Wood adhesive formulation

Patent metadata

Field	Value
Publication number	US-11028295-B2
Application number	US-201314370064-A
Country	US
Kind code	B2
Filing date	Jan 8, 2013
Priority date	Jan 26, 2012
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

The invention relates to a formulation comprising: —a first component which is formed from at least one isocyanate and at least one amino resin, wherein said amino resin is the condensation product of an aldehyde with a compound selected from the group comprising urea, melamine, benzoguanamine, glycoluril, acetoguanamine and mixtures thereof; and —a second component comprising at least one polyether, wherein said polyether comprises at least one ethylene oxide moiety and at least one isocyanate reactive group selected from the group comprising hydroxyl, amino, epoxy, and thiol, preferably hydroxyl.

First claim

The invention claimed is:

1. A lignocellulosic body consisting of:
(i) a plurality of lignocellulosic materials,
(ii) a two component adhesive formulation applied onto the lignocellulosic materials for bonding the lignocellulosic materials, the two component adhesive formulation consisting of:
(a) a first adhesive component which is formed from at least one isocyanate selected from hexamethylene diisocyanate, m-phenylene diisocyanate, p-phenylene diisocyanate, tolylene-2,4-diisocyanate, tolylene-2,6-diisocyanate, polymeric MDI, chlorophenylene-2,4-diisocyanate, naphthylene-1,5-diisocyanate, diphenylene-4,4′-diisocyanate, 4,4′-diisocyanate-3,3′-dimethyl-diphenyl, 3-methyl-diphenylmethane-4,4′-diisocyanate, diphenyl ether diisocyanate, cyclohexane-2,4-diisocyanate, cyclohexane-2,3-diisocyanate, 1-methylcyclohexyl-2,4-diisocyanate, 1-methylcyclohexyl-2,6-diisocyanate, bis-(isocyana-tocyclohexyl)methane, 2,4,6-triisocyanatotoluene, 2,4,4-triisocyanatodiphenylether, isophorone diisocyanate, butylene diisocyanate, trimethylhexamethylene diisocyanate, isocyanatomethyl-1,8-octane diisocyanate, tetramethylxylene diisocyanate, 1,4-cyclohexanediisocyanate, tolidine diisocyanate, and a mixture thereof and 64% by weight to 95% by weight, based on 100% by weight of the formulation of at least one amino resin, wherein said amino resin is the condensation product of an aldehyde with a compound selected from the group comprising urea, melamine, benzoguanamine, glycoluril, acetoguanamine and mixtures thereof; and
(b) a second adhesive component comprising at least one polyether compound, acting as a compatibilizing agent, having an average molecular weight of from 3500 to 40000 and an average nominal functionality of 2 to 6, wherein said polyether compound comprises at least 15% by weight ethylene oxide groups based on 100% by weight of the at least one polyether compound and at least one ethylene oxide moiety and at least two isocyanate reactive groups selected from the group consisting of hydroxyl, amino, epoxy, and thiol, and wherein the polyether compound is a reaction product of ethylene oxide and a polyfunctional initiator and, optionally, at least one other cyclic oxide; and wherein the ethylene oxide content to isocyanate is of at least 10% by weight based on the combined weight of the at least one isocyanate and the at least one polyether; and

(iii) optionally, an additive selected from the group comprising a hardener, a surfactant, a release agent, a wax, or a pigment.

2. The lignocellulosic body according to claim 1 , wherein said amino resin is the condensation product of a compound as defined in claim 1 with an aldehyde selected from the group comprising formaldehyde, acetaldehyde, crotonaldehyde, acrolein, benzaldehyde, and furfural.

3. The lignocellulosic body according to claim 1 , wherein the polyfunctional initiator is selected from the group consisting of ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, cyclohexane dimethanol, resorcinol, bisphenol A, glycerol, trimethylolopropane, 1,2,6-hexantriol, pentaerythritol and mixtures thereof.

4. The lignocellulosic body according to claim 3 , wherein the at least one other cyclic oxide is propylene oxide.

5. The lignocellulosic body according to claim 1 , wherein the at least one isocyanate is present in an amount of at least 0.5% by weight based on 100% by weight of the total adhesive formulation.

6. The lignocellulosic body according to claim 1 , wherein the at least one polyether is present in an amount of at least 0.01% by weight based on 100% by weight of the total adhesive formulation.

7. The lignocellulosic body according to claim 1 , wherein the adhesive formulation has an ethylene oxide content greater than 30% by weight based on the combined weight of the at least one isocyanate and the at least one polyether.

8. The lignocellulosic body according to claim 1 , wherein the additive is present in an amount of at least 0.01% by weight based on the total adhesive formulation.

9. The lignocellulosic body according to claim 1 , where the additive is an ammonium salt.

Assignees

• Huntsman Int Llc

Inventors

• Holvoet Servaas
• Pratelli Daniele
• Phanopoulos Christopher

Classifications

• C08G18/4837 Primary

  and other oxyalkylene units · CPC title

• C08G18/4027

  Mixtures of compounds of group C08G18/54 with other macromolecular compounds · CPC title

• C08G18/544

  with nitrogen compounds · CPC title

• C08G18/283

  Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds · CPC title

• C08L97/02

  Lignocellulosic material, e.g. wood, straw or bagasse {(manufacture of articles made from lignocellulosic material by dry processes B27N)} · CPC title