Integrated process and unit operation for conditioning a soot-containing syngas

Patent metadata

Field	Value
Publication number	US-11021667-B2
Application number	US-202017004641-A
Country	US
Kind code	B2
Filing date	Aug 27, 2020
Priority date	Aug 16, 2017
Publication date	Jun 1, 2021
Grant date	Jun 1, 2021

Abstract

The present invention relates to a method for conditioning a soot-containing syngas stream in a single integrated apparatus containing a scrubbing vessel wherein particulate matter is decoupled from the waste water stream.

First claim

What is claimed is:

1. An integrated apparatus for conditioning a soot-containing synthesis gas stream, comprising:
(a) a quenching device, wherein a raw soot-containing synthesis gas having particulate matter and gaseous contaminants having a temperature of less than 900° F. is introduced and the temperature of the soot-containing synthesis gas is reduced to a temperature ranging from 250-400° F. thereby forming a two-phase stream;
(b) a first scrubbing device for receiving the cooled two-phase stream, wherein said device is selected from the group of Venturi scrubbers, Venturi tubes, orifice plate, atomizers;
(c) a second scrubbing device for receiving the two-phase stream where it is separated into a liquid-phase fluid contaminated with particulate matter and a gas-phase fluid having water-soluble contaminants at a lower section of the second scrubbing device;
(d) a spray nozzle device disposed in an upper section of the second scrubbing device to clean the gas phase fluid by bringing said gas phase fluid in direct contact with cooled process water dispensed through said spray nozzle device, thereby reducing the temperature of the gas phase fluid below the dew temperature and removing the water-soluble contaminants therefrom, wherein a second line and associated pump route a portion of the liquid-phase fluid contaminated with particulate matter to a filtration system where substantially all of the particulate matter is removed thereby forming a clean process water stream which is routed through a heat exchanger and the temperature is cooled to a temperature ranging from ambient to about 150° F. forming said cooled process water which is sent to the spray nozzle device;
(e) a mist eliminating device above the spray nozzle device in the upper section of the second scrubbing device for the removal of substantially all of the remaining entrained water droplets in the gas phase fluid rising to the top of the second scrubbing device thereby producing a cooled and substantially soot free synthesis gas stream.

2. The integrated apparatus of claim 1 , further comprising a second spray nozzle device dedicated to clean the mist eliminating device.

3. The integrated apparatus of claim 1 , further comprising at least a first line and associated pump for the removal of the liquid-phase fluid contaminated with particulate matter from the lower section of the second scrubbing device.

4. The integrated apparatus of claim 3 , wherein said at least first line and associated pump recycles at least a portion of the liquid-phase fluid contaminated with particulate matter to said quenching device.

5. The integrated apparatus of claim 2 , further comprising directing a portion of the clean process water stream to said second spray nozzle device in order to clean the mist eliminating device.

6. The integrated apparatus of claim 2 , further comprising a heat exchanger disposed downstream of the pump to cool liquid-phase fluid contaminated with particulate matter to a temperature of about 150° F., and splitting the stream into at least three portions, wherein one portion is directed to the quenching device, a second portion is directed to a filtration system, and a third portion is directed to the first and/or second spray nozzle device disposed in the scrubbing device.

7. The integrated apparatus of claim 3 , further comprising a physical separation device disposed above an entry point of a two-phase synthesis fluid stream in the second scrubbing device to separate the liquid-phase fluid contaminated with particulate matter from predominantly clean water in the top portion of the second scrubbing device.

8. The integrated apparatus of claim 3 , further comprising introducing a portion of the liquid-phase fluid contaminated with particulate matter to said first scrubbing device.

Assignees

• Coleman Luke
• Shah Minish Mahendra
• Schwartz Joseph
• Jankowiak Jerome
• Praxair Technology Inc

Inventors

• Coleman Luke
• Shah Minish Mahendra
• Schwartz Joseph
• Jankowiak Jerome

Classifications

• B01D47/06 Primary

  Spray cleaning · CPC title

• C10L3/08 Primary

  Production of synthetic natural gas · CPC title

• C10K1/101

  with water only · CPC title

• B01D2247/04

  Regenerating the washing fluid · CPC title

• B01D2247/107

  using an unstructured demister, e.g. a wire mesh demister · CPC title