Use of percarboxylic acids for scale prevention in treatment systems

Patent metadata

Field	Value
Publication number	US-11040902-B2
Application number	US-201514972727-A
Country	US
Kind code	B2
Filing date	Dec 17, 2015
Priority date	Dec 18, 2014
Publication date	Jun 22, 2021
Grant date	Jun 22, 2021

Abstract

Methods of employing peroxycarboxylic acid compositions for the prevention of scale formation and in some embodiments the removal of existing scale are disclosed. In particular, the scale inhibition properties of percarboxylic acids of varying chain lengths including C1-C22 provide effective scale inhibition and scale removal or destruction. Methods of employing peroxycarboxylic acid compositions for scale inhibition and/or removal are particularly well suited for treating fluids intended to flow through pipes, namely in the energy industry, water and paper industries, etc. The methods provide suitable scale inhibition replacements and/or additives to known scale inhibitors.

First claim

What is claimed is:

1. A method for reducing scale formation from a target comprising:
providing a composition comprising a C1-C22 peroxycarboxylic acid composition comprising from about 1 wt-% to about 99 wt-% of a C1-C22 peroxycarboxylic acid, from about 10 wt-% to about 90 wt-% of a C1-C22 carboxylic acid, from about 0.1 wt-% to about 50 wt-% of hydrogen peroxide, or comprising a C1-C22 peroxycarboxylic acid forming composition comprising an ester of a polyhydric alcohol and a C1-C22 carboxylic acid, and hydrogen peroxide, wherein the composition is free of enzymes, mineral acids, sulfoperoxycarboxylic acids, polycarboxylates, and buffering agents;
contacting a target with 100 ppm to 10,000 ppm of the composition, wherein the target is contacted at a pH below about 10.5, and wherein the contacting step is for a sufficient amount of time to reduce scale formation;
reacting the composition with a scale formation in and/or on the target; and
reducing the scale formation;
wherein the scale formation is a mineral scale formation comprising an iron sulfide, and/or an inorganic sulfate comprising an inorganic calcium component, an inorganic strontium component and/or an inorganic barium component, and/or a chloride comprising barium chloride, strontium chloride, and/or calcium chloride.

2. The method of claim 1 , wherein the target comprises a water source in need of treatment to form a treated water source, a water source and a surface in contact therewith in need of treatment to form a treated water source, a water source and at least a portion of a medium, a container, an equipment, a system or a facility for producing, holding, processing, packaging, storing, or transporting pulp in need of treatment to form a treated water source, or combinations thereof.

3. The method of claim 2 , wherein the water source in need of treatment comprises fresh water, pond water, sea water, produced water, tower water or a combination thereof, and is used in oil and/or gas drilling operation.

4. The method of claim 3 , wherein the water source is a blended water source that comprises fresh water or pond water and reuse water and comprises at least 1% of reuse or produced water.

5. The method of claim 4 , wherein the water source or the peroxycarboxylic acid composition further comprises a friction reducer, a corrosion inhibitor or a viscosity enhancer.

6. The method of claim 2 , wherein the treated water source comprises from about 2 ppm to about 1,000 ppm of the composition.

7. The method of claim 1 , wherein the C1-C22 peroxycarboxylic acid comprises peroxyformic acid, peroxyacetic acid, peroxyoctanoic acid, and mixtures thereof.

8. The method of claim 1 , wherein the peroxycarboxylic acid forming composition is provided in a two-part premix.

9. The method of claim 8 , wherein the premixes for the peroxycarboxylic acid forming composition are combined in or at the target in need of scale reduction.

10. The method of claim 1 , wherein the pH of the target treated with the composition is between about 3 and about 10.5.

11. The method of claim 1 , wherein the scale formation is a phosphate scale, carbonate scale, chloride scale, sulfate scale and/or combinations thereof found in water sources employed for oil and gas operations, water cooling towers, recreational waters, warewash applications, clean-in-place applications, industrial equipment and process streams, a medium, a container, an equipment, a system or a facility for producing, holding, processing, packaging, storing, or transporting pulp and/or combinations thereof.

12. The method of claim 1 , wherein the contacting step provides the composition to the target for at least about 1 minute and by means of a spray, a fog, or a foam, or by dipping all or part of the target in the composition.

13. The method of claim 1 , wherein the contacting step is conducted at a temperature ranging from about 0° C. to about 130° C.

14. The method of claim 1 , wherein the composition further comprises an additional functional ingredient comprising a catalyst, friction reducer, viscosity enhancer, defoaming agent, anti-redeposition agent, bleaching agent, solubility modifier, dispersant, metal protecting agent, corrosion inhibitor, additional biocide, additional scale inhibitor, sequestrant, chelating agent, peracid stabilizer, surfactant, antimicrobial agent, additional carboxylic acid, emulsion breaker, emulsion stabilizer, additional scale inhibitor, fragrance, dye, rheology modifier, thickener, hydrotrope, coupler, solvent, or a combination thereof.

15. The method of claim 1 , wherein the treated target has reduced scale in comparison to a target that is not treated with the composition and/or in comparison with a target treated with a conventional scale inhibitor, wherein the conventional scale inhibitor comprises phosphonates, phosphates, amines, quaternary amines, nitrilotriacetic acid (NTA) and/or ethylenediaminetetraacetic acid (EDTA), phosphonic acid, diacids, phosphate esters, or combinations of the same.

16. The method of claim 1 , wherein the microbial population in and/or on the target is reduced by at least one log 10 and wherein the treatment with the composition further removes iron sulfide from the target.

17. A method for dissolving and removing scale from a target comprising:
contacting a target with about 100 ppm to about 10,000 ppm of a composition comprising a C1 C22 peroxycarboxylic acid composition comprising from about 1 wt-% to about 99 wt-% of a C1-C22 peroxycarboxylic acid, from about 10 wt-% to about 90 wt-% of a C1-C22 carboxylic acid from about 0.1 wt-% to about 50 wt-% of hydrogen peroxide, or comprising a C1-C22 peroxycarboxylic acid forming composition comprising from about 50 wt-% to about 99 wt-% of an ester of a polyhydric alcohol and a C1-C22 carboxylic acid, and from about 0.1 wt-% to about 50 wt-% hydrogen peroxide, wherein the composition is free of enzymes, mineral acids, sulfoperoxycarboxylic acids, polycarboxylates, and buffering agents; wherein the target is contacted at a pH below about 10.5, and wherein the contacting step is for a sufficient amount of time to dissolve and remove a scale source from and/or in a target; and
reacting the composition with a scale source and/or on the target; and
removing the scale source;
wherein the scale source is a mineral scale source comprising an iron sulfide, and/or an inorganic sulfate comprising an inorganic calcium component, an inorganic strontium component and/or an inorganic barium component, and/or a chloride comprising barium chloride, strontium chloride, and/or calcium chloride.

18. The method of claim 17 , wherein the target comprises a water source in need of treatment to form a treated water source, a water source and a surface in contact therewith in need of treatment to form a treated water source, a water source and at least a portion of a medium, a container, an equipment, a system or a facility for producing, holding, processing, packaging, storing, or transporting pulp in need of treatment to form a treated water source, or combinations thereof.

19. The method of claim 18 , wherein the water source in need of treatment comprises fresh water, pond water, sea water, produced water, tower water or a combination thereof, wherein a combination of the water sources is a blended water source that comprises fresh water or pond water and reuse water.

20. The method of claim 19 , wherein the water source or the composition further comprises a friction reducer, a corrosion inhibitor or a viscosity enhancer.

Assignees

• Ecolab Usa Inc

Inventors

• Balasubramanian Ramakrishnan
• Epps Brian
• Li Junzhong
• Staub Richard
• Keasler Victor

Classifications

• C02F2209/06

  pH · CPC title

• C02F2103/365

  from petrochemical industry (e.g. refineries) · CPC title

• C02F2101/101

  Sulfur compounds · CPC title

• C02F2101/12

  Halogens or halogen-containing compounds · CPC title

• C02F2303/22

  Eliminating or preventing deposits, scale removal, scale prevention (C02F1/042, C02F1/4602, C02F5/00 take precedence) · CPC title