Method for making carbon nanotube composite structure

Patent metadata

Field	Value
Publication number	US-11040468-B2
Application number	US-202016886045-A
Country	US
Kind code	B2
Filing date	May 28, 2020
Priority date	May 22, 2017
Publication date	Jun 22, 2021
Grant date	Jun 22, 2021

Abstract

A method for making a carbon nanotube composite structure is related. A substrate having a first surface is provided. A carbon nanotube structure including a plurality of carbon nanotubes is placed on the first surface, wherein the plurality of carbon nanotubes is in direct contact with the first surface. A monomer solution is coated to the carbon nanotube structure, wherein the monomer solution is formed by dispersing a monomer into an organic solvent. The monomer is polymerized, and then the substrate is removed.

First claim

What is claimed is:

1. A method for making a carbon nanotube composite structure, the method comprising:
providing a substrate having a first surface, wherein the first surface is a nanoscale smooth surface;
placing a carbon nanotube structure comprising a plurality of carbon nanotubes on the first surface to form a preform structure, wherein the plurality of carbon nanotubes is in direct contact with the first surface;
locating two preform structures on a base, wherein the two preform structures are spaced from each other, the substrates of the two preform structures and the base form a mold having an opening, and the carbon nanotube structures of the two preform structures are opposite to each other and inside of the mold;
injecting a monomer solution into the mold from the opening, wherein the monomer solution is formed by dispersing monomers into an organic solvent;
polymerizing the monomer; and
removing the substrates of the two preform structures and the base.

2. The method of claim 1 , wherein a height difference between a highest position of the first surface and a lowest position of the first surface is greater than or equal to 0 nanometers and less than or equal to 30 nanometers.

3. The method of claim 1 , wherein a material of the substrate is sapphire, monocrystalline quartz, gallium nitride, gallium arsenide, silicon, graphene, or polymer.

4. The method of claim 1 , wherein the plurality of carbon nanotubes is joined end-to-end by van der Waals attractive force and substantially extends along the same direction.

5. The method of claim 4 , wherein the carbon nanotube structure comprises two carbon nanotube films, and an angle between the plurality of carbon nanotubes in the two carbon nanotube films is range from about 0 degree to about 90 degrees.

6. The method of claim 1 , wherein the plurality of carbon nanotubes is substantially parallel to the first surface.

7. The method of claim 1 , wherein a plurality of gaps is defined by the plurality of carbon nanotubes, and the monomer solution passes through the plurality of gaps and arrives at the first surface during the injecting the monomer solution.

8. The method of claim 1 , wherein the monomer is polymerized to form a polymer, the substrate is a silicon wafer, the monomer is poly(amic acid), and the polymer is polyimide.

9. The method of claim 1 , wherein the monomer is polymerized to form a polymer, and a portion of one of the plurality of carbon nanotubes is exposed from the polymer after the removing the substrate.

10. The method of claim 1 , wherein the monomer is polymerized to form a polymer, and a portion of each of the plurality of carbon nanotubes is exposed from the polymer after the removing the substrate.

11. The method of claim 1 , wherein the locating the two preform structures on the base further comprises fixing the two preform structures and the base together by sticking or mechanically fastening.

12. The method of claim 1 , wherein a material of the base is glass, silica, metal, or metal oxide.

13. The method of claim 1 , wherein the injecting the monomer solution into the mold from the opening further comprises injecting the monomer solution into the mold along an inner wall of the mold.

Assignees

• Univ Tsinghua
• Hon Hai Prec Ind Co Ltd

Inventors

• Ning Wen
• Wang Zhen-He
• Liu Peng
• Yang Shi-Yong
• Jiang Kai-Li
• Fan Shou-Shan

Classifications

• C08J5/005

  Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials · CPC title

• B29C41/003 Primary

  characterised by the choice of material · CPC title

• C08J2379/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title

• C08G73/1071

  Wholly aromatic polyimides containing oxygen in the form of ether bonds in the main chain · CPC title

• C08G73/1007

  from tetracarboxylic acids or derivatives and diamines · CPC title