Process for producing foam molded parts with aesthetic surfaces by foam injection molding

Patent metadata

Field	Value
Publication number	US-11027466-B2
Application number	US-201616061922-A
Country	US
Kind code	B2
Filing date	Dec 13, 2016
Priority date	Dec 17, 2015
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

The invention relates to a process for producing a foam molded part, wherein a foamable material S comprising a thermoplastic polymer matrix M and at least one foaming agent F is foamed by foam injection molding. The polymer matrix M is preferably based on at least one thermoplastic styrene copolymer, such as ABS and ASA, and wherein the at least one foaming agent F is selected from chemical foaming agents, releasing carbon dioxide, and physical foaming agents, being carbon dioxide or nitrogen.

First claim

The invention claimed is:

1. A process for producing a foam molded part by foam injection molding, which comprises the following steps:
a) providing a melt of a foamable material S comprising a thermoplastic polymer matrix M and at least one foaming agent F selected from chemical foaming agents releasing carbon dioxide and physical foaming agents selected from nitrogen and carbon dioxide,
wherein the thermoplastic polymer matrix M comprises at least one thermoplastic styrene copolymer P consisting of, based on P:
1.1 5-95% by weight of a copolymer A consisting of, based on A:
1.1.1 70-76% by weight, of one or more vinyl aromatic monomer(s) A1 selected from styrene and substituted styrenes,
1.1.2 24-30% by weight, of one or more vinyl cyanide monomer(s) A2 selected from acrylonitrile, methacrylonitrile, or mixtures thereof, and
1.1.3 0-6% by weight, of one or more unsaturated copolymerizable monomers A3,

1.2 5-60% by weight of a graft rubber B consisting of, based on B:
1.2.1 10-95% by weight of a graft base B1 comprising, based on B1:
1.2.1.1 80-100% by weight of one or more rubber type monomer(s) B11 selected from butadiene, isoprene, and C 1 -C 10 alkyl acrylates, and
1.2.1.2 0-20% by weight of one or more polyfunctional crosslinking monomer(s) B12, and

1.2.2 5-90% by weight of a graft shell B2 comprising, based on B2:
1.2.2.1 75-85% by weight of one or more vinyl aromatic monomer(s) B21 selected from styrene and substituted styrenes,
1.2.2.2 15-25% by weight of one or more vinyl cyanide monomer(s) B22 selected from acrylonitrile, methacrylonitrile, or mixtures thereof, and
1.2.2.3 0-10% by weight of one or more unsaturated copolymerizable monomers B23;

b) filling a mold cavity K with the melt of the foamable material S by injection;
c) foaming the foamable material S in the mold cavity K by reduction of pressure and/or increase in temperature;
d) taking out the foam molded part; and
e) optionally further working of the foam molded part;

wherein the melt temperature shortly before or during injection of the melt into the mold cavity in step b) is in the range of 255° C. to 300° C., and wherein the mold temperature in step b) is in the range of 50° C. to 150° C., and
wherein filling of the mold cavity K with the melt of the foamable material S by injection in step b) is carried out with an injection speed in the range of 100 to 200 ccm/s.

2. The process according to claim 1 , wherein the foamable material S comprises as further additive one or more additives selected from fillers, plasticizers, impact modifiers, dyes, pigments, colorants, flame retardants, antistatic agents, mold-release agents, antioxidants, stabilizers, and lubricants.

3. The process according to claim 1 , wherein the vinyl aromatic monomer(s) A1 and/or B21 are selected from styrene, substituted styrenes of the formula I:

wherein:
R is C 1 -C 8 -alkyl or hydrogen,
R 1 is C 1 -C 8 -alkyl or hydrogen,
with the provision that not both R and R 1 are hydrogen, and
n is 1, 2, or 3,

and mixtures of these compounds.

4. The process according to claim 1 , wherein the thermoplastic polymer matrix M consists of a blend of at least one thermoplastic styrene copolymer P and at least one further polymer selected from polycarbonates and polyamides.

5. The process according to claim 1 , wherein the foamable material S comprises at least 0.1% by weight, based on the foamable material S, of a chemical foaming agent comprising bicarbonate and citric acid as sole foaming agent.

6. The process according to claim 1 , wherein the melt temperature shortly before or during injection of the melt into the mold cavity in step b) is equal or higher than 270° C., and wherein the mold temperature in step b) is equal or higher than 70° C.

7. The process according to claim 1 , wherein the melt temperature shortly before or during injection of the melt into the mold cavity in step b) is in the range of 265° C. to 290° C., and wherein the mold temperature in step b) is in the range of 50° C. to 100° C.

8. The process according to claim 1 , wherein filing of the mold cavity K with the melt of the foamable material S by injection in step b) is carried out with an injection speed in the range of 150 to 180 ccm/s.

9. The process according to claim 1 , wherein the mold cavity K exhibits a polished surface or a grained surface having grain domains of at least 10 μm.

10. The process according to claim 1 , wherein the thermoplastic polymer matrix M consists of at least one polymer selected from acrylonitrile-butadiene-styrene copolymers, acrylonitrile-styrene-acrylate copolymers, and blends of said styrene copolymers with at least one polyamide.

11. The process according to claim 1 , wherein the foaming in step c) is carried out by reduction of pressure and wherein the reduction of pressure and the foaming is performed together with the injection step b).

12. The process according to claim 1 , wherein the foaming of the foamable material S in step c) results in a density reduction in the range of 5 to 20%.

13. The process according to claim 1 , wherein the thermoplastic polymer matrix M consists of acrylonitrile-butadiene-styrene copolymers, acrylonitrile-styrene-acrylate copolymers, or blends of acrylonitrile-butadiene-styrene copolymer and at least one polyamide, wherein the melt temperature shortly before or during injection of the melt into the mold cavity in step b) is in the range of 265° C. to 290° C.; wherein the mold temperature in step b) is in the range of 70 to 90° C.; and wherein the foaming of the foamable material S in step c) results in a density reduction in the range of 7 to 18%.

Assignees

• Ineos Styrolution Group Gmbh

Inventors

• Raithel Bastian
• Niessner Norbert
• Bernhardt Achim
• Roettel Stefan
• Juan Pierre
• Popp Andreas

Classifications

• C08J9/08

  developing carbon dioxide · CPC title

• C08L55/02

  ABS [Acrylonitrile-Butadiene-Styrene] polymers · CPC title

• C08J2203/02

  CO2-releasing, e.g. NaHCO3 and citric acid · CPC title

• B29C44/42

  using pressure difference, e.g. by injection or by vacuum · CPC title

• B29C44/3446 Primary

  Feeding the blowing agent · CPC title