Scale control in phosphoric acid production and handling plants

Patent metadata

Field	Value
Publication number	US-11027998-B2
Application number	US-202016791300-A
Country	US
Kind code	B2
Filing date	Feb 14, 2020
Priority date	Apr 20, 2017
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

Disclosed herein are compositions and methods of mitigating scale in phosphoric acid and ammonium phosphate plants. Scale-mitigating compositions of the invention can be added to phosphoric acid before or during the concentration in the evaporator cycle of a phosphoric acid plant. The compositions retard the formation of scale on surfaces in contact with the phosphoric acid, and thus time between cleaning is extended and plant productivity increased. Further, the scale that forms is softer and more easily cleaned from surfaces, reducing non-operation time of the plant and/or evaporator. Methods of mitigating scale formation in phosphoric acid production and phosphoric acid handling plants are disclosed. In the methods, scales accumulate more slowly and are softer, more tractable, and more easily cleaned from surfaces to which they adhere.

First claim

What is claimed is:

1. A method comprising:
adding to a first phosphatic composition an aqueous scale-mitigating composition comprising
5% to 15% by weight of a polyamino polyether methylene tetraphosphonate,
1% to 50% by weight of a copolymer of acrylic acid and 2-acrylamido-2-methylpropane sulfonic acid,
2% to 15% by weight of a copolymer of acrylic acid and a hydroxypolyethoxy allyl ether, and water,

to form a second phosphatic composition,
wherein the first phosphatic composition comprises phosphoric acid and calcium sulfate.

2. The method of claim 1 , wherein the aqueous scale-mitigating composition comprises 2% to 30% by weight of the copolymer of acrylic acid and 2-acrylamido-2-methylpropane sulfonic acid.

3. The method of claim 1 , wherein the aqueous scale-mitigating composition comprises 2% to 15% by weight of the copolymer of acrylic acid and 2-acrylamido-2-methylpropane sulfonic acid.

4. The method of claim 1 , wherein the aqueous scale-mitigating composition comprises 3% to 20% by weight of the copolymer of acrylic acid and 2-acrylamido-2-methylpropane sulfonic acid.

5. The method of claim 1 , the method further comprising forming the first phosphatic composition by
combining a phosphate ore and sulfuric acid to form a phosphate reaction mixture;
maintaining the phosphate reaction mixture at 65° C. to 120° C. for 30 minutes to five hours to form a crude phosphoric acid; and
filtering the crude phosphoric acid to remove insoluble material and provide the first phosphatic composition.

6. The method of claim 5 , wherein the phosphate ore comprises an apatite.

7. The method of claim 6 , wherein the apatite is a fluorapatite, a hydroxylapatite, a chlorapatite, or any combination thereof.

8. The method of claim 1 , the method further comprising disposing the second phosphatic composition in a containment, and heating the second phosphatic composition to a temperature of about 50° C. to about 110° C.

9. The method of claim 1 , the method further comprising disposing the second phosphatic composition in a containment, and applying a pressure of about 0.01 atmospheres to about 0.9 atmospheres to the second phosphatic composition in the containment.

10. The method of claim 1 , wherein the aqueous scale-mitigating composition has a concentration of about 10% to about 50% solids by weight.

11. The method of claim 1 , wherein the second phosphatic composition comprises about 5 parts by weight to about 2000 parts by weight of the aqueous scale-mitigating composition to one million parts by weight of the first phosphatic composition.

12. A scale-mitigating composition comprising:
5% to 15% by weight of a polyamino polyether methylene tetraphosphonate;
1% to 50% by weight of a copolymer of acrylic acid and 2-acrylamido-2-methylpropane sulfonic acid;
2% to 15% by weight of a copolymer of acrylic acid and hydroxypolyethoxy allyl ether;
and water.

13. The scale-mitigating composition of claim 12 , the composition comprising 2% to 30% by weight of the copolymer of acrylic acid and 2-acrylamido-2-methylpropane sulfonic acid.

14. The scale-mitigating composition of claim 12 , the composition comprising 2% to 15% by weight of the copolymer of acrylic acid and 2-acrylamido-2-methylpropane sulfonic acid.

15. The scale-mitigating composition of claim 12 , the composition comprising 3% to 20% by weight of the copolymer of acrylic acid and 2-acrylamido-2-methylpropane sulfonic acid.

16. The scale-mitigating composition of claim 12 , the composition further comprising 1% to 10% by weight of poly(methacrylic acid).

17. The scale-mitigating composition of claim 12 , the composition further comprising a tetrapolymer of acrylic acid, 2-acrylamido-2-methylpropane sulfonic acid, N-(t-butyl)acrylamide, and itaconic acid.

18. The scale-mitigating composition of claim 12 , wherein a percent solids by weight of the aqueous scale-mitigating composition is from 10% to 50%.

19. The scale-mitigating composition of claim 12 , wherein the scale-mitigating composition consists essentially of the polyamino polyether methylene tetraphosphonate, the copolymer of acrylic acid and 2-acrylamido-2-methylpropane sulfonic acid, the copolymer of acrylic acid and hydroxypolyethoxy allyl ether, and water.

Assignees

• Ecolab Usa Inc

Inventors

• Bhattacharja Sankar
• Gill Jasbir
• Jin Yuhuan
• Wiatr Paul

Classifications

• C23F14/02

  by chemical means · CPC title

• C02F5/14

  containing phosphorus · CPC title

• C02F5/10 Primary

  using organic substances · CPC title

• C01B25/32

  Phosphates of magnesium, calcium, strontium, or barium · CPC title

• C01B25/222 Primary

  with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen · CPC title