Lithium-ion secondary battery

Patent metadata

Field	Value
Publication number	US-11031622-B2
Application number	US-201916443455-A
Country	US
Kind code	B2
Filing date	Jun 17, 2019
Priority date	Jul 4, 2018
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

The present disclosure provides a lithium-ion secondary battery, which comprises a positive electrode plate, a negative electrode plate, a separator and an electrolyte. The lithium-ion secondary battery satisfies a relationship: 1.5≤(m×C)/(ρ×Cap)≤6.5. In the present disclosure, by comprehensively considering the rated capacity of the battery, the mass of the electrolyte and the intrinsic parameters of the electrolyte and reasonably quantifying the relationship thereof, the lithium-ion secondary battery can have good dynamics performance and longer cycle life at the same time.

First claim

What is claimed:

1. A lithium-ion secondary battery comprising a positive electrode plate, a negative electrode plate, a separator and an electrolyte, the electrolyte comprising a lithium salt and an organic solvent;
wherein
the lithium-ion secondary battery satisfies a relationship:

2.13≤(m×C)/(ρ×Cap)<2.63, m represents a total mass of the electrolyte inside the lithium-ion secondary battery with a unit of g, ρ represents a density of the electrolyte with a unit of g/cm 3 , C represents a concentration of the lithium salt in the electrolyte with a unit of mol/L, Cap represents a rated capacity of the lithium-ion secondary battery with a unit of Ah,
the positive electrode plate comprises a positive current collector and a positive film, the positive film is provided on at least one surface of the positive current collector and comprises a positive active material, the positive active material comprises one or more selected from the group consisting of Li x Ni a Co b M c O 2 and a doping and/or coating modified compound thereof, M is one or two selected from the group consisting of Mn and Al, 0.95≤x≤1.2, 0<a<1, 0<b<1, 0<c<1, and
the density of the electrolyte represented by ρ is 1.1 g/cm 3 -1.25 g/cm 3 .

2. The lithium-ion secondary battery according to claim 1 , wherein the negative electrode plate comprises a negative current collector and a negative film, the negative film is provided on at least one surface of the negative current collector and comprises a negative active material, the negative active material at least comprises graphite.

3. The lithium-ion secondary battery according to claim 2 , wherein a coating weight of the negative film per unit area on one surface of the negative current collector represented by CW is 0.006 g/cm 2 -0.012 g/cm 2 .

4. The lithium-ion secondary battery according to claim 3 , wherein the coating weight of the negative film per unit area on one surface of the negative current collector represented by CW is 0.007 g/cm 2 -0.009 g/cm 2 .

5. The lithium-ion secondary battery according to claim 2 , wherein an OI value of the negative film represented by V OI is 11-30,
wherein
V OI =C 004 /C 110 ,
C 004 represents a characteristic diffraction peak area of (004) crystal plane in X-ray diffraction pattern of the negative film, and
C 110 represents a characteristic diffraction peak area of (110) crystal plane in X-ray diffraction pattern of the negative film.

6. The lithium-ion secondary battery according to claim 5 , wherein the OI value of the negative film represented by V OI is 14-30.

7. The lithium-ion secondary battery according to claim 6 , wherein the OI value of the negative film represented by V OI is 16-30.

8. The lithium-ion secondary battery according to claim 2 , wherein a pressing density of the negative film is 1.0 g/cm 3 -1.6 g/cm 3 .

9. The lithium-ion secondary battery according to claim 2 , wherein an average particle diameter of the negative active material represented by D50 is 4 μm-15 μm.

10. The lithium-ion secondary battery according to claim 1 , wherein the concentration of the lithium salt in the electrolyte represented by C is 0.6 mol/L-1.2 mol/L.

11. The lithium-ion secondary battery according to claim 10 , wherein the concentration of the lithium salt in the electrolyte represented by C is 0.8 mol/L-1.17 mol/L.

12. The lithium-ion secondary battery according to claim 1 , wherein m/Cap is 2 g/Ah-6 g/Ah.

13. The lithium-ion secondary battery according to claim 12 , wherein m/Cap is 2 g/Ah-3.0 g/Ah.

14. The lithium-ion secondary battery according to claim 1 , wherein a pressing density of the positive film is 3.3 g/cm 3 -3.55 g/cm 3 .

15. The lithium-ion secondary battery according to claim 1 , wherein a+b+c=1.

Assignees

• Contemporary Amperex Technology Co Ltd

Inventors

• Wang Qiaoge
• Wang Shengwei
• Yan Chuanmiao
• Luo Fuping
• Tan Yanyun
• Zhang Manfang

Classifications

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M10/0566

  Liquid materials · CPC title