Methods of generating and corrosion testing aqueous gas streams prepared from aqueous acid and salt precursor solutions

Patent metadata

Field	Value
Publication number	US-11035836-B2
Application number	US-201816050245-A
Country	US
Kind code	B2
Filing date	Jul 31, 2018
Priority date	Jul 31, 2018
Publication date	Jun 15, 2021
Grant date	Jun 15, 2021

Abstract

Embodiments of methods for producing and testing aqueous gas streams within a self-pressurized flow cell are disclosed. The aqueous gas streams comprise mixtures of aqueous salt precursor and aqueous acid precursor that are mixed in-line and introduced to the self-pressurized flow cell to produce aqueous gases. Once in the self-pressurized flow cell, the precursor mixture formed from the mixed aqueous salt precursor and the aqueous acid precursor may react with the sample. Both the sample and the reacted aqueous solution may be subjected to a variety of real-time tests, such electrochemical tests and in line characterization techniques. These embodiments allow for the concentrations of the aqueous salt precursor and the aqueous acid precursor to be accurately and precisely maintained while allowing for increased safety when handling and testing the various toxic aqueous gas streams produced.

First claim

What is claimed is:

1. A method for generating an aqueous gas solution comprising dissolved gas in an aqueous stream, the method comprising:
mixing an aqueous acid precursor solution and an aqueous salt precursor solution at an in-line mixing location to produce a liquid precursor mixture, wherein both the aqueous acid precursor solution and the aqueous salt precursor solution are fed under pressure through individual inlet pumps upstream of the in-line mixing location;
introducing the liquid precursor mixture under pressure through an inlet tube of a self-pressurized flow cell downstream of the in-line mixing location, wherein the inlet tube is surrounded by a sealing mechanism to maintain pressure within the self-pressurized flow cell; and
allowing the reaction of the aqueous acid precursor and the aqueous salt precursor to generate the aqueous gas solution and produce a pressure level that correlates to an amount of dissolved gas produced once in the self-pressurized flow cell;
wherein the dissolved gas comprises carbon dioxide, hydrogen sulfide, or a combination of both;
wherein the aqueous gas solution undergoes real-time testing within the self-pressurized flow cell; and
wherein the real-time testing comprises corrosion testing.

2. The method for generating an aqueous gas solution of claim 1 , wherein the real-time testing further comprises electrochemical measurements, pH measurements, ultraviolet-visible (UV-VIS) spectroscopy, weight loss or combinations thereof.

3. The method for generating an aqueous gas solution of claim 1 , wherein the aqueous gas solution is reacted with a sample, thereby producing a reacted aqueous gas stream.

4. The method for generating an aqueous gas solution of claim 3 , wherein the sample comprises conductive material.

5. The method for generating an aqueous gas solution of claim 4 , wherein the conductive material comprises steel, copper, aluminum, platinum, gold, silver, iron, brass, bronze, alloys, or combinations thereof.

6. The method for generating an aqueous gas solution of claim 3 , wherein the reacted aqueous gas stream undergoes testing comprising optical spectrometry or inductively coupled plasma (ICP) atomic emission spectroscopy or Fourier transform infrared spectroscopy, attenuated total reflection infrared spectroscopy, once the aqueous gas stream reacts with the sample and is transferred from the self-pressurized flow cell through an outlet tube.

7. The method for generating an aqueous gas solution of claim 6 , wherein the reacted aqueous gas stream is transferred from the self-pressurized flow cell through an outlet tube.

8. The method for generating an aqueous gas solution of claim 7 , wherein the reacted gas stream is further bubbled through a basic solution.

9. The method for generating an aqueous gas solution of claim 6 , wherein the outlet tube further comprises a pressure regulating device that prevents depressurization of the self-pressurized flow cell.

10. The method for generating an aqueous gas solution of claim 9 , wherein the pressure regulating device comprises an outlet pump, a back pressure regulator, or combinations thereof.

11. The method for generating an aqueous gas solution of claim 1 , wherein the aqueous acid precursor solution comprises sulfuric acid, hydrogen iodide, hydrogen bromide, perchloric acid, hydrogen chloride, chloric acid, nitric acid, or combinations thereof.

12. The method for generating an aqueous gas solution of claim 1 , wherein the aqueous acid precursor solution has a concentration of between 5 μM and 10 M.

13. The method for generating an aqueous gas solution of claim 1 , wherein the aqueous acid precursor solution has a concentration of between 100 μM and 100 mM.

14. The method for generating an aqueous gas solution of claim 1 , wherein the aqueous salt precursor solution comprises sodium sulfide, sodium carbonate, or a combination thereof.

15. The method of claim 14 , wherein the aqueous salt precursor solution further comprises sodium sulfate, magnesium chloride, calcium chloride, potassium chloride, and combinations thereof.

16. The method for generating an aqueous gas solution of claim 1 , wherein the aqueous salt precursor solution has a concentration of between 5 μM and 10 M.

17. The method for generating an aqueous gas solution of claim 1 , wherein the aqueous salt precursor solution has a concentration of between 100 μM and 100 mM.

18. The method for generating an aqueous gas solution of claim 1 , wherein the sealing mechanism comprises an injection port, an inlet port, an outlet port, a counter electrode port, a reference electrode port, or combinations thereof.

19. The method for generating an aqueous gas solution of claim 1 , wherein the sealing mechanism further comprises an inner portion and an outer portion.

20. The method for generating an aqueous gas stream of claim 19 , wherein the inner portion further comprises a PEEK rod.

21. The method for generating an aqueous gas solution of claim 19 , wherein the outer portion further comprises a stopper made from EPDM rubber, silicone rubber, neoprene rubber, pure gum rubber, natural rubber, butyl rubber, nitrile rubber, or any other suitable rubber or non-rubber materials.

Assignees

• Saudi Arabian Oil Co

Inventors

• Hayden Steven C
• Kucharski Timothy J
• Ostraat Michele L
• Grudt Rachael O
• Mullahoo James P

Classifications

• G01N2001/386

  Other diluting or mixing processes · CPC title

• G01N33/0004 Primary

  Gaseous mixtures, e.g. polluted air · CPC title

• G01N27/407

  for investigating or analysing gases {(G01N27/411 takes precedence)} · CPC title

• G01N21/17

  Systems in which incident light is modified in accordance with the properties of the material investigated (where the material investigated is optically excited causing a change in wavelength of the incident light G01N21/63) · CPC title

• G01N17/02 Primary

  Electrochemical measuring systems for weathering, corrosion or corrosion-protection measurement · CPC title