Composite material and composite product

Patent metadata

Field	Value
Publication number	US-11034838-B2
Application number	US-201816483149-A
Country	US
Kind code	B2
Filing date	Feb 1, 2018
Priority date	Feb 3, 2017
Publication date	Jun 15, 2021
Grant date	Jun 15, 2021

Abstract

The present invention is directed to a composite material comprising a cellulosic material, high impact polystyrene (HIPS) and styrene maleic anhydride (SMA). The cellulosic material may be thermally modified prior to being incorporated into the composite material. The present invention is also directed to a composite product that comprises the composite material according to the invention.

First claim

The invention claimed is:

1. A composite material comprising:
at least 20% by weight of a cellulosic material,
at least 1% by weight and less than 20% by weight of styrene maleic anhydride, and
from 5% to 50% by weight of a high impact polystyrene,
wherein the cellulosic material is a thermally modified cellulose material, and
wherein the cellulosic material has been thermally modified by heat treatment either at a temperature between 160-250° C. at atmospheric pressure or at a temperature above 120° C. at an elevated pressure.

2. The composite material according to claim 1 , wherein the composite material comprises from 2% to 15% by weight of styrene maleic anhydride.

3. The composite material according to claim 2 , wherein the composite material comprises from 5% to 10% by weight of styrene maleic anhydride.

4. The composite material according to claim 1 , comprising 25-75% by weight of a cellulosic material.

5. The composite material according to claim 4 , comprising 40-65% by weight of a cellulosic material.

6. The composite material according to claim 5 , comprising 45-65% by weight of a cellulosic material.

7. The composite material according to claim 6 , comprising 50-60% by weight of a cellulosic material.

8. The composite material according to claim 1 , comprising 35-50% by weight high impact polystyrene.

9. The composite material according to claim 1 , wherein the cellulosic material has a particle size below 1 mm.

10. The composite material according to claim 1 , wherein the cellulosic material is in the form of a powder.

11. A composite product comprising a composite material according to claim 1 .

12. A process for producing a composite product which process comprises the steps of:
a) providing a cellulosic material, high impact polystyrene (HIPS) and styrene maleic anhydride (SMA), wherein the cellulosic material is a thermally modified cellulose material, and
wherein the cellulosic material has been thermally modified by heat treatment at a temperature between 160-250° C. at atmospheric pressure or at a temperature above 120° C. at elevated pressure;
b) feeding said cellulosic material, HIPS and SMA to an extruder; and
c) extruding the composite product.

13. The composite material according to claim 1 wherein the cellulosic material has been thermally modified by heat treatment at a temperature between 200-230° C. at atmospheric pressure.

14. The composite material according to claim 1 wherein the cellulosic material has been thermally modified by heat treatment at a temperature above 120° C. at an elevated pressure.

Assignees

• Stora Enso Oyj
• Univ Maine System

Inventors

• Mayes Duncan
• Pynnonen Janne
• West Christopher H
• Gardner Douglas J
• Han Yousoo

Classifications

• C08L97/00

  Compositions of lignin-containing materials (of polysaccharides C08L1/00 - C08L5/00) · CPC title

• C08L25/04

  Homopolymers or copolymers of styrene · CPC title

• B27N1/02

  Mixing the material with binding agent (mixing in general B01F) · CPC title

• B27K5/00

  Treating of wood not provided for in groups B27K1/00, B27K3/00 · CPC title

• B27K2200/15

  Pretreated particles or fibres · CPC title