Process comprising exothermal catalytic reaction of a synthesis gas and related plant

Patent metadata

Field	Value
Publication number	US-11027972-B2
Application number	US-201816482553-A
Country	US
Kind code	B2
Filing date	Jan 31, 2018
Priority date	Feb 14, 2017
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

A synthesis process comprising steam reforming a gaseous hydrocarbon feedstock; exothermically reacting the resulting synthesis gas; removing heat from said exothermal reaction by producing steam; using said steam as heat input to the steam reforming, wherein the steam reforming comprises: a) forming a mixture containing steam and hydrocarbons by at least the step of adding a first stream of water to the hydrocarbon feedstock; b) heating said mixture by indirect heat exchange with synthesis gas; c) reforming said mixture after said heating step b).

First claim

The invention claimed is:

1. A synthesis process, comprising:
steam reforming a gaseous hydrocarbon feedstock, thereby obtaining a synthesis gas;
exothermically reacting said synthesis gas in the presence of a catalyst, thereby obtaining a synthesis product;
removing heat from said exothermal reaction by producing steam, wherein at least part of said steam provides a heat input to the reforming of said hydrocarbon feedstock;
wherein the steam reforming of the hydrocarbon feedstock includes:
a) forming a mixture containing steam and hydrocarbons by at least a step of adding a first stream of water to the hydrocarbon feedstock in a saturating tower, said stream of water being pre-heated by indirect heat exchange, prior to admission into said tower, with at least a portion of the steam produced by removing heat from the exothermal synthesis reaction;
b) heating said mixture by indirect heat exchange with at least part of said synthesis gas; and
c) reforming said mixture after said heating step b).

2. The synthesis process of claim 1 , wherein the formation of said mixture further includes mixing an effluent of said tower with a second stream of water, and said second stream is pre-heated by indirect heat exchange with said synthesis gas.

3. The synthesis process of claim 2 , wherein a stream of synthesis gas transfers heat to said mixture during the heating step b), and the synthesis gas effluent of said heating step b) transfers heat to said second stream of water.

4. The synthesis process of claim 1 , wherein excess water is drawn off from the saturating tower during said step a) and at least a portion of said excess water is recirculated into the tower, said portion being pre-heated, prior to admission into said tower, with a portion of the steam produced by removing heat from the exothermal synthesis reaction.

5. The synthesis process of claim 2 , wherein excess water is drawn off from the tower during said step a) and said second stream of water includes a portion of said excess water.

6. The synthesis process of claim 1 , wherein excess water is drawn off from the step b) and at least a portion of said excess water is added to the hydrocarbon feedstock in said saturating tower.

7. The synthesis process of claim 1 , wherein said synthesis product includes methanol.

8. The synthesis process of claim 7 , wherein the step of reacting the synthesis gas includes an isothermal reactive step, providing a methanol-containing stream, and wherein a stream of boiling water acts as cooling medium that removes heat of the exothermic reaction of the synthesis gas and generates said steam.

9. The synthesis process of claim 8 , wherein said step of reacting the synthesis gas further includes subjecting said methanol-containing stream to a further isothermal reactive step, providing said methanol product, and wherein a stream of fresh synthesis gas acts as cooling medium.

Assignees

• Casale Sa

Inventors

• Moreo Pietro
• Sassi Fabio

Classifications

• C01B3/38 Primary

  using catalysts · CPC title

• C07C29/151

  with hydrogen or hydrogen-containing gases · CPC title

• C01B2203/1276

  Mixing of different feed components · CPC title

• C01B2203/1294

  Evaporation by heat exchange with hot process stream · CPC title

• C01B2203/0244

  the reforming step being an autothermal reforming step, e.g. secondary reforming processes · CPC title