Selective plating of three dimensional surfaces to produce decorative and functional effects

Patent metadata

Field	Value
Publication number	US-11015255-B2
Application number	US-201816201092-A
Country	US
Kind code	B2
Filing date	Nov 27, 2018
Priority date	Nov 27, 2018
Publication date	May 25, 2021
Grant date	May 25, 2021

Abstract

A method of creating a selectively plated three-dimensional thermoplastic part. The method includes the steps of: a) providing a film of uncured polycarbonate film having a hardcoated layer on a first surface thereof; b) selectively catalyzing the polycarbonate film by depositing a catalyst in a desired pattern on the first surface of the polycarbonate film; c) thermoforming the polycarbonate film to form a three-dimensional polycarbonate film; d) UV-curing the hardcoated polycarbonate film by irradiating the film with UV rays; e) molding the hardcoated polycarbonate film to produce a three-dimensional molded part comprising the hardcoated polycarbonate film; f) activating the selectively catalyzed hardcoated polycarbonate film; and g) plating a metal layer on the catalyzed portions of the hardcoated polycarbonate film, wherein the plated metal only deposits on the catalyzed portions of the hardcoated polycarbonate film.

First claim

What is claimed is:

1. A method of creating a selectively plated three-dimensional thermoplastic part, the method comprising, in order, the steps of:
a) providing a film of uncured thermoplastic film, wherein the uncured thermoplastic film comprises a hardcoated layer on a first surface thereof;
b) selectively catalyzing the thermoplastic film by depositing a catalyst in a desired pattern on the first surface of the thermoplastic film;
c) thermoforming the thermoplastic film to form a three-dimensional thermoplastic film;
d) UV-catalyst the hardcoated thermoplastic film by irradiating the film with UV rays;
e) activating the selectively catalyzed hardcoated thermoplastic film; and
f) plating a metal layer on the catalyzed portions of the hardcoated thermoplastic film, wherein the metal layer only deposits on the catalyzed portions of the hardcoated thermoplastic film.

2. The method according to claim 1 , further comprising the step of applying an ink to a second surface of the thermoplastic film prior to step b).

3. The method according to claim 2 , wherein the ink is a colored ink that is applied by printing, and wherein the ink exhibits a desired color or pattern or finish on the second surface of the thermoplastic film.

4. The method according to claim 1 , further comprising the step of molding the hardcoated thermoplastic film to produce a three-dimensional molded part comprising the hardcoated thermoplastic film after step d).

5. The method according to claim 1 , wherein the thermoplastic film has a thickness of between about 50 microns and about 500 microns.

6. The method according to claim 5 , wherein the thermoplastic film has a thickness of between about 100 microns and about 300 microns.

7. The method according to claim 1 , wherein the step of plating the metal layer on the catalyzed portions of the hardcoated thermoplastic film comprises:
a) reducing the catalyst a) reducing the catalyst with a reducing agent;
b) electrolessly plating a seed layer of electroless metal on the catalyzed portions of the hardcoated thermoplastic film; and
c) electrolytically plating the metal layer over the top of the seed layer of electroless metal.

8. The method according to claim 7 , wherein the reducing agent comprises a hypophosphite salt or a borohydride salt.

9. The method according to claim 7 , wherein the electroless metal comprises copper, nickel, or nickel alloy.

10. The method according to claim 7 , wherein the metal layer of step (c) is selected from the group consisting of copper, copper alloy, zinc, zinc alloy, nickel, nickel alloy, iron, lead alloy, chromium, and combinations of one or more of the foregoing.

11. The method according to claim 1 , wherein the metal layer has a thickness of between about 10 microns and about 300 microns.

12. The method according to claim 11 , wherein the metal layer has a thickness of between about 30 microns and about 150 microns.

13. The method according to claim 1 , wherein the thermoplastic part is transparent or translucent.

14. The method according to claim 1 , further comprising a step of thermally curing the selectively plated three-dimensional thermoplastic part at a temperature of between about 150 and about 220° C.

15. The method according to claim 1 , further comprising a step of applying one or more additional metal plating layers.

16. The method according to claim 15 , wherein the metal layer comprises a layer of copper, a layer of nickel or nickel alloy plated on the layer of copper, and a layer of chromium plated on the layer of nickel or nickel alloy.

17. The method according to claim 1 , wherein prior to thermoforming, the thermoplastic film is pre-dried.

18. The method according to claim 1 , wherein the thermoplastic film is selected from the group consisting of polycarbonates, polyesters, polyethylene terephthalate, and polyarylate.

19. The method according to claim 18 , wherein the thermoplastic film comprises polycarbonate.

20. The method according to claim 1 , wherein the thermoplastic film is a multilayer film.

Assignees

• Macdermid Enthone Inc

Inventors

• Bray Paul Andrew
• Herbert Martin Vaughan
• Parsons Keith Paul
• Warwick Peter Alan

Classifications

• B44F1/00

  Designs or pictures characterised by special or unusual light effects · CPC title

• B44C1/005

  by altering locally the surface material (surface treatment to obtain special artistic surface effects or finishes B44D5/00) · CPC title

• B29K2105/246

  Uncured, e.g. green · CPC title

• B29K2105/24

  crosslinked or vulcanised · CPC title

• B29K2069/00

  Use of PC, i.e. polycarbonates {or derivatives thereof}, as moulding material · CPC title