Methods and compositions for use in oil and/or gas wells

Patent metadata

Field	Value
Publication number	US-11034879-B2
Application number	US-201916430138-A
Country	US
Kind code	B2
Filing date	Jun 3, 2019
Priority date	Mar 14, 2013
Publication date	Jun 15, 2021
Grant date	Jun 15, 2021

Abstract

Methods and compositions comprising an emulsion or a microemulsion for use in various aspects of the life cycle of an oil and/or gas well are provided. In some embodiments, the emulsion or the microemulsion comprises water, a solvent, and a surfactant, and optionally, one or more additives.

First claim

What is claimed is:

1. A composition for use in an oil and/or gas well having a wellbore, comprising a fluid and an emulsion or a microemulsion, wherein the emulsion or the microemulsion comprises:
water;
a solvent comprising a first type of solvent and a second type of solvent, wherein the first type of solvent is an unsubstituted cyclic or acyclic, branched or unbranched alkane having 6-12 carbon atoms and the second type of solvent is a cyclic or acyclic, branched or unbranched alkane having 9-12 carbon atoms and substituted with only an —OH group; and
a surfactant having a structure as in Formula II:

wherein each of R 7 , R 8 , R 9 , R 10 , and R 11 are the same or different and are selected from the group consisting of hydrogen, optionally substituted alkyl, and —CH═CHAr, provided at least one of R 7 , R 8 , R 9 , R 10 , and R 11 is —CH═CHAr;
Ar is an aryl group;
Y − is an anionic group;
X + is a cationic group;
n is 1-100; and
m is 1.

2. The composition of claim 1 , wherein the first type of solvent is selected from the group consisting of an isomer of methylheptane, an isomer of dimethylhexane, an isomer of ethylhexane, an isomer of trimethylpentane, an isomer of ethylmethylpentane, dimethylcyclohexane, ethylcyclohexane, cyclononane, methylcyclooctane, dimethylcycloheptane, ethylcycloheptane, trimethylcyclohexane, ethylmethylcyclohexane, and propylcyclohexane.

3. The composition of claim 1 , wherein the second type of solvent is selected from the group consisting of an isomer of nonanol, an isomer of decanol, an isomer of undecanol, and an isomer of dodecanol.

4. The composition of claim 3 , wherein the isomer of nonanol comprises 1-nonanol.

5. The composition of claim 3 , wherein the isomer of decanol comprises 1-decanol.

6. The composition as in claim 1 , wherein the emulsion or the microemulsion comprises a first type of surfactant and a second type of surfactant.

7. The composition as in claim 1 , wherein the surfactant is selected from the group consisting of a styrylphenol ethoxylate and a tristyrylphenol ethoxylate.

8. The composition as in claim 1 , wherein the emulsion or the microemulsion comprises between about 1 wt % and about 60 wt % water versus the total emulsion or microemulsion composition.

9. The composition as in claim 1 , wherein the emulsion or the microemulsion comprises between about 1 wt % and about 30 wt % solvent versus the total emulsion or microemulsion composition.

10. The composition as in claim 1 , wherein the emulsion or the microemulsion comprises between about 5 wt % and about 65 wt % surfactant versus the total emulsion or microemulsion composition.

11. The composition as in claim 1 , wherein the emulsion or the microemulsion is present in an amount between about 0.5 gallons per thousand and about 100 gallons per thousand of the fluid.

12. A composition for use in an oil and/or gas well having a wellbore, comprising a fluid and an emulsion or a microemulsion, wherein the emulsion or the microemulsion comprises:
water;
a solvent comprising a first type of solvent and a second type of solvent, wherein the first type of solvent is an unsubstituted cyclic or acyclic, branched or unbranched alkane having 6-12 carbon atoms and the second type of solvent is a cyclic or acyclic, branched or unbranched alkane having 8 carbon atoms and substituted with only an —OH group; and
a surfactant having a structure as in Formula II:

wherein each of R 7 , R 8 , R 9 , R 10 , and R 11 are the same or different and are selected from the group consisting of hydrogen, optionally substituted alkyl, and —CH═CHAr, provided at least one of R 7 , R 8 , R 9 , R 10 , and R 11 is —CH═CHAr;
Ar is an aryl group;
Y − is an anionic group;
X + is a cationic group;
n is 1-100; and
m is 1.

13. The composition of claim 12 wherein the first type of solvent is selected from the group consisting of an isomer of methylheptane, an isomer of dimethylhexane, an isomer of ethylhexane, an isomer of trimethylpentane, an isomer of ethylmethylpentane, dimethylcyclohexane, ethylcyclohexane, cyclononane, methylcyclooctane, dimethylcycloheptane, ethylcycloheptane, trimethylcyclohexane, ethylmethylcyclohexane, and propylcyclohexane.

14. The composition of claim 12 , wherein the second type of solvent is selected from the group consisting of 1-octanol and 2-ethyl-1-hexanol.

15. The composition as in claim 12 , wherein the emulsion or the microemulsion comprises a first type of surfactant and a second type of surfactant.

16. The composition as in claim 12 , wherein the surfactant is selected from the group consisting of a styrylphenol ethoxylate and a tristyrylphenol ethoxylate.

17. The composition as in claim 12 , wherein the emulsion or the microemulsion comprises between about 1 wt % and about 60 wt % water versus the total emulsion or microemulsion composition.

18. The composition as in claim 12 , wherein the emulsion or the microemulsion comprises between about 1 wt % and 30 wt % solvent versus the total emulsion or microemulsion composition.

19. The composition as in claim 12 , wherein the emulsion or the microemulsion comprises between about 5 wt % and 65 wt % surfactant versus the total emulsion or microemulsion composition.

20. The composition as in claim 12 , wherein the emulsion or the microemulsion is present in an amount between about 0.5 gallons per thousand and about 100 gallons per thousand of the fluid.

Assignees

• Flotek Chemistry Llc

Inventors

• Champagne Lakia M
• Fursdon-Welsh Angus
• Hill Randal M

Classifications

• C09K8/584

  characterised by the use of specific surfactants · CPC title

• C09K8/26

  Oil-in-water emulsions · CPC title

• C09K8/62

  Compositions for forming crevices or fractures · CPC title

• C09K8/602

  containing surfactants · CPC title

• C09K8/36 Primary

  Water-in-oil emulsions · CPC title