Coating agent containing clay, resin, and organic solvent, protective film using same, and product

Patent metadata

Field	Value
Publication number	US-11034140-B2
Application number	US-201615775896-A
Country	US
Kind code	B2
Filing date	Nov 17, 2016
Priority date	Nov 20, 2015
Publication date	Jun 15, 2021
Grant date	Jun 15, 2021

Abstract

Disclosed herein is a coating agent containing a synthetic organically-modified clay comprising a synthetic clay and an organic modification agent, a resin, and an organic solvent, wherein the organic solvent is contained in an amount within the range of 5-70 parts by weight with respect to 30 parts by weight of the resin, and contains at least two selected from the group consisting of toluene, xylene, and ethylbenzene; a protective film using the same; and a product provided with the protective film.

First claim

The invention claimed is:

1. A coating agent containing an organically-modified synthetic clay formed from a synthetic clay and an organically-modifying agent, a resin, and an organic solvent, wherein
the organic solvent is in the range of 5 parts by weight to 70 parts by weight with respect to 30 parts by weight of the resin, and the organic solvent contains two or more selected from the group consisting of toluene, xylene, ethylbenzene, ethyl acetate, butyl acetate, and methyl isobutyl ketone, and
wherein the organically-modifying agent contains polyoxypropylene methyl diethyl ammonium.

2. The coating agent according to claim 1 , wherein the organically-modified synthetic clay is in the range of 1 part by weight to 25 parts by weight with respect to 30 parts by weight of the resin.

3. The coating agent according to claim 1 , wherein the resin is an ultraviolet-curable resin.

4. The coating agent according to claim 1 , and further containing an organic compound that absorbs ultraviolet radiation.

5. A method of making a protective film on a surface of a base material or of a coating layer on the base material, said method comprises coating the coating agent according to claim 1 on the surface, and evaporating said organic solvent therefrom.

6. The method according to claim 5 , wherein when a reinforced coating layer having the protective film is on the surface of the coating layer, a color difference ΔE*ab between the coating layer and the reinforced coating layer is 1.6 or less.

7. The method according to claim 5 , wherein when a reinforced coating layer having the protective film is on the surface of the coating layer, a difference in a G value, which is an index relating to a gloss, between the coating layer and the reinforced coating layer is 20 or less.

8. A method of making a reinforced coating layer, said method comprises coating the coating agent according to claim 1 on comprising: a coating layer, and evaporating the organic solvent therefrom.

9. The method according to claim 8 , wherein the reinforced coating layer has a pencil hardness is 3H or more.

10. A method of making a product comprising a reinforced coating layer according to claim 8 on a surface of at least a part of a base material constituting the product, said method comprises coating the coating agent according to claim 1 on a coating layer coated on the surface, and evaporating the organic solvent therefrom.

11. The method according to claim 10 , wherein the base material comprises at least one selected from the group consisting of glass, ceramics, plastics, metals, and wood, wherein the base material is a molded article.

12. The method according to claim 10 , wherein
the coating layer is formed of a plurality of layers including a silver-seeded layer and a semitransparent layer,
the silver-seeded layer is formed as a layer positioned between the base material and the semitransparent layer, and
a dye is contained in the semitransparent layer.

13. The method according to claim 10 , wherein a main component of the semitransparent layer is a urethane resin, a cashew resin, or a lacquer.

14. The method according to claim 10 , wherein after 100 cycles of washing the product with a detergent in a dishwasher, the product has a color difference ΔE*ab of 1.6 or less from the color of the product before the 100 cycles of washing.

15. The method according to claim 10 , wherein after exposing the product to 1 hour of irradiation with ultraviolet radiation of a wavelength of 365 nm and an intensity of 12,000 μW/cm 2 , the product has a color difference ΔE*ab of 1.6 or less from the color of the product before the exposure.

16. A coating agent comprising
a synthetic clay being organically modified with an organically-modifying agent consisting of polyoxypropylene methyl diethyl ammonium,
a resin, and
an organic solvent mixture consisting of two or more organic solvents selected from the group consisting of toluene, xylene, ethylbenzene, ethyl acetate, butyl acetate, and methyl isobutyl ketone,
wherein the amount of the synthetic clay is 1 to 25 parts per weight per 30 parts per weight of the resin, and
wherein the amount of the organic solvent mixture is 5 to 70 parts per weight per 30 parts per weight of the resin.

17. The coating agent according to claim 16 ,
wherein the amount of the synthetic clay is 1.5 to 3 parts per weight per 30 parts per weight of the resin, and
wherein the amount of the organic solvent mixture is 35 to 70 parts per weight per 30 parts per weight of the resin.

Assignees

• Aist
• Kunimine Ind Co Ltd

Inventors

• Ebina Takeo
• Ishii Ryo
• Hayashi Hiromichi
• Wakui Yoshito
• Tomon Emiko
• Saura Yasuhiro
• Saura Midori
• Matukawa Yasukatu
• Kimura Shinsuke

Classifications

• C03C2217/74

  UV-absorbing coatings · CPC title

• C03C2217/485

  Pigments · CPC title

• C03C2217/475

  Inorganic materials · CPC title

• C03C2217/445

  Organic continuous phases · CPC title

• C03C2217/43

  consisting of a dispersed phase in a continuous phase · CPC title