Toner, image forming method, image forming apparatus, and process cartridge

Patent metadata

Field	Value
Publication number	US-11036152-B2
Application number	US-201816492986-A
Country	US
Kind code	B2
Filing date	Feb 21, 2018
Priority date	Mar 13, 2017
Publication date	Jun 15, 2021
Grant date	Jun 15, 2021

Abstract

Provided is a toner including a binder resin, a release agent, and a charge-controlling agent, wherein the toner includes toner particles having particle diameters of 3 micrometers or smaller, among the toner particles having particle diameters of 3 micrometers or smaller, a proportion of the toner particles having an average circularity of 0.70 or greater but 0.85 or less in all of the toner particles is 10% by number or greater but less than 20% by number and a proportion of the toner particles having an average circularity of less than 0.70 in all of the toner particles is 10% by number or less.

First claim

The invention claimed is:

1. A toner comprising:
a binder resin;
a release agent; and
a charge-controlling agent,
wherein the toner includes toner particles having particle diameters of 3 micrometers or smaller,
among the toner particles having particle diameters of 3 micrometers or smaller, a proportion of the toner particles having a circularity of 0.70 or greater but 0.85 or less in all of the toner particles is 10% by number or greater but less than 20% by number and a proportion of the toner particles having a circularity of less than 0.70 in all of the toner particles is 10% by number or less.

2. The toner according to claim 1 , wherein among the toner particles having particle diameters of 3 micrometers or smaller, the proportion of the toner particles having the circularity of less than 0.70 in all of the toner particles is 5% by number or less.

3. The toner according to claim 1 , wherein an amount of the charge-controlling agent relative to 100 parts by mass of the binder resin is 0.5 parts by mass or greater but 3.0 parts by mass or less, and a surface-exposed ratio of the charge-controlling agent relative to the binder resin is 0.02% or greater but 0.07% or less.

4. The toner according to claim 1 , wherein an amount of the release agent relative to 100 parts by mass of the binder resin is 1.0 parts by mass or greater but 6.0 parts by mass or less, and a surface-exposed ratio of the release agent relative to the binder resin is 0.02% or greater but 0.10% or less.

5. The toner according to claim 1 , wherein the toner includes a THF-insoluble component in an amount of 10% by mass through 40% by mass,
a molecular-weight distribution of a THF-soluble component of the toner obtained by gel permeation chromatography (GPC) has a main peak between 10,000 and 16,000, where a half-value width of the main peak is a molecular weight of 60,000 through 90,000, and
within the THF-soluble component of the toner, a component having a molecular weight of 2,000 or less as determined by GPC is from 15.0% by mass through 25.0% by mass and a component having a molecular weight of 100,000 or greater as determined by GPC is 10.0% by mass or less.

6. The toner according to claim 1 , wherein the charge-controlling agent is an azo iron dye.

7. An image forming method comprising:
forming an image by one-component development using the toner according to claim 1 .

8. An image forming apparatus comprising:
an electrostatic-latent-image bearer;
an electrostatic latent image-forming unit configured to form an electrostatic latent image on the electrostatic-latent-image bearer; and
a developing unit including a developer and configured to develop the electrostatic latent image with the developer to form a visible image,
wherein the developer includes the toner according to claim 1 .

9. A process cartridge comprising:
an electrostatic-latent-image bearer; and
a developing unit including a developer and configured to develop an electrostatic latent image formed on the electrostatic-latent-image bearer with the developer to form a visible image,
wherein the process cartridge is detachably mounted in a main body of an image forming apparatus, and
the developer includes the toner according to claim 1 .

10. The toner of claim 1 , wherein the toner particles having particle diameter of 3 micrometers or smaller each include a polyester resin.

11. The toner of claim 1 , wherein the charge-controlling agent comprises an azo iron dye of formula (1) and/or azo iron dye of formula (2)

12. The toner of claim 11 , wherein the azo iron dye further comprises an ammonium, alkyl ammonium, and/or an alkali metal cation.

13. The toner of claim 1 , wherein the binder comprises a polyester comprising, in a polymerized form:
ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, 1,4-bis(hydroxymethyl)cyclohexane, and/or bisphenol A; and
maleic acid, fumaric acid, phthalic acid, isophthalic acid, terephthalic acid, succinic acid, malonic acid, 1,2,4-benzenetricarboxylic acid, 1,2,5-benzenetricarboxylic acid, 1,2,4-cyclohexanetricarboxylic acid, 1,2,4-naphthalenetricarboxylic acid, 1,2,5-hexanetricarboxylic acid, 1,3-dicarboxyl-2-methylenecarboxypropane, and/or 1,2,7,8-octanetetracarboxylic acid.

14. The toner of claim 1 , wherein the binder comprises a polyester comprising, in a polymerized form:
ethylene glycol, diethylene glycol, triethylene glycol, and/or propylene glycol;
(i-b) 1,4-bis(hydroxymethyl)cyclohexane and/or bisphenol A:
(ii-a) maleic acid, fumaric acid, phthalic acid, isophthalic acid, terephthalic acid, succinic acid, and/or malonic acid; and
(ii-b) 1,2,4-benzenetricarboxylic acid, 1,2,5-benzenetricarboxylic acid, 1,2,4-cyclohexanetricarboxylic acid, 1,2,4-naphthalenetricarboxylic acid, 1,2,5-hexanetricarboxylic acid, 1,3-dicarboxyl-2-methylenecarboxypropane, and/or 1,2,7,8-octanetetracarboxylic acid.

15. The toner of claim 1 , wherein the binder comprises a polyester comprising, in a polymerized form:
ethylene glycol;
bisphenol A;
fumaric acid, terephthalic acid, and/or succinic acid; and
1,2,4-benzenetricarboxylic acid.

16. The toner of claim 1 , wherein the binder comprises only polyester.

17. The toner of claim 1 , wherein, among the toner particles having the particle diameters of 3 micrometers or smaller, the proportion of the toner particles having the circularity in the range of from 0.70 to 0.85 relative to the total number of the toner particles is in a range of from 10 to 15%.

18. The toner of claim 1 , wherein the surface-exposed ratio of the charge-controlling agent to the binder resin in a range of from 0.02 to 0.05%, and
wherein the surface-exposed ratio of the release agent to the binder resin is in a range of from 0.02 to 0.06%.

19. The toner of claim 18 , wherein an amount of the charge-controlling agent is in a range of from 0.5 to 2.0 parts by mass, and
wherein an amount of the release agent is in a range of from 1.0 to 6.0 parts by mass,
relative to 100 parts by mass of the binder resin.

20. The toner of claim 1 , comprising a first and a second polyester,
wherein the first and second polyesters are different.

Assignees

• Kobayashi Shohta
• Ogawa Satoshi
• Sekiguchi Yoshitaka
• Ishii Masayuki
• Kitada Naoko
• Ricoh Co Ltd

Inventors

• Kobayashi Shohta
• Ogawa Satoshi
• Sekiguchi Yoshitaka
• Ishii Masayuki
• Kitada Naoko

Classifications

• G03G9/0827

  characterised by their shape, e.g. degree of sphericity · CPC title

• G03G9/08795

  characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants · CPC title

• G03G9/0825

  characterised by their structure; characterised by non-homogenuous distribution of components (microcapsular toners G03G9/093) · CPC title

• G03G9/0819 Primary

  characterised by the dimensions of the particles · CPC title

• G03G9/0821

  characterised by physical parameters (magnetic parameters G03G9/083) · CPC title