Photocatalyst, and method for producing photocatalyst
US-2015231606-A1 · Aug 20, 2015 · US
US11020323B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11020323-B2 |
| Application number | US-201615751597-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 12, 2016 |
| Priority date | Aug 12, 2015 |
| Publication date | Jun 1, 2021 |
| Grant date | Jun 1, 2021 |
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Aqueous solution of a transition and main group metal salt for use as conditioning agent in dental restoration therapy.
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The invention claimed is: 1. A conditioning agent for teeth comprising an aqueous solution which comprises 0.5 to 25 wt.-% of one or more transition and/or main group metal salts, wherein the transition and/or main group metal salt is a salt of Zr 4+ , Hf 4+ , Ti 4+ or Sn 4+ . 2. The conditioning agent according to claim 1 , wherein the transition or main group metal salt comprises as anion Cl − , Br − , I − , NO 3 − , SO 4 2− , optionally as mixed salts with oxoanions. 3. The conditioning agent according to claim 1 , which comprises as transition and/or main group metal salt ZrOCl 2 , ZrO(NO 3 ) 2 , Zr(SO 4 ) 2 , Hf(SO 4 ) 2 , HfCl 4 , Hf(NO 3 ) 4 , TiOSO 4 , SnCl 4 or a mixture of these salts. 4. The conditioning agent according to claim 1 , which additionally comprises a further metal salt which is selected from the salts of Cu 2+ , Zn 2+ , Al 3+ and mixtures thereof. 5. The conditioning agent according to claim 4 , which additionally comprises Al(NO 3 ) 3 , CuSO 4 , ZnSO 4 or a mixture thereof. 6. The conditioning agent according to claim 1 , wherein the metal ion is Zr 4+ , Hf 4 or Ti 4+ . 7. The conditioning agent according to claim 6 , wherein the transition or main group metal salt comprises as anion Cl − , Br − , I − , NO 3 − , SO 4 2 , optionally as mixed salts with oxoanions. 8. The conditioning agent according to claim 6 , which comprises as transition and/or main group metal salt ZrOCl 2 , ZrO(NO 3 ) 2 , Zr (SO 4 ) 2 , Hf(SO 4 ) 2 , HfCl 4 , Hf(NO 3 ) 4 , TiOSO 4 or a mixture of these salts. 9. The conditioning agent according to claim 6 , which additionally comprises a further metal salt which is selected from the salts of Cu 2+ , Zn 2+ , Al 3+ , Sn 4+ and mixtures thereof. 10. The conditioning agent according to claim 9 , which comprises as a further metal salt Al (NO 3 ) 3 , CuSO 4 , ZnSO 4 , SnCl 4 or a mixture thereof. 11. The conditioning agent according to claim 1 , which contains no added acid. 12. The conditioning agent according to claim 1 , which comprises 2 to 15 wt.-% transition and/or main group metal salt, 36 to 98 wt.-% water and 0 to 49 wt.-% organic solvent. 13. The conditioning agent according to claim 1 , which comprises as organic solvent glycerol, ethanol, ethylene glycol, propylene glycol, propanediol, butanediol and polyethylene glycol or a mixture thereof. 14. The conditioning agent according to claim 1 , which comprises 4 to 10 wt.-% transition and/or main group metal salt, 42 to 96 wt.-% water and 0 to 48 wt.-% organic solvent.
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