Stabilization and reduction of TCT of divalent iodide-containing brines

Patent metadata

Field	Value
Publication number	US-11021645-B2
Application number	US-201715791748-A
Country	US
Kind code	B2
Filing date	Oct 24, 2017
Priority date	Oct 24, 2017
Publication date	Jun 1, 2021
Grant date	Jun 1, 2021

Abstract

A composition for use in a wellbore activity, the composition comprising a stabilized divalent iodide brine, the stabilized divalent iodide brine comprises a divalent salt system, where the divalent salt system comprises a divalent iodide, an primary iodide stabilizer, the primary iodide stabilizer operable to remove free iodine, prevent the formation of free iodine, and suppress TCT, and an aqueous fluid, where the stabilized divalent iodide brine has a density greater than 11 lb/gal, where the stabilized divalent iodide brines has a TCT of less than or equal to 70 deg F.

First claim

What is claimed is:

1. A composition for use in a wellbore activity, the composition consisting essentially of:
a stabilized divalent iodide brine, the stabilized divalent iodide brine comprises:
a divalent salt system, the divalent salt system comprises a divalent iodide, wherein the divalent iodide is selected from the group consisting of calcium iodide, magnesium iodide, strontium iodide, and combinations of the same;
a primary iodide stabilizer, the primary iodide stabilizer operable to remove free iodine, prevent the formation of free iodine, and suppress true crystallization temperature (TCT), wherein the primary iodide stabilizer comprises a low molecular weight polyol selected from the group consisting of sorbitol, glycerol, xylitol, mannitol, diglycerol, polyethylene glycol with a molecular weight less than 1000 Da, and combinations of the same;
a secondary iodide stabilizer, the secondary iodide stabilizer operable to scavenge free oxygen or carbon dioxide and prevent oxidation of the iodide to iodine, the secondary iodide stabilizer selected from the group consisting of amines, amino alcohols, hydroxylamines, hydrazines, erythorbic acid and derivative erythorbate salts, ascorbic acid and derivative ascorbate salts, citric acid and derivative citrate salts, and combinations of the same;
and an aqueous fluid,
where the stabilized divalent iodide brine has a density greater than 11 lb/gal, and where the stabilized divalent iodide brine has a TCT of less than or equal to 70 deg F.

2. The composition of claim 1 , wherein the divalent iodide is present in the range between 1 wt % and 70 wt %, and further wherein the primary iodide stabilizer is present in the range between 0.1 wt % and 35 wt % of the stabilized divalent iodide brine.

3. The composition of claim 1 , wherein the secondary iodide stabilizer is present in the range between 0.001% v/v and 5% v/v.

4. The composition of claim 1 , where the secondary iodide stabilizer comprises an amine selected from the group consisting of ethylenediamine (EDA), diethylenetriamine (DETA), triethylenetetramine (TETA), tetraethylenepentamine (TEPA), pentaethylenehexamine (PEHA), aminoethylpiperazine (AEP), hexaethyleneheptamine (HEHA), piperazine, methoxypropylamine (MOPA), morpholine, n-aminopropylmorpholine (APM), and combinations of the same.

5. The composition of claim 1 , where the secondary iodide stabilizer comprises an amino alcohol selected from the group consisting of monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA), diethylaminoethanol (DEAE), dimethylethanolamine (DMEA), N-[3-aminopropyl]diethanolamine, aminoethylethanolamine (AEEA), 4-[2-hydroxyethyl]morpholine, diglycolamine, and combinations of the same.

6. The composition of claim 1 , where the secondary iodide stabilizer comprises an hydroxylamine selected from the group consisting of diethylhydroxylamine (DEHA), dimethylhydroxylamine (DMHA), hydroxylamine, and combinations of the same.

7. The composition of claim 1 , where the secondary iodide stabilizer comprises sodium erthyorbate.

8. The composition of claim 1 , where the secondary iodide stabilizer comprises a derivative ascorbate salt selected from the group consisting of sodium ascorbate, potassium ascorbate, magnesium ascorbate, calcium ascorbate and combinations of the same.

9. The composition of claim 1 , where the secondary iodide stabilizer comprises a derivative citrate salt selected from the group consisting of mono-, di-, and tri-sodium citrate, potassium citrate, magnesium citrate, calcium citrate, and combinations of the same.

10. The composition of claim 1 , where the secondary iodide stabilizer is selected form the group consisting of monoethanolamine (MEA), aminoethylethanolamine (AEEA), diethylhydroxylamine (DEHA), and combinations of the same.

11. The composition of claim 1 , wherein the divalent iodide is present in the range between 1 wt % and 70 wt %, and further wherein the primary iodide stabilizer is present in the range between 2 wt % and 25 wt % of the stabilized divalent iodide brine.

Assignees

• Tetra Tech

Inventors

• Mack Arthur G
• Fowler Drew A

Classifications

• E21B36/00

  Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones · CPC title

• C09K8/032 Primary

  Inorganic additives · CPC title

• C09K8/42

  Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells (compositions for plastering C09K8/50) · CPC title

• C09K8/528 Primary

  inorganic depositions, e.g. sulfates or carbonates · CPC title

• C09K8/06

  Clay-free compositions (containing inorganic compounds only C09K8/05) · CPC title