Paste-like composition and method for producing three-dimensional structures or structural elements on substrate surfaces

Patent metadata

Field	Value
Publication number	US-11034848-B2
Application number	US-201716093907-A
Country	US
Kind code	B2
Filing date	Mar 30, 2017
Priority date	Apr 15, 2016
Publication date	Jun 15, 2021
Grant date	Jun 15, 2021

Abstract

A pasty composition for the manufacture of three-dimensional structures or structural elements on the surface of a substrate is formed together with a polymer as an organic component B1, and a powdery material that makes up a proportion of solid in the range of 60 mass % to 95 mass % in the composition, and
at least two mutually different solvents C1 and C2 that form a solvent mixture. A first solvent C1 has a boiling temperature here that is lower than the boiling temperature of the further solvent or solvents C2.

First claim

The invention claimed is:

1. A method of manufacturing three-dimensional structures or structural elements in which a pasty composition is printed in the form of at least one layer onto the surface of a substrate and a temperature increase is observed in this process at which a first solvent C1 evaporates but a further solvent C2 does not evaporate so that the viscosity of the pasty composition is increased, and subsequently a mechanical processing or plastic deformation is carried out in which a predefined outer contour of the respective structure or of a respective structural element is achieved and subsequently a thermal treatment is carried out in which all organic components including the further solvent C2 are removed and a powdery material is sintered, wherein the pasty composition comprises a polymer as the organic component B1, and the powdery material that makes up a proportion of solid in the range of 60 mass % to 95 mass % in the composition, and
at least two mutually different solvents C1 and C2 that form a solvent mixture, wherein the first solvent C1 has a boiling temperature that is lower than the boiling temperature of the further solvent C2;
wherein the first solvent C1 is selected from hexane, cyclohexane, methyl acetate, ethyl acetate, benzene, methyl ethyl ketone, isopropanol, ethanol, and methanol; and
the further solvent C2 is selected from butyl carbitol, monoethylene glycol, diethylene glycol, 1,2-propanediol, butanol, 3-methoxy-1-butanol, terpene oil, or pine oil; and
the organic polymer B1 is selected from ethyl cellulose of the type N-4 to N-300, methyl methacrylates, n-butyl methacrylates, acrylic polymers or alkyd resins; and
wherein the pasty composition comprises one or more further organic components B2 selected from the group consisting of 1,2,3,4-tetrahydronaphthalene, dimethyl cyclohexyl phthalate, naphthalene, N-oleoylsarcosine, 1,2-cyclohexane dicarboxylic acid diisononylester, 2,4,7,9-tetramethyl-5-decyne-4,7-diol, trihydroxystearin, octadecylamine, triethanolamine, oleic acid and stearic acid.

2. The method in accordance with claim 1 , characterized in that the printing takes place by means of silk screen printing, template printing, tampon printing, or dispensing with a respective layer thickness of at least 100 μm; and/or in that a height to width ratio α in the range 0.05≤a≤1.0 is observed.

3. The method in accordance with claim 1 , characterized in that, at a temperature in the range from 20° C. to 30° C., a viscosity in the range from 40 Pas to 300 Pas is observed with a shear rate γ of 10 s −1 and a viscosity in the range from 10 Pas to 35 Pas is observed with a shear rate γ of 100 s −1 .

4. The method in accordance with claim 1 , characterized in that the first solvent and the at least one further solvent, C1 and C2, are contained with a proportion in the range 3 mass % to 40.0 mass %.

5. The method in accordance with claim 1 , characterized in that 0.05 mass % to 6.0 mass % of plasticizer, softener, leveling agent, wetting additive or dispersion additive B2 and 0.05 mass % to 8.0 mass % of organic polymers B1 are contained in the composition.

6. The method in accordance with claim 1 , characterized in that an oxide, a mixed oxide, a spinel, a perovskite, a metal and/or a glass or a mixture thereof is contained as the powdery material.

7. The method in accordance with claim 1 , characterized in that the powdery material having a mean particle size d 50 in the range between 0.1 μm and 10 μm is contained.

Assignees

• Fraunhofer Ges Forschung

Inventors

• Trofimenko Nikolai
• Lucke Katrin
• Kusnezoff Mihails

Classifications

• B33Y70/10

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• C09D17/00 Primary

  Pigment pastes, e.g. for mixing in paints (artists' paints C09D5/06) · CPC title

• C09D7/68

  Particle size between 100-1000 nm · CPC title

• C09D7/69

  Particle size larger than 1000 nm · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title