Method for manufacturing polymer latex

Patent metadata

Field	Value
Publication number	US-11034799-B2
Application number	US-201716077612-A
Country	US
Kind code	B2
Filing date	Feb 16, 2017
Priority date	Feb 29, 2016
Publication date	Jun 15, 2021
Grant date	Jun 15, 2021

Abstract

A method for producing a polymer latex, including an emulsification step of mixing a polymer solution obtained by dissolution of synthetic polyisoprene and/or a styrene-isoprene-styrene block copolymer in an organic solvent, with an aqueous solution including 0.1 to 30 parts by weight of a rosinate based on 100 parts by weight in total of the synthetic polyisoprene and the styrene-isoprene-styrene block copolymer, and emulsifying the resultant in water to thereby obtain an emulsified liquid, a solvent removal step of removing the organic solvent in the emulsified liquid, and a concentration step of concentrating the emulsified liquid from which the organic solvent is removed, and also adjusting the content rate of the rosinate in the emulsified liquid after concentration, in the range of 0.1 to 3 parts by weight based on 100 parts by weight in total of the synthetic polyisoprene and the styrene-isoprene-styrene block copolymer in the emulsified liquid.

First claim

The invention claimed is:

1. A method for producing a polymer latex, comprising:
an emulsification step of mixing a polymer solution obtained by dissolution of synthetic polyisoprene and/or a styrene-isoprene-styrene block copolymer in an organic solvent, with an aqueous solution comprising 0.1 to 15 parts by weight of a rosinate based on 100 parts by weight in total of the synthetic polyisoprene and the styrene-isoprene-styrene block copolymer, and emulsifying the resultant in water to thereby obtain an emulsified liquid;
a solvent removal step of removing the organic solvent in the emulsified liquid; and
a concentration step of concentrating the emulsified liquid from which the organic solvent is removed, and also adjusting a content rate of the rosinate in the emulsified liquid in the range of 0.1 to 3 parts by weight based on 100 parts by weight in total of the synthetic polyisoprene and the styrene-isoprene-styrene block copolymer in the emulsified liquid,
wherein an amount of water for use in the emulsification step is 50 to 100 parts by weight based on 100 parts by weight of the polymer solution of the synthetic polyisoprene and the styrene-isoprene-styrene block copolymer.

2. The method for producing a polymer latex according to claim 1 , wherein the emulsified liquid is concentrated by centrifugation in the concentration step.

3. The method for producing a polymer latex according to claim 2 , wherein the centrifugation is performed under a condition of a centrifugal acceleration of 100 to 20,000 G.

4. The method for producing a polymer latex according to claim 1 , wherein the concentration is performed in the concentration step by use of, as the emulsified liquid, an emulsified liquid that is adjusted to have a solid content concentration in the range of 1 to 40% by weight.

5. The method for producing a polymer latex according to claim 1 , wherein the emulsified liquid is concentrated such that a solid content concentration of the emulsified liquid after concentration in the concentration step is 40 to 70% by weight.

6. The method for producing a polymer latex according to claim 1 , wherein the polymer solution is a polymer solution obtained by dissolving, in an organic solvent, the synthetic polyisoprene obtained by solution polymerization of a monomer comprising isoprene dissolved in an organic solvent, and/or the styrene-isoprene-styrene block copolymer obtained by solution polymerization of a styrene-containing monomer and an isoprene-containing monomer, dissolved in an organic solvent, and
the emulsified liquid is obtained by directly emulsifying the polymer solution in water without coagulation in the emulsification step.

7. A method for producing a latex composition, comprising a step of adding a crosslinking agent to a polymer latex obtained by the method according to claim 1 .

8. A method for producing a dip molded article, comprising a step of dip molding a latex composition obtained by the method according to claim 7 .

9. A method for producing an adhesive layer formation substrate, comprising a step of forming an adhesive layer formed by use of a polymer latex obtained by the method according to claim 1 , on a substrate surface.

Assignees

• Zeon Corp

Inventors

• Ishiba Masatoshi
• Aihara Shunjin
• Kodemura Junji

Classifications

• C08C1/10 Primary

  by centrifugation · CPC title

• C08L9/10

  Latex (C08L9/04, C08L9/08 take precedence) · CPC title

• C08C1/15

  characterised by the coagulants used · CPC title

• C08C2/00

  Treatment of rubber solutions · CPC title

• C08L53/02

  of vinyl-aromatic monomers and conjugated dienes · CPC title