Electrolyte for lithium secondary batteries and lithium secondary battery including the same
US-2015249269-A1 · Sep 3, 2015 · US
US11031624B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11031624-B2 |
| Application number | US-201816186625-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 12, 2018 |
| Priority date | Nov 21, 2017 |
| Publication date | Jun 8, 2021 |
| Grant date | Jun 8, 2021 |
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Disclosed is a polyalkylene glycol (PAG) polymer having urethane bonds, represented by Structural Formula 1 below. The present invention further relates to a solid polymer electrolyte composition, composed of a polyalkylene glycol polymer having urethane bonds, and a lithium salt. The solid polymer electrolyte of the invention can exhibit superior compatibility, stability, flexibility, mechanical properties and ionic conductivity.
Opening claim text (preview).
What is claimed is: 1. A solid polymer electrolyte, comprising: a matrix comprising polyalkylene glycol polymer gel prepared by subjecting a polyalkylene glycol (PAG) polymer having urethane bonds by Structural Formula 1 below to a sol-gel reaction; and a lithium salt dispersed in the matrix: in Structural Formula 1, R 1 is independently a C1 to C20 alkylene group, R 2 is independently a C1 to C20 alkylene group, R 3 to R 5 are the same as or different from each other, and are each independently a C1 to C20 alkyl group, and n is any one integer of 1 to 150, wherein the lithium salt includes at least one selected from among lithium bis(trifluoromethane)sulfonimide salt, lithium perchlorate, lithium hexafluorophosphate, lithium tetrafluoroborate, and lithium trifluoromethanesulfonate. 2. A lithium secondary battery, comprising the solid polymer electrolyte of claim 1 .
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