Method for producing alcohol

Patent metadata

Field	Value
Publication number	US-11020685-B2
Application number	US-201916570117-A
Country	US
Kind code	B2
Filing date	Sep 13, 2019
Priority date	Mar 14, 2017
Publication date	Jun 1, 2021
Grant date	Jun 1, 2021

Abstract

The object is to provide a method for producing an alcohol by applying a multiple-effect method to improve the energy efficiency of the whole process. The object is achieved by a method for producing an alcohol including a concentration step of introducing a water-alcohol mixed solution into a multiple-effect distillation column for concentrating the same; a condensation step of introducing a vapor recovered from the top of the distillation column into a condenser for condensing the same; and a separation step of introducing the water-alcohol mixed solution condensed in the condensation step in a liquid phase into a membrane separation apparatus for separating the water and alcohol in the mixed solution.

First claim

What is claimed is:

1. A method for producing an alcohol comprising:
a concentration step of introducing a water-alcohol mixed solution into a multiple-effect distillation column to concentrate the water-alcohol mixed solution;
a condensation step of introducing a vapor recovered from the top of the multiple-effect distillation column into a condenser to condense the vapor totally, and
a separation step of introducing the water-alcohol mixed solution condensed in the condensation step in a liquid phase into a membrane separation apparatus to separate the water and alcohol in the mixed solution,
wherein the heat of condensation developed when the vapor recovered from the top of the distillation column is condensed in a condenser is utilized as a heat source for the concentration step.

2. The method for producing an alcohol according to claim wherein the multiple-effect distillation column comprises two distillation columns arranged in series.

3. The method for producing an alcohol according to claim 1 , wherein the multiple-effect distillation column comprises two distillation columns arranged in parallel.

4. The method for producing an alcohol according to claim 1 , wherein the multiple-effect distillation column comprises three distillation columns arranged in series.

5. The method for producing an alcohol according to claim 1 , wherein the multiple-effect distillation column comprises at least a crude distillation column placed on the upstream side of the process, and a rectifying column placed on the downstream side of the process; and the alcohol concentration of the distillate after concentration by the crude distillation column is from 40 to 60 wt %, and the alcohol concentration of the distillate after concentration by die rectifying column is from 80 to 95 wt %.

6. The method for producing an alcohol according to claim 1 , wherein the multiple-effect distillation column comprises at least a crude distillation column placed on the upstream side of the process, and a rectifying column placed on the downstream side of the process; and the reflux ratio of the crude distillation column is from 0 to 30, and the reflux ratio of the rectifying column is from 0.1 to 30.

7. The method for producing an alcohol according to claim 1 , wherein the membrane separation apparatus comprises a porous support-zeolite membrane complex, in which a zeolite membrane is placed on a porous support.

8. The method for producing an alcohol according to claim 7 , wherein the molar ratio of SiO 2 /Al 2 O 3 in a zeolite composing the zeolite membrane is 5 or more.

9. The method for producing an alcohol according to claim 8 , wherein the zeolite has an LTA structure.

10. The method for producing an alcohol according to claim 8 , Wherein a thickness of the zeolite membrane is in a range from 0.1 to 100 μm, and
wherein the zeolite is in the form of particles having a diameter equal to the thickness of the zeolite membrane.

11. The method for producing an alcohol according to claim 10 , wherein a thickness of the zeolite membrane is in a range from 0.1 to 10 μm.

12. The method for producing an alcohol according to claim 1 , wherein the alcohol is ethanol.

13. The method for producing an alcohol according to claim 1 , wherein the condensation ratio with respect to the total vapor fed into the condenser in terms of weight is 99% or more.

14. The method for producing an alcohol according to claim 1 , wherein the beat of condensation is utilized to generate low-pressure steam to provide the heat source.

Assignees

• Mitsubishi Chem Corp

Inventors

• Hidaka Hideto
• Sato Yohei

Classifications

• C07C29/76 Primary

  by physical treatment · CPC title

• B01D3/146 Primary

  Multiple effect distillation · CPC title

• C07C29/80

  by distillation · CPC title

• B01D3/145

  One step being separation by permeation · CPC title

• C07C29/78

  by condensation or crystallisation · CPC title