Partial trip system for ethylene furnace with ground flare

Patent metadata

Field	Value
Publication number	US-11028327-B2
Application number	US-201916519162-A
Country	US
Kind code	B2
Filing date	Jul 23, 2019
Priority date	Aug 9, 2018
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

Systems and methods are provided for performing a partial trip for an ethane steam cracker while reducing or minimizing ethane consumption in a ground flare system during the partial trip. In particular, a trip system is provided that reduces the firing on an ethylene furnace (such as a reduction into a range of 10% to 40% of normal firing) while also providing a reduced flow of feed to the furnace with dilution steam at a steam to hydrocarbon ratio similar to a ratio that is suitable during normal operation. The trip system can be actuated, for example, when the loss of circulating quench water to the water quench tower is detected.

First claim

What is claimed is:

1. A method for operating a steam cracker, comprising:
combusting fuel comprising a first fuel heating value in one or more burners of a steam cracker furnace to form a first flue gas, the furnace comprising a plurality of process tubes;
passing a first feed comprising ethane and steam to the plurality of process tubes at a process tube inlet temperature of about 840° C. or more to form a product comprising ethylene, a volume ratio of steam to hydrocarbon in the feed being about 0.2 to about 0.5;
separating an ethylene-containing stream from the product comprising ethylene in a water quench system;
detecting a condition indicating a partial furnace trip is required;
combusting, based on the detected condition, fuel comprising a second fuel heating value in the one or more burners to form a second flue gas, the second fuel heating value being 10% to 40% of the first fuel heating value;
passing, based on the detected condition, a second feed comprising ethane and steam into the plurality of process tubes at a process tube inlet temperature of about 538° C. or more to produce an exit stream comprising ethane and steam, a volume ratio of steam to hydrocarbon in the second feed being about 0.2 to about 0.5, a ratio of a volume flow rate of the second feed relative to a volume flow rate of the first feed being about 0.3 to about 0.6; and
directing at least a portion of the exit stream to a ground flare system.

2. The method of claim 1 , wherein the second feed comprising ethane and steam comprises a ratio of steam to hydrocarbon that is the same as the ratio of steam to hydrocarbon in the first feed.

3. The method of claim 1 , wherein the second feed is passed into the plurality of process tubes at a temperature of 538° C. to 815° C.

4. The method of claim 1 , wherein the first feed is substantially composed of ethane and steam, and wherein the second feed is substantially composed of ethane and steam.

5. The method of claim 1 , wherein the first feed comprises 90 wt % or more of ethane relative to a weight of C 2+ hydrocarbons in the first feed, wherein the second feed comprises 90 wt % or more of ethane relative to a weight of C 2+ hydrocarbons in the second feed, or a combination thereof.

6. The method of claim 1 , further comprising:
flowing the first flue gas to a flue gas stack exit via a blower; and
flowing at least a portion of the second flue gas to the flue gas stack exit through a blower bypass conduit, the blower bypass conduit being in fluid communication with the flue gas stack exit during the directing.

7. The method of claim 1 , wherein the steam cracker furnace further comprises a flue gas stack having a height of about 20 m to about 65 m.

8. The method of claim 1 , wherein the ratio of the volume flow rate of the second feed relative to the volume flow rate of the first feed is about 0.3 to about 0.5.

9. The method of claim 1 , wherein at least one of the exit stream and the at least a portion of the exit stream has a heating value of about 700 Btu/SCF or more.

10. The method of claim 1 , wherein at least one of the exit stream and the at least a portion of the exit stream has a heating value of about 800 Btu/SCF or more.

11. The method of claim 1 , further comprising combusting the at least a portion of the exit stream in the ground flare system.

12. The method of claim 11 , wherein the at least a portion of the exit stream is combusted in the ground flare system without introducing additional fuel into the ground flare system.

13. The method of claim 11 , further comprising introducing additional fuel into the ground flare system, a heating value of the additional fuel being 25% or less of a heating value of the at least a portion of the exit stream.

14. The method of claim 1 , wherein a temperature of the plurality of process tubes during the passing of the second feed into the plurality of process tubes is 538° C. to 730° C.

15. The method of claim 1 , wherein the detected condition indicates at least one of:
(i) one or more parameters characteristic of a blower shut-off event, the blower being used to conduct the first flue gas to a flue gas stack exit,
(ii) a bridgewall pressure within the furnace exceeds a pre-determined value,
(iii) a process coil outlet temperature is greater than a pre-determined value,
(iv) a loss of quench water circulating within the water quench system, and
(v) a stop in operation of a component downstream from the water quench system.

16. The process of claim 1 , wherein the condition indicates one or more parameters characteristic of a blower shut-off event, and wherein the one or more parameters comprise a pressure, an electrical current, a blower speed, or a combination thereof.

17. The method of claim 1 , wherein the condition indicates a loss of quench water circulating within the water quench system.

18. The method of claim 17 , wherein detecting the loss of quench water circulating within the water quench system comprises:
detection of a quench tower overhead temperature exceeding a predetermined value;
detection of a quench tower oil flow rate falling below a predetermined value;
detection of a pressure within the quench water system in at least three locations with at least two of the three locations being below a predetermined value for the respective location;
detection of a quench water pump discharge pressure dropping below a pre-determined value;
or a combination thereof.

19. The method of claim 1 , wherein the condition indicates a stop in operation of a component downstream from the water quench system.

20. The method of claim 19 , wherein the component comprises a process gas compressor, and wherein detecting the condition comprises detecting an increase in a pressure associated with the process gas compressor.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Yeo Gregory E
• Port Jennifer L
• Le Roy Philippe J

Classifications

• C10G2300/1081

  Alkanes · CPC title

• C10G9/206 Primary

  controlling or regulating the tube furnaces · CPC title

• C10G2300/4012

  Pressure · CPC title

• C10G2300/4056

  Retrofitting operations · CPC title

• C07C5/327

  Formation of non-aromatic carbon-to-carbon double bonds only · CPC title