Transparently coated polycarbonate component, its production and use

Patent metadata

Field	Value
Publication number	US-11027312-B2
Application number	US-201716469394-A
Country	US
Kind code	B2
Filing date	Dec 13, 2017
Priority date	Dec 15, 2016
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

The present invention relates to a multilayer construction containing a support or frame composed of a nontransparent polymer as layer c) and a transparent layer b) based on a thermoplastic polymer having a solar transmittance TDS of more than 20%, determined in accordance with ISO 13837:2008 at a layer thickness of 4 mm, and a siloxane-based protective layer a) which is applied to layer c) and layer b), wherein the siloxane layer a) is selectively postcured in selected regions by means of ultrashort-wave UV radiation, and to a method for selective surface treatment.

First claim

The invention claimed is:

1. A multilayer construction, comprising:
a) a siloxane-based protective layer;
b) a transparent layer based on a thermoplastic polymer having a first surface and an opposing second surface, wherein the siloxane-based protective layer is disposed on the first surface; and
c) a carrier or frame layer of a nontransparent polymer, disposed on and covering only a portion of the second surface, with a remaining portion not covered forming in plan view a region of the transparent layer having a solar transmittance T DS of greater than 20% (determined according to ISO 13837:2008 at a layer thickness of 4 mm),
wherein the siloxane-based protective layer is post-cured using ultrashortwave UV radiation only in the region where the solar transmittance is greater than 20%, not overlapping with the carrier or frame in plan view.

2. The multilayer construction as claimed in claim 1 , wherein the transparent layer is transparent in the visible wavelength range, meaning a light transmission of at least 80% (determined according to ASTM 1003:2011/ISO 13468:2006; reported in % and with illuminant D65/10°).

3. The multilayer construction as claimed in claim 1 , wherein the transparent layer is transparent in the IR wavelength range meaning an average transmittance of at least 10% in the range between 750 nm and 2500 nm (determined according to ISO 13468-2:2006) and a light transmission less than 1% in the range between 380 nm and 780 nm (determined according to ISO 13468:2006, with illuminant D65/10°).

4. The multilayer construction as claimed in claim 1 , wherein the thermoplastic polymer of the transparent layer is selected from at least one of the group consisting of polycarbonate, copolycarbonate, polyester carbonate, polystyrene, styrene copolymers, aromatic polyesters, polyethylene terephthalate, PET-cyclohexanedimethanol copolymer, polyethylene naphthalate, polybutylene terephthalate, polyamide, cyclic polyolefin, poly- or copolyacrylate, poly- or copolymethacrylate, poly- or copolymethyl methacrylate, polystyrene-acrylonitrile copolymer, and thermoplastic polyurethane.

5. The multilayer construction as claimed in claim 4 , wherein the thermoplastic polymer of wherein the thermoplastic polymers of the transparent layer is selected from group consisting of polycarbonate, copolycarbonate, polyester carbonate, aromatic polyesters, and polymethylmethylacrylate.

6. The multilayer construction as claimed in claim 5 , wherein the thermoplastic polymer of the transparent layer is polycarbonate.

7. The multilayer construction as claimed in claim 1 , wherein the haze value of the transparent layer is less than 3% (measured according to ASTM 1003:2011).

8. The multilayer construction as claimed in claim 1 , wherein the carrier or frame is along at least a portion of the peripheral edge of the second surface of the transparent layer.

9. The multilayer construction as claimed in claim 8 , wherein the nontransparent polymer is a black polymer blend.

10. The multilayer construction as claimed in claim 9 , wherein the black polymer blend is a polycarbonate blend.

11. The multilayer construction as claimed in claim 10 , wherein the solar transmittance T DS of carrier or frame is less than 1%.

12. The multilayer construction as claimed in claim 1 , wherein the ultrashortwave UV radiation comprises a radiation dose of 200 to 2100 mJ/cm 2 .

13. The multilayer construction as claimed in claim 1 , wherein the siloxane-based layer contains organosilicon compounds of formula:
R n SiX 4-n ,  (I)

and/or partial condensates thereof,
wherein R is identical or different and represents a linear or branched, saturated or mono- or polyunsaturated or aromatic hydrocarbon X is identical or different and represents hydrolyzable groups or hydroxyl groups, and n is 0, 1, 2, or 3.

14. The multilayer construction as claimed in claim 13 , wherein in formula (I) R represents saturated, branched or unbranched alkyl radicals having 1 to 20 carbon atoms and/or represents mono- or polyunsaturated branched or unbranched alkenyl radicals having 2 to 20 carbon atoms or aromatic groups having 6 to 12 carbon atoms,
X represents a C1- to C4-alkoxy group and n is 1 or 2.

15. The multilayer construction as claimed in claim 1 , wherein the protective layer comprises a topcoat layer a primer layer, wherein the primer layer is arranged between the topcoat layer and the transparent layer.

16. The multilayer construction as claimed in claim 15 , wherein the topcoat layer comprises a polysiloxane-based topcoat comprising:
i. at least one UV-absorber selected from the group consisting of benzophones, resorcinols, 2-(2-hydroxyphenol)benzotriazoles, hydroxphenyl-s-triazines, cyanoacrylates, and oxalanilides,

and optionally a UV-inhibitor from the group of sterically hindered amines; and
ii. at least one combination of an organomodified silane with a silica sol.

17. A process for making the multilayer construction as claimed in claim 1 , wherein the transparent layer and carrier or frame are formed by a two-component injection molding process.

18. A process for treating the siloxane-based protective layer of the multilayer construction as claimed in claim 1 , wherein ultrashortwave UV radiation is generated via excimer lamp or excimer laser.

19. A process for surface treating a multilayer construction, wherein the multilayer construction comprises:
a) a siloxane-based protective layer;
b) a transparent layer based on a thermoplastic polymer having a first surface and an opposing second surface, wherein the siloxane-based protective layer is disposed on the first surface; and
c) a carrier or frame layer of a nontransparent polymer, disposed on and covering only a portion of the second surface, with a remaining portion not covered forming in plan view a region of the transparent layer having a solar transmittance T DS of greater than 20% (determined according to ISO 13837:2008 at a layer thickness of 4 mm),
wherein the step of surface treating comprises post-curing the siloxane-based protective layer using ultrashortwave UV radiation only in the region where the solar transmittance is greater than 20%, not overlapping with the carrier or frame in plan view.

20. The process for surface treating a multilayer construction as claimed in claim 19 , wherein the ultrashortwave UV radiation dose is in the range of 700 to 1400 mJ/cm 2 , generated by an excimer lamp or laser.

Assignees

• Covestro Deutschland Ag

Inventors

• Hinzmann Dirk
• Kuhlmann Timo
• Capellen Peter

Classifications

• C09D183/04

  Polysiloxanes · CPC title

• C09D7/62

  modified by treatment with other compounds · CPC title

• C09D5/002

  Priming paints (C09D5/08 takes precedence) · CPC title

• C08J2369/00

  Characterised by the use of polycarbonates; Derivatives of polycarbonates · CPC title

• C08J7/123

  Treatment by wave energy or particle radiation (C08J7/18 takes precedence) · CPC title