Method for recovering dimethyl sulfoxide from recovered resist remover

Patent metadata

Field	Value
Publication number	US-11028047-B2
Application number	US-201816630630-A
Country	US
Kind code	B2
Filing date	Jul 31, 2018
Priority date	Aug 2, 2017
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

A method for recovering dimethyl sulfoxide, including a step of contacting a recovered resist remover containing at least one compound selected from the group consisting of glycol ether, glycol and triol, and dimethyl sulfoxide with water and performing distillation.

First claim

The invention claimed is:

1. A method for recovering dimethyl sulfoxide from a composition, the method comprising:
contacting the composition with water, where the composition comprises at least one compound selected from a group consisting of glycol ethers, glycols, and triols, and dimethyl sulfoxide;
and performing distillation on the composition contacted with water to recover a purified dimethyl sulfoxide product,
wherein an amount of the water contacted with the composition is from 0.1 to 100 parts by mass with respect to 1 part by mass of the composition.

2. The method according to claim 1 , wherein the at least one compound is selected from a group consisting of 3-methoxy-3-methyl-1-butanol, diethylene glycol, propylene glycol, glycerin and 2-(2-methoxyethoxy)ethanol.

3. The method according to claim 1 , wherein the at least one compound is 3-methoxy-3-methyl-1-butanol.

4. The method according to claim 1 , wherein the composition is a resist remover that has been used to wash and remove an unnecessary resist film in photolithography.

5. The method according to claim 1 , wherein the composition further comprises a quaternary ammonium hydroxide, a resist component, or both.

6. The method according to claim 5 , wherein the composition further comprises at least one other component selected from a group consisting of water, alkanolamines, amino acids, surfactants, and antifoaming agents.

7. The method according to claim 1 , wherein the distillation is performed such that the purified dimethyl sulfoxide product has a purity of 99.9%.

8. The method according to claim 1 , wherein a purity of the purified dimethyl sulfoxide product obtained by the distillation is higher than a purity of a dimethyl sulfoxide product obtained by distilling the composition without contacting with water.

9. The method according to claim 1 , wherein the distillation is performed at a temperature of from 104 to 250° C.

Assignees

• Kuraray Co

Inventors

• Mayahara Kunio
• Tamura Koji
• Takeda Akinobu

Classifications

• B01D3/34

  with one or more auxiliary substances · CPC title

• C07C315/06 Primary

  Separation; Purification; Stabilisation; Use of additives · CPC title

• C07C317/04

  of an acyclic saturated carbon skeleton · CPC title

• B01D3/38 Primary

  Steam distillation · CPC title

• Y02W30/62

  Plastics recycling; Rubber recycling · CPC title