Weighted composition for treatment of a subterranean formation

Patent metadata

Field	Value
Publication number	US-11034873-B2
Application number	US-201515753506-A
Country	US
Kind code	B2
Filing date	Sep 17, 2015
Priority date	Sep 17, 2015
Publication date	Jun 15, 2021
Grant date	Jun 15, 2021

Abstract

Various embodiments disclosed relate to weighted compositions for treatment of a subterranean formation. In various embodiments, the present invention provides a method of treating a subterranean formation. The method can include placing in the subterranean formation a coated weighting agent. The coated weighting agent can include a weighting agent and an inorganic coating material on the weighting agent.

First claim

What is claimed is:

1. A method of treating a subterranean formation, the method comprising:
placing in the subterranean formation a weighted composition, wherein the weighted composition comprises a coated weighting agent, wherein the coated weighting agent comprises a weighting agent and an inorganic coating material on the weighting agent, wherein the inorganic coating material comprises barium sulfate,
wherein the coated weighting agent has a surface coverage of about 10% to about 40% of the weighting agent, and wherein the coated weighting agent has a specific gravity of 4 to 18.

2. The method of claim 1 , further comprising drilling into a production zone or reservoir in the subterranean formation using the weighted composition as a drill-in fluid.

3. The method of claim 1 , further comprising cleaning the coated weighting agent from a production zone or reservoir after drilling into the production zone or reservoir.

4. The method of claim 3 , wherein the cleaning comprises at least partially dissolving the coated weighting agent with an acidic solution, and/or, wherein the coated weighting agent has a greater surface roughness than the weighting agent, and, optionally, wherein the coated weighting agent has about 101% to about 100,000% of the surface area of the weighting agent, and, optionally, wherein the coated weighting agent has about 110% to about 10,000% of the surface area of the weighting agent.

5. The method of claim 4 , wherein the coated weighting agent is a homogeneous suspension in the weighted composition, and, optionally, wherein the coated weighting agent does not settle out of the suspension under static conditions, and, optionally, wherein the coated weighting agent settles out of the suspension under static conditions more slowly than a suspension of the weighting agent in a corresponding composition that is free of the coated weighting agent under static conditions, and, optionally, wherein the coated weighting agent has a particle size of at least about 0.1 μm.

6. The method of claim 1 , wherein the weighting agent is an acid-treated weighting agent.

7. The method of claim 6 , wherein the acid-treated weighting agent has greater surface area than a corresponding weighting agent not treated with acid, and, optionally, wherein the acid-treated weighting agent has a greater surface roughness than a surface roughness of a corresponding weighting agent not treated with acid, and, optionally, wherein the acid-treated weighting agent has greater concentration of inorganic coating material-seeding sites than the concentration of such seeding sites on a corresponding weighting agent not treated with acid.

8. The method of claim 1 , wherein the weighting agent is selected from the group consisting of allemontite, altaite, aluminum oxide, anglesite, tin oxide, antimony trioxide, awaruite, barium sulfate, bastnaesite, beryllium oxide, birnessite, bismite, bismuth oxycarbonates, bismuth oxychloride, bismuth trioxide, bismuth (III) oxide, bixbyite, bournonite, braunite, brucite, cadimum sulfide, calayerite, calcium oxide, calcium carbonate, cassiterite, cerium oxide, cerussite, chromium oxide, clinoclase, columbite, copper, copper oxide, corundum, crocoite, cuprite, dolomite, euxenite, fergusonite, franklinite, gahnite, geothite, greenockite, hausmmanite, hematite, hercynite, hessite, ilvaite, Jacobsite, magnesium oxide, manganite, manganosite, magnetite, manganese dioxide, manganese (IV) oxide, manganese oxide, manganese tetraoxide, manganese (II) oxide, manganese (III) oxide, microlite, minium, molybdenum (IV) oxide, molybdenum oxide, molybdenum trioxide, nickel oxide, pearceite, phosgenite, psilomelane, pyrochlore, pyrolusite, rutile, scandium oxide, siderite, smithsonite, spessartite, stillwellite, stolzite, strontium oxide, tantalite, tenorite, tephroite, thorianite, thorite, tin dioxide, tin (II) oxide, titanium dioxide, vanadium oxide, vanadium trioxide, vanadium (IV) oxide, vanadium (V) oxide, witherite, wulfenite, yttrium oxide, zincite, zircon, zirconium oxide, zirconium silicate, zinc oxide, and combinations thereof.

9. The method of claim 1 , wherein the inorganic coating material further comprises calcium carbonate, and wherein the inorganic coating material is about 1 wt % to about 50 wt % of the coated weighting agent.

10. The method of claim 1 , wherein the inorganic coating material is at least partially acid soluble at a pH of less than about 6.5.

11. The method of claim 1 , further comprising cleaning the coated weighting agent from the subterranean formation.

12. The method of claim 1 , further comprising dissolving the coated weighting agent with an acidic solution.

13. The method of claim 1 , further comprising combining the weighted composition with an aqueous or oil-based fluid.

14. The method of claim 1 , wherein the weighted composition further comprises a viscosifier, wherein the viscosifier is about 0.0001 wt % to about 10 wt % of the weighted composition.

15. The method of claim 1 , wherein the weighted composition further comprises a crosslinker, wherein the crosslinker is about 0.0001 wt % to about 5 wt % of the weighted composition.

16. The method of claim 1 , wherein the weighted composition further comprises a breaker, wherein the breaker is about 0.001 wt % to about 30 wt % of the weighted composition.

17. A method of treating a subterranean formation, the method comprising:
placing in the subterranean formation a weighted composition, wherein the weighted composition comprises a coated weighting agent, wherein the coated weighting agent comprises a weighting agent and an inorganic material on the weighting agent, wherein the inorganic coating material coats about 10% to about 25% of the surface of the weighting agent;
wherein the weighting agent is iron oxide, and wherein the inorganic coating material comprises barium sulfate, and wherein the coated weighting agent has a specific gravity of 4 to 18.

18. The method of claim 17 , further comprising cleaning the coated weighting agent from the subterranean formation.

19. The method of claim 17 , further comprising dissolving the coated weighting agent with an acidic solution.

20. The method of claim 17 , wherein the inorganic coating material further comprises calcium carbonate.

Assignees

• Halliburton Energy Services Inc

Inventors

• Mcdaniel Cato Russell
• Jamison Dale E
• Ye Xiangnan
• Harvey Timothy N

Classifications

• C04B14/308

  Iron oxide · CPC title

• C04B20/107

  Acids or salts thereof · CPC title

• C09K8/48

  Density increasing or weighting additives · CPC title

• C04B28/02

  containing hydraulic cements other than calcium sulfates · CPC title

• C04B20/008

  Micro- or nanosized fillers, e.g. micronised fillers with particle size smaller than that of the hydraulic binder (colloidal silica C04B14/062 ; silica fume C04B18/146) · CPC title