Weakly coloured sulfonic acid

Patent metadata

Field	Value
Publication number	US-11040940-B2
Application number	US-201816643076-A
Country	US
Kind code	B2
Filing date	Aug 30, 2018
Priority date	Sep 1, 2017
Publication date	Jun 22, 2021
Grant date	Jun 22, 2021

Abstract

The subject of the present invention is a weakly corrosive and weakly coloured sulfonic acid, with an APHA colour index of less than 20, comprising chlorides and nitrites in a chloride/sulfonic acid molar ratio of between 1 ppm and 200 ppm, and a nitrite/sulfonic acid molar ratio of between 200 ppm and 6000 ppm, limits inclusive.

First claim

The invention claimed is:

1. Sulfonic acid comprising:
a chloride/sulfonic acid molar ratio of between 1 ppm and 200 ppm, limits inclusive, and
a nitrite/sulfonic acid molar ratio of between 200 ppm and 6000 ppm, limits inclusive, and the APHA colour of which is less than 20.

2. The sulfonic acid according to claim 1 , having the formula R—SO 3 H, where R is selected from linear, branched or cyclic hydrocarbons having from 1 to 12 carbon atoms, where the hydrocarbons are unsubstituted or substituted with one or more radicals and/or atoms selected from halogen atoms, alkyl radicals containing from 1 to 6 carbon atoms, aryl or heteroaryl radicals having 6 or 10 ring members.

3. The sulfonic acid according to claim 1 , selected from methanesulfonic acid, ethanesulfonic acid, n-propanesulfonic acid, iso-propanesulfonic acid, n-butanesulfonic acid, iso-butanesulfonic acid, sec-butanesulfonic acid, tert-butanesulfonic acid, trifluoromethanesulfonic acid, para-toluenesulfonic acid, benzenesulfonic acid, naphthalenesulfonic acid, or mixtures thereof.

4. The sulfonic acid according to claim 1 , selected from the group consisting of methanesulfonic acid, ethanesulfonic acid, trifluoromethanesulfonic acid and para-toluenesulfonic acid.

5. Composition comprising at least one sulfonic acid according to claim 1 , and a solvent, where said solvent is water, an organic solvent a mixture of organic solvents, or water as a mixture with one or more organic solvents.

6. Composition comprising at least one sulfonic acid according to claim 1 , and one or more additives and/or fillers selected from viscosity or rheology modifiers, foaming agents, anti-foams, surfactants, disinfectants, biocides, stabilizers, oxidizing agents, enzymes, pigments, dyes, fire retardants, flame retardants, fragrances and aromas.

7. Composition comprising at least one sulfonic acid according to claim 1 , a solvent, and optionally one or more additive(s) and/or filler(s).

8. The sulfonic acid according to claim 1 , where the sulfonic acid is methanesulfonic acid.

9. The sulfonic acid according to claim 1 , where the chloride/sulfonic acid molar ratio is between 5 ppm and 200 ppm, limits inclusive, and the nitrite/sulfonic acid molar ratio is of between 400 ppm and 2000 ppm, limits inclusive, and the APHA colour of which is less than 15.

10. The sulfonic acid according to claim 1 , where the chloride/sulfonic acid molar ratio is between 10 ppm and 200 ppm, limits inclusive, and the nitrite/sulfonic acid molar ratio is between 400 ppm and 2000 ppm, limits inclusive, and the APHA colour of which is less than 10.

11. The sulfonic acid according to claim 1 , where the chloride/sulfonic acid molar ratio is between 10 ppm and 190 ppm, limits inclusive, and the nitrite/sulfonic ratio is between 500 ppm and 1900 ppm, limits inclusive, and the APHA colour is less than 5.

Assignees

• Arkema France

Inventors

• Laffitte Jean-Alex
• Monguillon Bernard

Classifications

• C23F11/181

  Nitrogen containing compounds · CPC title

• C07C303/42 Primary

  Separation; Purification; Stabilisation; Use of additives · CPC title

• C07C309/04 Primary

  containing only one sulfo group · CPC title

• C07C309/35

  Naphthalene sulfonic acids · CPC title

• C07C309/29

  of non-condensed six-membered aromatic rings · CPC title