Oil-based drilling fluid compositions which include layered double hydroxides as rheology modifiers and amino amides as emulsifiers
US-10647903-B2 · May 12, 2020 · US
US11034880B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11034880-B2 |
| Application number | US-202016825489-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 20, 2020 |
| Priority date | Aug 15, 2017 |
| Publication date | Jun 15, 2021 |
| Grant date | Jun 15, 2021 |
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Oil-based drilling fluid compositions comprising an oil phase comprising a base oil, an aqueous phase comprising water, at least one emulsifier, and one or more additives. The at least one emulsifier comprises an amino amide comprising the formula R—CO—NH—R′—NH—R″—NH 2 , where R is a fatty acid alkyl and R′ and R″ are alkyl groups. The one or more additives are chosen from a wetting agent, a rheology modifier, a fluid-loss control additive, and a weighting additive. Methods of making the oil-based drilling fluid compositions and methods of drilling a subterranean well utilizing the oil-based drilling fluid compositions are also provided.
Opening claim text (preview).
The invention claimed is: 1. A method for drilling a subterranean well, the method comprising: providing an oil-based drilling fluid composition; and introducing the oil-based drilling fluid composition into a wellbore; wherein the oil-based drilling fluid composition comprises: an oil phase comprising a base oil; an aqueous phase comprising water; at least one emulsifier, in which the at least one emulsifier comprises an amino amide comprising the formula R—CO—NH—R′—NH—R″—NH 2 , where R is a fatty acid alkyl and R′ and R″ are alkyl groups; and one or more additives chosen from a wetting agent, a rheology modifier a fluid-loss control additive, and a weighting additive. 2. The method of claim 1 , where the method further comprises operating a drill in the wellbore. 3. The method of claim 1 , where the wellbore comprises a wellbore temperature greater than 300° F. 4. The method of claim 1 , where the wellbore comprises a wellbore pressure greater than 10,000 psi. 5. The method of claim 1 , where R is selected from C 15 H 31 , C 17 H 35 , C 21 H 43 or C 8 H 17 CHCHC 7 H 14 . 6. The method of claim 1 , where R′ is selected from C 2 H 4 , C 6 H 12 or C 10 H 20 . 7. The method of claim 1 , where R″ is selected from C 2 H 4 , C 6 H 12 or C 10 H 20 . 8. The method of claim 1 , where R is C 17 H 35 , R′ is C 2 H 4 , and R′ is C 2 H 4 . 9. The method of claim 1 , where the oil-based drilling fluid comprises from 0.05% by weight to 5.0% by weight emulsifier, based on the total weight of the oil-based drilling fluids. 10. The method of claim 1 , where the oil-based drilling fluid comprises from 0.1% by weight to 2.0% by weight rheology modifier, based on the total weight of the oil-based drilling fluids. 11. The method of claim 10 , where the rheology modifier comprises one or more of an organophilic clay, a hectorite clay, a dimeric fatty acid, a trimeric fatty acid, a polyamine, a sepiolite, and an attapulgite. 12. The method of claim 1 , where the oil-based drilling fluid comprises from 64% by weight to 85.3% by weight weighting additive, based on the total weight of the oil-based drilling fluids. 13. The method of claim 12 , where the weight additive comprises one or more of barite, calcite, aragonite, iron carbonate, zinc carbonate, manganese tetroxide, zinc oxide, zirconium oxide, hematite, ilmenite, and lead carbonate. 14. The method of claim 1 , where the viscosity at a shear rate of 10.22 s −1 measured at 50° C. is greater than 400 cP. 15. The method of claim 1 , where the viscosity at a shear rate of 170 s −1 measured at 50° C. is less than 125 cP.
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