Dual in situ infrared spectroscopy for fuel cells

Patent metadata

Field	Value
Publication number	US-11035791-B2
Application number	US-201615779465-A
Country	US
Kind code	B2
Filing date	Nov 30, 2016
Priority date	Nov 30, 2015
Publication date	Jun 15, 2021
Grant date	Jun 15, 2021

Abstract

A rotating dual-electrode infrared cell for in situ electrochemical attenuated-total-reflection infrared spectroscopy (ATR-IRS) comprising:
a first and second prism; a first and second thin metal film, wherein the first thin metal film is coated on a surface of the first prism and the second thin metal film is coated on a surface of the second prism; an ion exchange membrane; and a first and second cell body, wherein each cell body comprises an inlet and outlet.

First claim

What is claimed is:

1. A rotating dual-electrode infrared cell for in situ electrochemical attenuated-total-reflection infrared spectroscopy (ATR-IRS) comprising:
a first and second prism;
a first and second metal film,
wherein the first metal film is coated on a surface of the first prism and the second metal film is coated on a surface of the second prism;
an ion exchange membrane; and
a first and second cell body,
wherein each cell body comprises an inlet and outlet, and the ion exchange membrane is located between the first and second cell bodies forming a first cell body/ion exchange membrane/second cell body structure, and the first cell body/ion exchange membrane/second cell body structure is located between the first prism and the second prism.

2. The rotating dual-electrode cell of claim 1 , wherein one of the first and second metal films is configured as an anode and another one of the first and second metal films is configured as a cathode.

3. The rotating dual-electrode cell of claim 1 , further comprising:
a first and second seal, wherein the first seal is located between the first prism and the first cell body, and wherein the second seal is located between the second prism and the second cell body.

4. The rotating dual-electrode cell of claim 1 , further comprising:
a light source configured to reflect light through the plurality of prisms.

5. The rotating dual-electrode cell of claim 1 , further comprising:
a plurality of fuel lines, wherein each of the fuel lines is connected to one of the inlet and outlet holes of the first and second cell bodies.

6. The rotating dual-electrode of claim 2 , wherein each of the first and second cell bodies respectively comprise a cavity.

7. The rotating dual-electrode of claim 6 , further comprising:
a first and second seal, wherein the first seal is located between the first prism and the first cell body, and wherein the second seal is located between the second prism and the second cell body;
a light source configured to reflect light through the plurality of prisms;
a plurality of fuel lines, wherein each of the fuel lines is connected to one of the inlet and outlet holes of the first and second cell bodies; and
a first electrical lead electrically coupled to the first metal film and a second electrical lead electrically coupled to the second metal film.

8. The rotating dual-electrode cell of claim 1 , further comprising:
a first electrical lead electrically coupled to the first metal film and a second electrical lead electrically coupled to the second metal film.

9. The rotating dual-electrode of claim 1 , wherein each of the first and second cell bodies respectively comprise a cavity.

10. The rotating dual-electrode of claim 1 , wherein the first and second metal film each has a thickness of 60 to 100 nm.

11. The rotating dual-electrode of claim 2 , wherein the first metal film is configured as an anode and comprises an Au supporting film and a PtRu catalyst, and the second metal film is configured as a cathode and comprises a Pt film.

12. A device comprising:
(a) a module comprising:
(i) a first prism having a first metal film disposed on an inner surface of the first prism and a second prism having a second metal film disposed on an inner surface of the second prism;
(ii) a fuel cell body located between the inner surface of the first prism and the inner surface of the second prism;

(b) a light source configured to direct a light beam to the first prism or to the second prism; and
(c) a detector configured to receive a light beam reflected from the first prism or from the second prism.

13. The device of claim 12 , wherein the first metal film is configured as an anode and the second metal film is configured as a cathode.

14. The device of claim 13 , wherein the first metal film comprises an Au supporting film and a PtRu catalyst, and the second metal film comprises a Pt film.

15. The device of claim 12 , wherein the fuel cell body comprises:
a first cell body located adjacent to the first metal film;
a second cell body located adjacent to the second metal film; and
an ion exchange membrane positioned between the first cell body and the second cell body.

16. The device of claim 15 , wherein the first cell body comprises a first cavity, and the second cell body comprises a second cavity.

17. A method comprising:
positioning a first prism in a light beam path and then positioning a second prism in the light beam path, wherein the first prism and the second prism are included in a device that comprises:
the first and second prism;
a first and second metal film,
wherein the first metal film is coated on a surface of the first prism and the second metal film is coated on a surface of the second prism;
an ion exchange membrane; and
a first and second cell body,
wherein each cell body comprises an inlet and outlet, and the ion exchange membrane is located between the first and second cell bodies forming a first cell body/ion exchange membrane/second cell body structure, and the first cell body/ion exchange membrane/second cell body structure is located between the first prism and the second prism.

18. The method of claim 17 , comprising initially positioning the first prism in the light beam path, and then rotating the device so that the second prism is positioned in the light beam path.

19. The method of claim 17 , wherein the light beam path is an IR light beam path.

20. The method of claim 19 , wherein one of the first and second metal films is configured as an anode and another one of the first and second metal films is configured as a cathode, and each of the first and second cell bodies respectively comprise a cavity, wherein each cavity holds an electrolyte and a fuel.

21. The method of claim 20 , wherein the method comprises directing the IR light beam path through the first prism and performing IR measurements on the first metal film, rotating the device, and directing the IR light beam path through the second prism and performing IR measurements on the first second film.

Assignees

• Univ Georgetown

Inventors

• Tong Yuye J
• Sorte Eric G
• Chen de-jun

Classifications

• G01N2201/0638

  Refractive parts · CPC title

• G01N21/552 Primary

  Attenuated total reflection · CPC title

• Y02E60/50

  Fuel cells · CPC title

• G01N21/75

  Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated (systems in which material is burnt in a flame or plasma G01N21/72, G01N21/73) · CPC title

• G01N21/3563

  for analysing solids; Preparation of samples therefor · CPC title