Method to make phosphoric acid and ammonium phosphates from phosphate minerals

Patent metadata

Field	Value
Publication number	US-11027975-B2
Application number	US-202016778474-A
Country	US
Kind code	B2
Filing date	Jan 31, 2020
Priority date	Jan 31, 2019
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

A method of producing phosphoric acid from at least one mineral containing phosphate and an element which is calcium, magnesium, iron, or aluminum. The method includes contacting the at least one mineral (or a combination of them) with a cation exchanger for a time and at a temperature sufficient to yield phosphoric acid from the mineral.

First claim

What is claimed is:

1. A method of producing phosphoric acid comprising:
contacting at least one mineral with a cation exchanger for a time and at a temperature sufficient to yield phosphoric acid from the mineral, wherein the mineral comprises phosphate and at least one element selected from the group consisting of calcium, magnesium, iron, and aluminum, and wherein the mineral requires from 30 to 1000 mass parts of water of pH 7.0 to one mass part of the mineral to dissolve the mineral and has increased solubility in acidic water having a pH range from about 2.0 to less than 7.0.

2. The method of claim 1 , wherein the cation exchanger comprises a solid substrate functionalized with a cation exchange moiety selected from the group consisting of carboxylic acid, sulfonic acid, phosphonic acid, carboxyalkyl, sulfoalkyl, phosphoalkyl, sulfoxyalkyl, and orthophosphate.

3. The method of claim 1 , comprising contacting with the cation exchanger at least one mineral selected from the group consisting of brushite (CaHPO 4 .2H 2 O), struvite (NH 4 MgPO 4 .6H 2 O), monetite (CaHPO 4 ), octacalcium phosphate (Ca 4 H(PO 4 ) 3 .2½H 2 O), newberryite (MgHPO 4 .3H 2 O), bobierrite (Mg 3 (PO 4 ) 2 .8H 2 O), strengite (FePO 4 .2H 2 O), vivianite (Fe 3 (PO 4 ) 2 .8H 2 O), variscite (AlPO 4 .2H 2 O), berlinite (AlPO 4 ), and amorphous, noncrystalline phosphate residuals recovered from wastewater treatment.

4. The method of claim 3 , wherein the cation exchanger comprises a solid substrate functionalized with a cation exchange moiety selected from the group consisting of carboxylic acid, sulfonic acid, phosphonic acid, carboxyalkyl, sulfoalkyl, phosphoalkyl, sulfoxyalkyl, and orthophosphate.

5. The method of claim 1 , comprising contacting brushite with the cation exchanger.

6. The method of claim 5 , wherein the cation exchanger comprises a solid substrate functionalized with a cation exchange moiety selected from the group consisting of carboxylic acid, sulfonic acid, phosphonic acid, carboxyalkyl, sulfoalkyl, phosphoalkyl, sulfoxyalkyl, and orthophosphate.

7. The method of claim 1 , comprising contacting struvite with the cation exchanger.

8. The method of claim 7 , wherein the cation exchanger comprises a solid substrate functionalized with a cation exchange moiety selected from the group consisting of carboxylic acid, sulfonic acid, phosphonic acid, carboxyalkyl, sulfoalkyl, phosphoalkyl, sulfoxyalkyl, and orthophosphate.

9. The method of claim 1 , wherein the at least one mineral is isolated from a water stream.

10. The method of claim 1 , wherein the cation exchanger is acid-charged.

11. A method of producing phosphoric acid comprising:
(a) isolating from a water stream at least one mineral, wherein the mineral comprises phosphate and at least one element selected from the group consisting of calcium, magnesium, iron, and aluminum, and wherein the mineral requires from 30 to 1000 mass parts of water of pH 7.0 to one mass part of the mineral to dissolve the mineral and has increased solubility in acidic water having a pH range from about 2.0 to less than 7.0; and
(b) contacting the at least one mineral with a cation exchanger for a time and at a temperature sufficient to yield phosphoric acid from the mineral.

12. The method of claim 11 , wherein the cation exchanger of step (b) comprises a solid substrate functionalized with a cation exchange moiety selected from the group consisting of carboxylic acid, sulfonic acid, phosphonic acid, carboxyalkyl, sulfoalkyl, phosphoalkyl, sulfoxyalkyl, and orthophosphate.

13. The method of claim 11 , wherein step (b) comprises contacting with the cation exchanger at least one mineral selected from the group consisting of brushite (CaHPO 4 .2H 2 O), struvite (NH 4 MgPO 4 .6H 2 O), monetite (CaHPO 4 ), octacalcium phosphate (Ca 4 H(PO 4 ) 3 .2½H 2 O), newberryite (MgHPO 4 .3H 2 O), bobierrite (Mg 3 (PO 4 ) 2 .8H 2 O), strengite (FePO 4 .2H 2 O), vivianite (Fe 3 (PO 4 ) 2 .8H 2 O), variscite (AlPO 4 .2H 2 O), berlinite (AlPO 4 ), and amorphous, noncrystalline phosphate residuals recovered from wastewater treatment.

14. The method of claim 13 , wherein the cation exchanger of step (b) comprises a solid substrate functionalized with a cation exchange moiety selected from the group consisting of carboxylic acid, sulfonic acid, phosphonic acid, carboxyalkyl, sulfoalkyl, phosphoalkyl, sulfoxyalkyl, and orthophosphate.

15. The method of claim 11 , wherein step (b) comprises contacting brushite with the cation exchanger.

16. The method of claim 15 , wherein the cation exchanger of step (b) comprises a solid substrate functionalized with a cation exchange moiety selected from the group consisting of carboxylic acid, sulfonic acid, phosphonic acid, carboxyalkyl, sulfoalkyl, phosphoalkyl, sulfoxyalkyl, and orthophosphate.

17. The method of claim 11 , wherein step (b) comprises contacting struvite with the cation exchanger.

18. The method of claim 17 , wherein the cation exchanger of step (b) comprises a solid substrate functionalized with a cation exchange moiety selected from the group consisting of carboxylic acid, sulfonic acid, phosphonic acid, carboxyalkyl, sulfoalkyl, phosphoalkyl, sulfoxyalkyl, and orthophosphate.

19. The method of claim 11 , wherein step (a) comprises isolating the at least one mineral from a waste-water stream.

20. The method of claim 11 , wherein the cation exchanger is acid-charged.

Assignees

• Wisconsin Alumni Res Found

Inventors

• Barak Phillip Warren

Classifications

• C01B25/28

  Ammonium phosphates · CPC title

• C05B7/00

  Fertilisers based essentially on alkali or ammonium orthophosphates (C05B11/00 takes precedence) · CPC title

• C01B25/321

  Methods for converting an alkaline earth metal ortho-phosphate into another ortho-phosphate (by reaction, e.g. of phosphate rock with phosphoric acid C01B25/322) · CPC title

• B01J39/16

  Organic material · CPC title

• C01B25/185 Primary

  Preparation neither from elemental phosphorus or phosphoric anhydride nor by reacting phosphate-containing material with an acid, e.g. by reacting phosphate-containing material with an ion-exchange resin or an acid salt used alone · CPC title