Absorbent article containing a porous polyolefin film

Patent metadata

Field	Value
Publication number	US-11028246-B2
Application number	US-201414895223-A
Country	US
Kind code	B2
Filing date	Jun 6, 2014
Priority date	Jun 12, 2013
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

An absorbent article containing a polyolefin film is provided. The polyolefin film is formed by a thermoplastic composition containing a continuous phase that includes a polyolefin matrix polymer and nanoinclusion additive is provided. The nanoinclusion additive is dispersed within the continuous phase as discrete nano-scale phase domains. When drawn, the nano-scale phase domains are able to interact with the matrix in a unique manner to create a network of nanopores.

First claim

What is claimed is:

1. An absorbent article that contains an absorbent member positioned between a backsheet and a topsheet, wherein the absorbent article comprises a film formed from a thermoplastic composition that contains a continuous phase that includes a polyolefin matrix polymer and a nanoinclusion additive dispersed within the continuous phase in the form of discrete domains, wherein the nanoinclusion additive includes a functionalized polyolefin,
wherein a porous network is defined in the composition that includes a plurality of nanopores having an average cross-sectional dimension of about 800 nanometers or less;
wherein the nanoinclusion additive is present in the thermoplastic composition in an amount from about 0.05 wt. % to about 10 wt. % based on the weight of the continuous phase;
wherein the composition further comprising a microinclusion additive dispersed within the continuous phase in the form of discrete domain and the microinclusion additive is a polymer that includes a styreneic copolymer, fluoropolymer, polyvinyl alcohol, polyvinyl acetate, or polyester;
wherein the microinclusion additive is present in the thermoplastic composition in an amount of from about 1 wt. % to about 20 wt. %; and
wherein the film has a hydrohead value of 50 centimeters or more, as determined in accordance with ATTCC 127-2008.

2. The absorbent article of claim 1 , wherein the nanopores have an average cross-sectional dimension of from about 5 to about 700 nanometers.

3. The absorbent article of claim 1 , wherein the nanopores have an average axial dimension of from about 100 to about 5000 nanometers.

4. The absorbent article of claim 1 , wherein the polyolefin matrix polymer has a melt flow rate of from about 0.5 to about 80 grams per 10 minutes, determined at a load of 2160 grams and at 230° C. in accordance with ASTM D1238.

5. The absorbent article of claim 1 , wherein the polyolefin matrix polymer is a propylene homopolymer, a propylene/a-olefin copolymer, an ethylene/a-olefin copolymer, or a combination thereof.

6. The absorbent article of claim 1 , wherein the polyolefin matrix polymer is an isotactic polypropylene homopolymer or a copolymer containing at least about 90% by weight propylene.

7. The absorbent article of claim 1 , wherein the continuous phase constitutes from about 60 wt. % to about 99 wt. % of the thermoplastic composition.

8. The absorbent article of claim , wherein the functionalized polyolefin is a polyepoxide.

9. The absorbent article of claim 1 , wherein the nanoinclusion additive has a melt flow rate of from about 0.1 to about 100 grams per 10 minutes, determined at a load of 2160 grams and at a temperature at least about 40° C. above the melting temperature in accordance with ASTM D1238.

10. The absorbent article of claim 9 , wherein the ratio of the melt flow rate of the polyolefin matrix polymer to the melt flow rate of the nanoinclusion additive is from about 0.2 to about 8.

11. The absorbent article of claim 1 , wherein the nanoinclusion additive is in the form of nano-scale domains, wherein the nano-scale domains have an average cross-sectional dimension of from about 1 nanometer to about 1000 nanometers.

12. The absorbent article of claim 1 , wherein the polymer of the microinclusion additive is polylactic acid.

13. The absorbent article of claim 1 , wherein the microinclusion additive has a melt flow rate of from about 5 to about 200 grams per 10 minutes, determined at a load of 2160 grams and at a temperature of 210° C.

14. The absorbent article of claim 1 , wherein the microinclusion additive is in the form of micro-scale domains having an average axial dimension of from about 1 micrometer to about 400 micrometers.

15. The absorbent article of claim 1 , wherein the thermoplastic composition further comprises an interphase modifier.

16. The absorbent article of claim 1 , wherein the porous network further includes micropores.

17. The absorbent article of claim 1 , wherein the total pore volume of the composition is from about 15% to about 80% per cubic centimeter.

18. The absorbent article of claim 1 , wherein nanopores constitute about 20 vol.% or more of the total pore volume of the composition.

19. The absorbent article of claim 1 , wherein the thermoplastic composition has a density of about 0.90 g/cm 3 or less.

20. The absorbent article of claim 1 , wherein the film has a water vapor transmission rate of about 300 g/m 2 /24 hours or more.

21. The absorbent article of claim 1 , wherein the film is a multi-layered film that contains a core layer and at least one outer layer, wherein the core layer, the outer layer, or both contain the thermoplastic composition.

22. The absorbent article of claim 1 , wherein the thermoplastic composition is free of calcium carbonate fillers.

23. The absorbent article of claim 1 , wherein the backsheet contains the film.

24. The absorbent article of claim 1 , wherein the article contains an additional component that includes the film, the additional component including ears, containment flaps, side panels, elastic members, fasteners, or a combination thereof.

Assignees

• Kimberly Clark Co
• Kimberly Clark Inc

Inventors

• Topolkaraev Vasily A
• Mceneany Ryan J
• Carrillo Antonio J
• Mleziva Mark M
• Meyer Andy J

Classifications

• B01D71/262

  Polypropylene · CPC title

• A61F13/53

  characterised by the absorbing medium (A61F13/20 takes precedence) · CPC title

• B01D67/0027 Primary

  by stretching · CPC title

• B29C55/00

  Shaping by stretching, e.g. drawing through a die; Apparatus therefor (B29C61/08 takes precedence) · CPC title

• B29L2007/007

  Narrow strips, e.g. ribbons, tapes, bands (belts B29L2029/00; tapes as carrier of sound or information B29L2017/008) · CPC title