Steam reforming process

Patent metadata

Field	Value
Publication number	US-11021365-B2
Application number	US-201716333746-A
Country	US
Kind code	B2
Filing date	Aug 29, 2017
Priority date	Sep 19, 2016
Publication date	Jun 1, 2021
Grant date	Jun 1, 2021

Abstract

Steam reforming system having a steam cracker and a steam reformer. The steam cracker includes a steam cracking unit to steam crack a feed stream to produce a stream comprising hydrogen, methane and C2+ hydrocarbons; a heat exchanger for cooling the steam cracking product stream; a separation unit for separating the cooled steam cracking product stream into a gas stream including hydrogen and methane and a liquid stream including methane and C2+ hydrocarbons, a demethanizer which is fed the liquid stream producing a third stream containing at least 95% methane and a fourth stream comprising C2+ hydrocarbons. The steam reformer includes a feed preheater which is fed the third stream and steam to provide a preheated stream and a steam reforming unit arranged for heating the preheated stream to at least 800° C. to steam reforming the heated stream and obtain a product stream containing hydrogen and CO2.

First claim

The invention claimed is:

1. A steam reforming process using a steam reforming system comprising a steam cracker and a steam reformer,
wherein the steam cracker comprises:
i) a steam cracking unit arranged for steam cracking a steam cracking feed stream to produce a steam cracking product stream comprising hydrogen, methane, and C2+ hydrocarbons,
ii) a heat exchanger for cooling the steam cracking product stream to provide a cooled steam cracking product stream,
iii) a separation unit arranged for separating the cooled steam cracking product stream into a first, gas stream comprising hydrogen and methane and a second, liquid stream comprising methane and C2+ hydrocarbons,
iv) a demethanizer arranged for being fed at least with the second stream and producing a third stream comprising methane and a fourth stream comprising C2+ hydrocarbons, wherein the amount of methane in the third stream is at least 95 wt %; and the steam reformer comprises
v) a feed preheater arranged for being fed with the third stream and steam to provide a preheated stream, and
vi) a steam reforming unit arranged for heating the preheated stream to a temperature of 800° C. and steam reforming the heated stream to obtain a steam reforming product stream comprising both hydrogen and CO 2 , wherein the steam cracker further comprises a cryogenic separation unit for separating the first stream into a fifth, gas stream comprising hydrogen and a sixth, liquid stream comprising methane, wherein the demethanizer is arranged for further being fed with the sixth stream, wherein the process comprises the steps of:
a) steam cracking the steam cracking feed stream by the steam cracking unit to produce the steam cracking product stream,
b) cooling the steam cracking product stream by the heat exchanger to provide the cooled steam cracking product stream,
c) separating the cooled steam cracking product stream into the first stream and the second stream by the separation unit,
d) feeding at least the second stream to the demethanizer to produce the third stream and the fourth stream comprising C2+ hydrocarbons,
e) feeding the third stream and steam to the feed preheater to provide the preheated stream, and
f) heating the preheated stream to a temperature of 800° C. and steam reforming the heated stream by the steam reforming unit to obtain the steam reforming product stream;
g) feeding back the third stream from the demethanizer to the heat exchanger, to assist cooling of the steam cracking product stream, and
h) feeding back the fifth stream from the cryogenic separation unit to the heat exchanger, to assist cooling of the steam cracking product stream,
wherein the third stream comprises C2+ hydrocarbons at an amount of less than 0.5 wt %.

2. A steam reforming process using a steam reforming system comprising a steam cracker and a steam reformer,
wherein the steam cracker comprises:
i) a steam cracking unit arranged for steam cracking a steam cracking feed stream to produce a steam cracking product stream comprising hydrogen, methane, and C2+ hydrocarbons,
ii) a heat exchanger for cooling the steam cracking product stream to provide a cooled steam cracking product stream,
iii) a separation unit arranged for separating the cooled steam cracking product stream into a first, gas stream comprising hydrogen and methane and a second, liquid stream comprising methane and C2+ hydrocarbons,
iv) a demethanizer arranged for being fed at least with the second stream and producing a third stream comprising methane and a fourth stream comprising C2+ hydrocarbons, wherein the amount of methane in the third stream is at least 95 wt %; and the steam reformer comprises
v) a feed preheater arranged for being fed with the third stream and steam to provide a preheated stream, and
vi) a steam reforming unit arranged for heating the preheated stream to a temperature of 800° C. and steam reforming the heated stream to obtain a steam reforming product stream comprising both hydrogen and CO 2 , wherein the steam cracker further comprises a cryogenic separation unit for separating the first stream into a fifth, gas stream comprising hydrogen and a sixth, liquid stream comprising methane, wherein the demethanizer is arranged for further being fed with the sixth stream, the process consisting of the steps of a) steam cracking the steam cracking feed stream by the steam cracking unit to produce the steam cracking product stream, b) cooling the steam cracking product stream by the heat exchanger to provide the cooled steam cracking product stream, c) separating the cooled steam cracking product stream into the first stream and the second stream by the separation unit, d) feeding at least the second stream to the demethanizer to produce the third stream and the fourth stream comprising C2+ hydrocarbons, e) feeding the third stream and steam to the feed preheater to provide the preheated stream, and f) heating the preheated stream to a temperature of 800° C. and steam reforming the heated stream by the steam reforming unit to obtain the steam reforming product stream; g) feeding back the third stream from the demethanizer to the heat exchanger, to assist cooling of the steam cracking product stream, and h) feeding back the fifth stream from the cryogenic separation unit to the heat exchanger to assist cooling of the steam cracking product stream, wherein the third stream comprises C2+ hydrocarbons at an amount of less than 0.5 wt %.

Assignees

• Sabic Global Technologies Bv

Inventors

• Van Willigenburg Joris

Classifications

• C01B3/34 Primary

  by reaction of hydrocarbons with gasifying agents · CPC title

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title

• C01B2203/1241

  Natural gas or methane · CPC title

• C01B2203/046

  Purification by cryogenic separation · CPC title

• C01B2203/1205

  Composition of the feed · CPC title