Flame retardant polyolefin-type resin and preparation method as well as optic fiber cable using the same

Patent metadata

Field	Value
Publication number	US-11028207-B2
Application number	US-201916394556-A
Country	US
Kind code	B2
Filing date	Apr 25, 2019
Priority date	Oct 26, 2016
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

A method of preparing a flame retardant grafted polyolefin resin is provided. The method includes a step of reacting in an extrusion barrel a reactive polyolefin and a monomeric flame retardant agent to form the flame retardant grafted polyolefin resin. The reactive polyolefin has a functional group including a moiety selected from the group consisting of anhydrides, epoxies, carboxylic acids, ketones, and isocyanates. The monomeric flame retardant agent has an amine functional group. The method also includes a step of extruding the flame retardant grafted polyolefin resin. Also provided is a flame retardant grafted polyolefin resin that can be made according to the method. Further provided is a flame retardant cable that incorporates can incorporate the flame retardant grafted polyolefin resin.

First claim

What is claimed is:

1. A method of preparing a flame retardant grafted polyolefin resin, the method comprising the steps of:
reacting in an extrusion barrel a reactive polyolefin and a monomeric flame retardant agent to form the flame retardant grafted polyolefin resin, wherein the reactive polyolefin has a functional group including a moiety selected from the group consisting of anhydrides, epoxies, carboxylic acids, ketones, and isocyanates and wherein the monomeric flame retardant agent has an amine functional group and contains at least one element selected from the group consisting of phosphorus, nitrogen, silicon, and sulfur, the at least one element comprising more than 10% by weight of the monomeric flame retardant agent; and
extruding the flame retardant grafted polyolefin resin.

2. The method of claim 1 , wherein the reactive polyolefin is a copolymer selected from the group consisting of olefin/glycidyl methacrylate, olefin/maleic anhydride, olefin/acrylate/glycidyl methacrylate, olefin/acrylate/maleic anhydride, and combinations thereof.

3. The method of claim 1 , wherein the at least one element comprises more than 30% by weight of the monomeric flame retardant agent.

4. The method of claim 1 , wherein the amine functional group is a primary amine functional group.

5. The method of claim 1 , wherein the reactive polyolefin comprises from 51 wt % to 98 wt % of olefin repeating units.

6. The method of claim 1 , wherein the reactive polyolefin comprises from 2 wt % to 49 wt % of functional group repeating units.

7. The method of claim 6 , wherein the reactive polyolefin comprises from 2 wt % to 20 wt % of functional group repeating units.

8. The method of claim 1 , wherein the steps of reacting and extruding are performed in the extrusion barrel of a twin screw extruder.

9. The method of claim 8 , wherein, during the reacting step, the reactive polyolefin and the monomeric flame retardant agent resides in the extrusion barrel for a time of 30 minutes or less.

10. The method of claim 9 , wherein the reacting step is performed at a temperature of 140° C. or higher.

11. The method of claim 9 , wherein the reacting step achieves a conversion of at least 60%.

12. The method of claim 1 , wherein the functional group of the reactive olefin and the monomeric flame retardant agent are provided to the extrusion barrel in a molar ratio of between 1:2 and 2:1.

13. A flame retardant grafted polyolefin resin, comprising:
a reactive polyolefin having a functional group including a moiety selected from the group consisting of anhydrides, epoxies, carboxylic acids, ketones, and isocyanates; and
a monomeric flame retardant agent including an amine group and containing at least one element selected from the group consisting of phosphorus, nitrogen, silicon, and sulfur, the at least one element comprising more than 10% by weight of the monomeric flame retardant agent;
wherein the monomeric flame retardant agent is grafted to the reactive polyolefin through a reaction between the amine group and the functional group of the reactive polyolefin.

14. The flame retardant compound of claim 13 , wherein the reactive polyolefin is a copolymer selected from the group consisting of olefin/glycidyl methacrylate, olefin/maleic anhydride, olefin/acrylate/glycidyl methacrylate, olefin/acrylate/maleic anhydride, and mixtures thereof.

15. The flame retardant compound of claim 13 , wherein amine functional group is a primary amine functional group.

16. The flame retardant compound of claim 13 , wherein the reactive polyolefin comprises from 2 wt % to 49 wt % of functional group repeating units.

17. A flame retardant cable comprising:
at least one communication element;
a polymeric jacket that surrounds the at least one communication element;
wherein the polymeric jacket is formed at least in part from a flame retardant grafted polyolefin resin comprising:
a reactive polyolefin having a first functional group; and
a monomeric flame retardant agent have a second functional group;
wherein the monomeric flame retardant agent is grafted to the reactive polyolefin through a reaction between the first functional group and the second functional group.

18. The flame retardant cable of claim 17 , wherein the at least one communication element comprises an optical fiber.

19. The flame retardant cable of claim 17 , wherein the first functional group includes a moiety selected from the group consisting of anhydrides, epoxies, carboxylic acids, ketones, and isocyanates.

20. The flame retardant cable of claim 17 , wherein the monomeric flame retardant is comprised of at least 10% by weight of a at least one element selected from the group consisting of phosphorus, nitrogen, silicon, and sulfur.

21. The flame retardant cable of claim 17 , wherein the second functional group includes an amine.

Assignees

• Corning Inc

Inventors

• Cheng Xiaole
• Jiang Dayue

Classifications

• C08F255/026 Primary

  on to ethylene-vinylester copolymers · CPC title

• C08F8/32 Primary

  by reaction with amines · CPC title

• C08L51/06

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• H01B7/00

  Insulated conductors or cables characterised by their form · CPC title

• C08F8/40

  Introducing phosphorus atoms or phosphorus-containing groups · CPC title