Flame-retardant resin composition, and insulating wire, metal cable, optical fiber cable and molded article using the same

Patent metadata

Field	Value
Publication number	US-11028257-B2
Application number	US-201716462478-A
Country	US
Kind code	B2
Filing date	Oct 3, 2017
Priority date	Nov 22, 2016
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

A flame-retardant resin composition may include a base resin composed of polyethylene and an acid-modified polyolefin, a silicone compound, a fatty acid-containing compound, and a hindered amine-based compound that includes a hindered amine structure. The polyethylene may include a high-density polyethylene, a medium-density polyethylene and a low-density polyethylene, where the high-density polyethylene has a density of 945 kg/m3 or more, the medium-density polyethylene has a density of 914 kg/m3 or more and less than 945 kg/m3, and the low-density polyethylene has a density of 864 kg/m3 or more and less than 914 kg/m3. The base resin may contain the high-density polyethylene in an amount of 40 mass % or more and 60 mass % or less, the medium-density polyethylene in an amount of 1 mass % or more and 35 mass % or less, and the low-density polyethylene in an amount of 10 mass % or more and 30 mass % or less.

First claim

The invention claimed is:

1. A flame-retardant resin composition, comprising:
a base resin composed of polyethylene and an acid-modified polyolefin;
a silicone compound;
a fatty acid-containing compound; and
a hindered amine-based compound including a hindered amine structure;
wherein the polyethylene includes a high-density polyethylene, a medium-density polyethylene and a low-density polyethylene,
wherein the high-density polyethylene has a density of 945 kg/m 3 or more,
the medium-density polyethylene has a density of 914 kg/m 3 or more and less than 945 kg/m 3 , and
the low-density polyethylene has a density of 864 kg/m 3 or more and less than 914 kg/m 3 ,
wherein the base resin contains the high-density polyethylene in an amount of 40 mass % or more and 60 mass % or less,
the base resin contains the medium-density polyethylene in an amount of 1 mass % or more and 35 mass % or less,
the base resin contains the low-density polyethylene in an amount of 10 mass % or more and 30 mass % or less, and
the base resin contains the acid-modified polyethylene in an amount of 1 mass % or more and 20 mass % or less,
wherein the silicone compound is blended in an amount of 3 parts by mass or more and 10 parts by mass or less relative to 100 parts by mass of the base resin,
the fatty acid-containing compound is blended in an amount of 3 parts by mass or more and 10 parts by mass or less relative to 100 parts by mass of the base resin,
the hindered amine-based compound is blended in an amount of 0.2 part by mass or more and 2.4 parts by mass or less relative to 100 parts by mass of the base resin, and
wherein the hindered amine-based compound is composed of a first hindered amine-based compound and a second hindered amine-based compound different from the first hindered amine-based compound.

2. The flame-retardant resin composition according to claim 1 , wherein in the first hindered amine-based compound, a nitrogen atom of the hindered amine structure is bonded to an oxygen atom, and
in the second hindered amine-based compound, a nitrogen atom of the hindered amine structure is bonded to a hydrogen atom or a carbon atom.

3. The flame-retardant resin composition according to claim 2 , wherein the first hindered amine-based compound includes a group represented by the following formula (1A):

where R 1 to R 4 each independently represent an alkyl group having 1 to 8 carbon atoms; R 5 represents an alkyl group having 1 to 18 carbon atoms, a cycloalkyl group having 5 to 12 carbon atoms, an aralkyl group having 7 to 25 carbon atoms, or an aryl group having 6 to 12 carbon atoms.

4. The flame-retardant resin composition according to claim 3 , wherein the first hindered amine-based compound is represented by the following formula (2A):

where R 6 to R 8 each independently represent a group represented by the following formula (3A):

where R 9 and R 10 each independently represent a group represented by the formula (1A); and R 11 and R 12 each independently represent an alkyl group having 1 to 18 carbon atoms.

5. The flame-retardant resin composition according to claim 4 , wherein the second hindered amine-based compound includes a repeating unit represented by the following formula (4A):

where R 13 represents a group containing a nitrogen atom; R 14 and R 15 each independently represent a group represented by the following formula (5A); and n represents an integer of 1 to 8,

where R 16 represents a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, a cycloalkyl group having 5 to 12 carbon atoms, an aralkyl group having 7 to 25 carbon atoms, or an aryl group having 6 to 12 carbon atoms; and R 17 to R 20 each independently represent an alkyl group having 1 to 8 carbon atoms.

6. The flame-retardant resin composition according to claim 1 , wherein the first hindered amine-based compound is blended in an amount of 0.1 part by mass or more and 1.2 parts by mass or less relative to 100 parts by mass of the base resin, and
the second hindered amine-based compound is blended in an amount of 0.1 part by mass or more and 1.2 parts by mass or less relative to 100 parts by mass of the base resin.

7. The flame-retardant resin composition according to claim 1 , further comprising calcium carbonate,
wherein the calcium carbonate is blended in an amount of more than 0 part by mass and 60 parts by mass or less relative to 100 parts by mass of the base resin.

8. The flame-retardant resin composition according to claim 1 , wherein the acid-modified polyolefin is a maleic anhydride-modified polyolefin.

9. The flame-retardant resin composition according to claim 1 , wherein the silicone compound is silicone gum.

10. The flame-retardant resin composition according to claim 1 , wherein the fatty acid-containing compound is magnesium stearate.

11. An insulating wire, comprising:
a metal conductor; and
an insulating layer that covers the metal conductor,
wherein the insulating layer is composed of the flame-retardant resin composition according to claim 1 .

12. A metal cable, comprising:
an insulating wire including a metal conductor and an insulating layer covering the metal conductor; and
a covering layer covering the insulating wire,
wherein at least one of the insulating layer and the covering layer is composed of the flame-retardant resin composition according to claim 1 .

13. An optical fiber cable, comprising:
an optical fiber; and
a covering part covering the optical fiber,
wherein the covering part includes an insulating body directly covering the optical fiber cable, and
wherein the insulating body is composed of the flame-retardant resin composition according to claim 1 .

14. A molded article, comprising the flame-retardant resin composition according to claim 1 .

Assignees

• Fujikura Ltd

Inventors

• Yamaki Yusuke
• Nakamura Shoichiro

Classifications

• C08L23/0815 Primary

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08L2207/062

  HDPE · CPC title

• C08K5/09

  Carboxylic acids; Metal salts thereof; Anhydrides thereof · CPC title

• C08L2207/064

  VLDPE · CPC title

• H01B3/44

  vinyl resins; acrylic resins (silicones H01B3/46) · CPC title