Development of a sol-gel anticorrosion treatment

Patent metadata

Field	Value
Publication number	US-11028275-B2
Application number	US-201716076508-A
Country	US
Kind code	B2
Filing date	Feb 9, 2017
Priority date	Feb 9, 2016
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

The invention relates to a process for treating a metal alloy part, characterized in that it comprises the following steps: —producing a stock formulation by mixing, in equal molar parts of silicon, an alcoholic solution of hydrolysed epoxysilane and an alcoholic solution of hydrolysed aminosilane, —mixing the stock formulation with a suspension comprising conductive nanowires in an amount by weight of between 0.1% and 10% relative to the total weight of the stock formulation in order to obtain a dilute formulation, and —depositing the dilute formulation on the part in order to obtain the coating.

First claim

The invention claimed is:

1. A treatment process for a metal alloy part comprising the following steps:
produce a stock formulation by mixing, in equal molar parts of silicon, an alcoholic solution of hydrolyzed epoxysilane and an alcoholic solution of hydrolyzed aminosilane,
mix the stock formulation with a suspension comprising conductive nanowires in an amount by weight between 0.1% and 10% based on the total weight of the stock formulation to obtain a dilute formulation, and
deposit the dilute formulation on the part to obtain the coating,
wherein the stock formulation further comprises fluorosilane, at a molar concentration between 0.5% and 5% based on the silicon derived from the epoxysilane and from the aminosilane and/or from the nanometric silica, at a molar concentration between 1% and 5% based on the silicon derived from the epoxysilane and from the aminosilane.

2. The process according to claim 1 , wherein the conductive nanowires comprise silver nanowires, carbon nanowires and/or copper nanowires.

3. The process according to claim 1 , wherein the conductive nanowires comprise silver nanowires, the suspension of silver nanowires being produced by centrifugation of a suspension of nanowires and silver particles at a speed between 2000 and 6000 revolutions per minute.

4. The process according to claim 3 , wherein the suspension of silver nanowires is obtained in accordance with the following substeps:
dissolve polyvinyl pyrrolidone in ethylene glycol to obtain a solution,
heat the solution thus obtained to a temperature between 100° C. and 160° C., and
after temperature stabilization, add a solution of sodium chloride and iron(II) acetylacetonate, then add a solution of silver nitrate in ethylene glycol.

5. The process according to claim 1 , wherein the alcoholic solution of aminosilane comprises isopropanol.

6. The process according to claim 1 , wherein a concentration of the alcoholic solution of hydrolyzed epoxysilane and a concentration of the alcoholic solution of hydrolyzed aminosilane is about 0.1 mol/L.

7. The process according to claim 1 , wherein the stock formulation further comprises a dye at a weight concentration between 0.5% and 5% based on the dry weight of the stock formulation.

8. The process according to claim 1 , further comprising, prior to the deposition step of the coating, a step of stripping the part and/or a step of pretreating the part with an adhesion promoter.

9. The process according to claim 1 , further comprising, after the deposition step of the coating, a step of polymerization of the part at a temperature between 80° C. and 150° C.

10. The process according to claim 1 , wherein, in the stock formulation, the conductive nanowires have an aspect ratio between 1 and 100.

11. The process according to claim 1 , wherein the deposition step is carried out by spraying the dilute formulation onto the part, by dipcoating the part in the dilute formulation or by robotic means.

12. A metal alloy part, characterized in that it comprises a coating obtained according to a treatment process according to claim 1 , having a coating thickness between 0.5 and 5 microns.

13. The part according to claim 12 , wherein a constituent material of the part comprises an aluminum alloy, an iron alloy or a magnesium alloy.

14. The part according to claim 12 , wherein the coating comprises silver nanowires.

15. The process according to claim 9 , wherein the step of polymerization of the part is performed at a temperature between 80° C. and 120° C.

Assignees

• Safran
• Rbnano
• Safran Landing Systems

Inventors

• Cambon Jean-Baptiste
• Esteban Julien
• Mafouana Roland Rodrigue
• Ruetsch Jean-Philippe

Classifications

• C08K2201/001

  Conductive additives · CPC title

• C09D5/08

  Anti-corrosive paints · CPC title

• C23C18/127

  Preformed particles · CPC title

• C09D7/43

  Thickening agents · CPC title

• C23C18/122

  Inorganic polymers, e.g. silanes, polysilazanes, polysiloxanes · CPC title