Passive thermally driven variable opacity materials

Patent metadata

Field	Value
Publication number	US-11028319-B2
Application number	US-201816222424-A
Country	US
Kind code	B2
Filing date	Dec 17, 2018
Priority date	Dec 20, 2017
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

A variable opacity material is provided that may be in the form of a mixture, such as an emulsion that contains a discontinuous aqueous polymeric solution having an LCST of 0 to 100° C. and a continuous phase containing a hydrophobic polymer, such as a polysiloxane. One or more salts, such as lithium bromide and sodium chloride, may be added to the aqueous solution to lower the LCST of the aqueous solution and to raise the refractive index of the aqueous polymeric solution to substantially match the refractive index of the hydrophobic polymer. The variable opacity materials may be applied in the form of a film to various substrates, such as glass.

First claim

We claim:

1. A variable opacity material comprising an emulsion of an aqueous polymeric solution and a hydrophobic polymer, wherein:
the aqueous polymeric solution comprises hydroxypropyl cellulose or poly(N-isopropylacrylamide) and from 10 to 60 wt. % of an alkaline earth metal salt, wherein the hydroxypropyl cellulose or poly(N-isopropylacrylamide) phase separates at temperatures above the lower critical solution temperature (LCST),
the aqueous polymeric solution has an LCST from 0 to 100° C.,
the aqueous polymeric solution is emulsified in the hydrophobic polymer,
the aqueous polymeric solution is a discontinuous phase of the emulsion and the hydrophobic polymer is a continuous phase of the emulsion, and
below the LCST, the difference between refractive indices of the aqueous polymeric solution and the hydrophobic polymer is less than or equal to 0.05.

2. The variable opacity material of claim 1 , wherein the hydrophobic polymer comprises a polysiloxane.

3. The variable opacity material of claim 2 , wherein the polysiloxane comprises polydimethyl siloxane.

4. The variable opacity material of claim 1 , wherein the aqueous polymeric solution comprises a second salt.

5. The variable opacity material of claim 4 , wherein the aqueous polymeric solution comprises less than or equal to 5 wt. % of the second salt.

6. The variable opacity material of claim 4 , wherein the second salt is sodium chloride.

7. The variable opacity material of claim 1 , wherein the at least one salt is magnesium bromide.

8. The variable opacity material of claim 1 , wherein the aqueous polymeric solution comprises hydroxypropyl cellulose.

9. The variable opacity material of claim 1 , wherein the aqueous polymeric solution has an LCST greater than or equal to 25° C. and less than or equal to 35° C.

10. The variable opacity material of claim 1 , wherein the aqueous polymeric solution has a refractive index greater than or equal to 1.4.

11. The variable opacity material of claim 1 , wherein the aqueous polymeric solution comprises from 1 to 40 wt. % of a polymer.

12. The variable opacity material of claim 1 , wherein the hydrophobic polymer is curable.

13. The variable opacity material of claim 12 , wherein the hydrophobic polymer is thermally curable.

14. The variable opacity material of claim 1 , wherein the hydrophobic polymer is crosslinked.

15. The variable opacity material of claim 1 , wherein the continuous phase is crosslinked.

16. A variable opacity film comprising the variable opacity material of claim 1 coated between two substrates.

17. The variable opacity film of claim 16 , wherein at least one of the substrates is transparent.

Assignees

• E Ink Corp

Inventors

• Widger Peter Carsten Bailey
• Anseth Jay William
• Paolini Jr Richard J
• Breen Craig Alan
• Viola Wesley

Classifications

• B32B2307/41

  Opaque · CPC title

• C09K9/02 Primary

  Organic tenebrescent materials · CPC title

• B32B17/10

  of synthetic resin · CPC title

• G02F1/0147 Primary

  based on thermo-optic effects (G02F1/132 takes precedence) · CPC title