Cellulose ester and ethylene vinyl acetate compositions and articles made using these compositions

Patent metadata

Field	Value
Publication number	US-11034820-B2
Application number	US-201716348560-A
Country	US
Kind code	B2
Filing date	Nov 9, 2017
Priority date	Nov 11, 2016
Publication date	Jun 15, 2021
Grant date	Jun 15, 2021

Abstract

A cellulose ester composition is provided comprising at least one cellulose ester and at least one ethylene vinyl acetate copolymer and optionally at least one plasticizer. Processes for producing the cellulose ester compositions as well as articles made using these compositions, such as eyeglass frames, automotive parts, and toys are also provided.

First claim

That which is claimed is:

1. A cellulose ester composition comprising at least one cellulose ester, at least one ethylene vinyl acetate (EVA) copolymer, and optionally at least one plasticizer,
wherein said at least one cellulose ester is chosen from cellulose propionate (CP), cellulose butyrate (CB), cellulose acetate propionate (CAP), cellulose acetate butyrate (CAB), cellulose propionate butyrate (CPB), cellulose tripropionate (CTP), or cellulose tributyrate (CTB);
wherein the relative viscosity of the at least one cellulose ester is greater than 6.0, for an acetone solution containing 2 wt % of the cellulose ester, measured at 25° C.; and
wherein said cellulose ester composition has a Tg of at least 120° C.

2. The cellulose ester composition of claim 1 , wherein said composition comprises 65-99 wt % of said cellulose ester, 1-35 wt % of said EVA, and 0-15 wt % of said plasticizer.

3. The cellulose ester composition of claim 1 , wherein said composition comprises 65-99 wt % of said cellulose ester, 1-35 wt % of said EVA, and 0-5 wt % of said plasticizer.

4. The cellulose ester composition of claim 1 , wherein said composition comprises 70-97.5 wt % of said cellulose ester, 2.5-30 wt % of said EVA, and contains no plasticizer.

5. The cellulose ester composition of claim 1 , wherein said cellulose ester is chosen from cellulose acetate propionate (CAP) or cellulose acetate butyrate (CAB).

6. The cellulose ester composition of claim 1 , wherein said cellulose ester composition comprises at least two different cellulose esters chosen from cellulose propionate (CP), cellulose butyrate (CB), cellulose acetate propionate (CAP), cellulose acetate butyrate (CAB), cellulose propionate butyrate (CPB), cellulose tripropionate (CTP), or cellulose tributyrate (CTB),
wherein at least one of cellulose esters has a relative viscosity greater than 6.0, for an acetone solution containing 2 wt % of the cellulose ester, measured at 25° C.; and wherein said cellulose ester composition has a Tg of at least 120° C.

7. The cellulose ester composition of claim 1 , wherein said EVA has a vinyl acetate content in the range from 40 to 70 wt %.

8. The cellulose ester composition of claim 7 , wherein said EVA has a vinyl acetate content in the range from 50 to 65 wt %.

9. The cellulose ester composition of any of claim 1 , wherein said EVA is combination of at least two EVA copolymers having different vinyl acetate (VA) content, wherein the average VA content of the combination is in the range from 50 to 65 wt %, and wherein the composition exhibits ductile failure (when tested in accordance with the examples).

10. A cellulose ester composition comprising:
i) at least one cellulose ester chosen from cellulose propionate (CP), cellulose butyrate (CB), cellulose acetate propionate (CAP), cellulose acetate butyrate (CAB), cellulose propionate butyrate (CPB), cellulose tripropionate (CTP), or cellulose tributyrate (CTB);
ii) at least one ethylene vinyl acetate (EVA) copolymer, and
iii) at least one plasticizer;
wherein said cellulose ester composition has a Tg of at least 120° C. and a notched Izod impact strength of at least 200 J/m, measured according to ASTM Method D256 at 23° C. using a 3.2 mm bar, after conditioning the bar at 23° C. and 50% RH for 48 hours.

11. The cellulose ester composition according to claim 10 , wherein said cellulose ester composition has a cellulose ester continuous phase and an EVA copolymer discontinuous phase, and wherein the plasticizer is contained in the EVA discontinuous phase.

12. The cellulose ester composition according to claim 10 , wherein said cellulose ester composition has a Tg that is not more than 5% different than the Tg of a similar cellulose ester composition without the plasticizer.

13. The cellulose ester composition according to claim 10 , wherein the cellulose ester is CAP, the plasticizer is dioctyl adipate (DOA), and said EVA has a vinyl acetate content in the range from 40 to 70 wt %.

14. The cellulose ester composition according to claim 10 , wherein the cellulose ester is CAP, the plasticizer is dioctyl adipate (DOA), and said EVA has a vinyl acetate content in the range from 50 to 65 wt %.

15. The cellulose ester composition according to claim 1 , wherein said composition further comprises at least one additive selected from the group consisting of antioxidants, thermal stabilizers, mold release agents, antistatic agents, whitening agents, colorants, plasticizers, minerals, UV stabilizers, lubricants, nucleating agents, reinforcing fillers, glass fiber, carbon fiber, flame retardants, dyes, pigments, colorants, additional resins and combinations thereof.

16. The cellulose ester composition according to claim 1 , further comprises at least one polymeric component as a blend
wherein said polymer is selected from the group consisting of nylons; polyesters; polyamides; polystyrenes; other cellulose esters, cellulose ethers; polystyrene copolymers; styrene acrylonitrile copolymers; polyolefins; polyurethanes; acrylonitrile butadiene styrene copolymers; poly(methylmethacrylate); acrylic copolymers; poly(ether-imides); polyphenylene oxides; polyvinylchlorides; polyphenylene sulfides; polyphenylene sulfide/sulfones; poly(ester-carbonates); polycarbonates; polysulfones; poly lactic acid; poly butylenesuccinate; polysulfone ethers; and poly(ether-ketones) of aromatic dihydroxy compounds; and combinations thereof.

17. A process for producing a cellulose ester composition comprising mixing:
a) at least one cellulose ester chosen from cellulose propionate (CP), cellulose butyrate (CB), cellulose acetate propionate (CAP), cellulose acetate butyrate (CAB), cellulose propionate butyrate (CPB), cellulose tripropionate (CTP), or cellulose tributyrate (CTB), and
b) at least one EVA for a sufficient time and temperature to disperse said EVA throughout said cellulose ester to produce said composition;
wherein the relative viscosity of the at least one cellulose ester is greater than 6.0, for an acetone solution containing 2 wt % of the cellulose ester, measured at 25° C.

18. An article of manufacture comprising the cellulose ester composition of claim 1 .

19. The article of manufacture according to claim 18 , wherein the article is chosen from an injection molded article, extrusion molded article, injection blow molded article, injection stretch blow molded article, extrusion blow molded article comprising the cellulose ester compositions of claim 1 .

20. A film or sheet comprising a cellulose ester composition according to claim 1 .

Assignees

• Eastman Chem Co

Inventors

• An Haining
• Donelson Michael Eugene
• Feng Wenlai
• Pecorini Thomas Joseph
• Rodig Michael John
• Shelby Marcus David

Classifications

• C08K5/0016

  Plasticisers · CPC title

• C08L1/14 Primary

  Mixed esters, e.g. cellulose acetate-butyrate · CPC title

• C08L23/0853

  Ethylene vinyl acetate copolymers · CPC title

• C08L1/10

  Esters of organic acids {, i.e. acylates} · CPC title