Field	Value
Publication number	US-11045760-B2
Application number	US-201916536299-A
Country	US
Kind code	B2
Filing date	Aug 8, 2019
Priority date	Aug 8, 2018
Publication date	Jun 29, 2021
Grant date	Jun 29, 2021

Abstract

A facility and method for membrane permeation treatment of a feed gas flow containing at least methane and carbon dioxide that includes a compressor, a pressure measurement device, at least one valve, and first, second, third, and fourth membrane separation units for separation of CO 2 from CH 4 to permeates enriched in CO 2 and retentates enriched in CH 4 , respectively. A temperature of the first retentate is adjusted at an inlet of the second membrane separation unit with at least one heat exchanger as a function of the measured CH 4 concentration in such a way so as to reduce the determined difference.

First claim

What is claimed is:

1. A method for membrane permeation treatment of a feed gas flow containing at least methane and carbon dioxide, comprising:
compressing the feed gas flow with a compressor;
receiving a flow of gas coming from the compressor at a first membrane separation unit that supplies a first permeate and a first retentate;
receiving the first retentate at a second membrane separation unit that supplies a second permeate and a second retentate;
receiving the first permeate at a third membrane separation unit that supplies a third permeate and a third retentate;
receiving the third retentate at a fourth membrane separation unit that supplies a fourth permeate and a fourth retentate;
with a gas analyzer, measuring a CH 4 concentration of the third permeate, a CH 4 concentration of the fourth permeate, or a CH 4 concentration of a flow of gas that is comprised of a combination of the third permeate and the fourth permeate;
comparing the measured CH 4 concentration with a setpoint CH 4 concentration and determining a difference therebetween; and
adjusting a temperature of the first retentate at an inlet of the second membrane separation unit with at least one heat exchanger as a function of the measured CH 4 concentration in such a way so as to reduce the determined difference, wherein each membrane separation unit comprises at least one membrane that is more permeable to carbon dioxide than to methane.

2. The method of claim 1 , wherein the adjusting of the temperature of the first retentate is carried out by heat exchange with a secondary flow having a temperature higher or lower than the temperature of the first retentate.

3. The method of claim 1 , wherein the adjusting step comprises increasing or decreasing the temperature of the first retentate.

4. The method of claim 1 , wherein the feed gas flow is biogas.

5. The method of claim 1 , wherein said steps of comparing, determining, and adjusting step are carried out automatically by a programmable controller.

Assignees

• Air Liquide

Inventors

• Chareyre Jean-Marc
• Grabie Veronique
• Zick Golo

Classifications

• Y02C20/40

  of CO2 · CPC title

• C10L2290/12

  Regeneration of a solvent, catalyst, adsorbent or any other component used to treat or prepare a fuel · CPC title

• B01D53/30

  Controlling by gas-analysis apparatus (regulating non electrical variables in general G05D) · CPC title

• C07C7/144

  using membranes, e.g. selective permeation · CPC title

• C10L2290/548

  Membrane- or permeation-treatment for separating fractions, components or impurities during preparation or upgrading of a fuel · CPC title