Magnetic material and manufacturing method therefor

Patent metadata

Field	Value
Publication number	US-11033958-B2
Application number	US-201716087868-A
Country	US
Kind code	B2
Filing date	Mar 24, 2017
Priority date	Mar 25, 2016
Publication date	Jun 15, 2021
Grant date	Jun 15, 2021

Abstract

Provided is a new magnetic material with high magnetic stability, as well as a manufacturing method therefor, said magnetic material having a higher saturation magnetization than ferrite-based magnetic materials, and having a higher electrical resistivity than existing metal-based magnetic materials, thus solving problems such as that of eddy current loss. Mn-ferrite nanoparticles obtained through wet synthesis are reduced within hydrogen, and grains are allowed to grow while simultaneously using a phase separation phenomenon due to a disproportionation reaction to produce a magnetic material powder in which an α-(Fe, Mn) phase and a Mn-enriched phase are nano-dispersed. This powder is then sintered to produce a solid magnetic material.

First claim

The invention claimed is:

1. A soft magnetic or semi-hard magnetic material, comprising a first phase having crystals with a bcc structure containing Fe and Mn and a second phase containing Mn, the second phase having a Mn content that is, when a sum of the Fe and the Mn contained in the second phase is taken to be 100 atom %, larger than a Mn content when a sum of the Fe and the Mn contained in the first phase is taken to be 100 atom %,
wherein the second phase comprises a phase having crystals with a bcc structure containing Fe and Mn, and the Mn content is, when the sum of the Fe and the Mn contained in the phase is taken to be 100 atom %, is an amount of 2 times or more and 10 5 times or less relative to the Mn content when the sum of the Fe and the Mn contained in the first phase is taken to be 100 atom % and/or the Mn content when the sum of the Fe and the Mn contained in the second phase is taken to be 100 atom % is 2 atom % or more and the 100 atom % or less, and
wherein the magnetic material is in a powder form, and when the magnetic material is soft magnetic, the magnetic material has an average powder particle diameter of 10 nm or more and 5 mm or less, and when the magnetic material is semi-hard magnetic, the magnetic material has an average powder particle diameter of 10 nm or more and 10 μm or less.

2. The magnetic material according to claim 1 , wherein the magnetic material is soft magnetic.

3. The magnetic material according to claim 1 , wherein the first phase has a composition represented by a composition formula Fe 100-x Mn x (where x is 0.001≤x≤33 in terms of atomic percentage).

4. The magnetic material according to claim 1 , wherein the first phase has a composition represented by a composition formula Fe 100-x (Mn 100-y M y ) x/100 (where x and y are 0.001≤x≤33 and 0.001≤y<50 in terms of atomic percentage, and M is one or more of Zr, Hf, Ti, V, Nb, Ta, Cr, Mo, W, Ni, Co, Cu, Zn, and Si).

5. The magnetic material according to claim 1 , wherein the second phase comprises a Mn-ferrite phase.

6. The magnetic material according to claim 1 , wherein the second phase comprises a wustite phase.

7. The magnetic material according to claim 1 , wherein the first phase and second phases which have crystals with the bcc structure containing Fe and Mn have a volume fraction of 5% by volume or more based on the whole magnetic material.

8. The magnetic material according to claim 5 , wherein the magnetic material has a composition in a range of, based on the composition of the whole magnetic material, 20 atom % or more and 99.998 atom % or less of Fe, 0.001 atom % or more and 50 atom % or less of Mn, and 0.001 atom % or more and 55 atom % or less of O.

9. The magnetic material according to claim 5 , wherein the magnetic material has a composition in a range of, based on the composition of the whole magnetic material, 66.95 atom % or more and 99.9 atom % or less of Fe, 0.05 atom % or more and 33 atom % or less of Mn, and 0.05 atom % or more and 33 atom % or less of O.

10. The magnetic material according to claim 1 , wherein an average crystal grain size of the first phase, the second phase, or the whole magnetic material is 1 nm or more and 10 μm or less.

11. The magnetic material according to claim 1 , wherein at least the first phase has a bcc phase having a composition represented by a composition formula Fe 100-x Mn x (where x is 0.001≤x≤1 in terms of atomic percentage), and the bcc phase has a crystallite size of 1 nm or more and less than 100 nm.

12. The magnetic material according to claim 1 , wherein at least one of the first phase and the second phase is ferromagnetically coupled with adjacent phases.

13. The magnetic material according to claim 1 , wherein the first phase and the second phase are continuously bonded to each other directly or via a metal phase or an inorganic phase to form a massive state as the whole magnetic material.

14. A method for producing the magnetic material according to claim 1 , comprising reducing a manganese ferrite powder having an average powder particle diameter of 1 nm or more and less than 1 μm in a reducing gas containing hydrogen gas at a reduction temperature of 400° C. or more and 1350° C. or less.

15. A method for producing the magnetic material according to claim 1 , comprising reducing a manganese ferrite powder having an average powder particle diameter of 1 nm or more and less than 1 μm in a reducing gas containing hydrogen gas, and forming the first phase and the second phase by a disproportionation reaction.

16. A method for producing the magnetic material according to claim 13 , comprising reducing a manganese ferrite powder having an average powder particle diameter of 1 nm or more and less than 1 μm in a reducing gas containing hydrogen gas at a reduction temperature of 400° C. or more and 1350° C. or less to produce a magnetic material, and sintering the magnetic material.

17. A method for producing a soft magnetic or semi-hard magnetic material, comprising producing a magnetic material according to claim 14 , and performing annealing at least once after the reduction step.

18. A method for producing a soft magnetic or semi-hard magnetic material, comprising producing a magnetic material according to claim 15 , and performing annealing at least once after the reduction step.

19. A method for producing a soft magnetic or semi-hard magnetic material, comprising producing a magnetic material according to claim 16 , and performing annealing at least once after the reduction step.

20. A method for producing the magnetic material according to claim 13 , comprising reducing a manganese ferrite powder having an average powder particle diameter of 1 nm or more and less than 1 μm in a reducing gas containing hydrogen gas to produce a magnetic material, forming the first phase and the second phase by a disproportionation reaction, and sintering the magnetic material.

Assignees

• Aist

Inventors

• Imaoka Nobuyoshi
• Ozaki Kimihiro

Classifications

• B22F1/08

  Metallic powder characterised by particles having an amorphous microstructure · CPC title

• H01F1/147 Primary

  Alloys characterised by their composition {(treatment thereof for enhancing their electromagnetic properties C21D8/12)} · CPC title

• H01F1/20

  in the form of particles, e.g. powder (H01F1/147 takes precedence) · CPC title

• C22C38/00

  Ferrous alloys, e.g. steel alloys (cast-iron alloys C22C37/00) · CPC title

• C22C22/00

  Alloys based on manganese · CPC title