Unitary laundry detergent article

Patent metadata

Field	Value
Publication number	US-11015153-B2
Application number	US-201916253246-A
Country	US
Kind code	B2
Filing date	Jan 22, 2019
Priority date	Jan 26, 2018
Publication date	May 25, 2021
Grant date	May 25, 2021

Abstract

A water-soluble unitary laundry detergent article that contains two or more surfactant-containing non-fibrous sheets with a fabric hueing agent located between such non-fibrous sheets.

First claim

What is claimed is:

1. A unitary laundry detergent structure comprising two or more non-fibrous sheets and at least one fabric hueing agent present in a water-soluble fibrous structure disposed between said two or more non-fibrous sheets, wherein said unitary laundry detergent structure is water-soluble, wherein each of said two or more non-fibrous sheets comprises at least one film former and a first surfactant.

2. The unitary laundry detergent structure of claim 1 , wherein each of said two or more non-fibrous sheets has a thickness ranging from 0.1 mm to 10 mm, a length-to-thickness aspect ratio of at least 5:1, and a width-to-thickness aspect ratio of at least 5:1.

3. The unitary laundry detergent structure according to claim 1 , wherein said water-soluble fibrous structure comprises a plurality of fibrous elements that each comprises from 0.01% to 30%, of the fabric hueing agent by total dry weight of said each fibrous element.

4. The unitary laundry detergent structure of claim 3 , wherein the plurality of fibrous elements each comprise from 0.5% to 10% of the fabric hueing agent by total dry weight of said each fibrous element.

5. The unitary laundry detergent structure of claim 3 , wherein each of said fibrous element further comprises from 30% to 70% of a filament-forming material by total dry weight of said each fibrous element, and wherein said filament-forming material is selected from the group consisting of polyvinyl alcohols, starch, cellulosic polymers, polyethylene oxides, and combinations thereof.

6. The unitary laundry detergent structure according to claim 1 , wherein said at least one fabric hueing agent is selected from the group consisting of dyes, dye-clay conjugates, organic pigments, inorganic pigments, optical brighteners, and combinations thereof.

7. The unitary laundry detergent structure of claim 1 , wherein the at least one fabric hueing agent is a fabric hueing dye selected from the group consisting of direct dyes, basic dyes, reactive dyes, solvent dyes, disperse dyes, and combinations thereof.

8. The unitary laundry detergent structure according to claim 1 , wherein said fabric hueing agent has a chemical structure of:
(a)

wherein the index values x and y are independently selected from 1 to 10; or (b)

wherein: R 1 and R 2 are independently selected from the group consisting of:
H; alkyl; alkoxy; alkyleneoxy; alkyl capped alkyleneoxy; urea; and amido; R 3
is a substituted aryl group; X is a substituted group comprising sulfonamide moiety and optionally an alkyl and/or aryl moiety, and wherein the substituent group comprises at least one alkyleneoxy chain that comprises an average molar distribution of at least four alkyleneoxy moieties.

9. The unitary laundry detergent structure according to claim 1 , wherein said fabric hueing agent is an optical brightener selected from the group consisting of diaminostilbenes, distyrylbiphenyls, and combinations thereof.

10. The unitary laundry detergent structure of claim 9 , wherein said optical brightener is selected from the group consisting of: disodium 4,4′-bis {[4-anilino-6-morpholino-s-triazin-2-yl]-amino}-2,2′-stilbenedisulfonate; disodium 4,4′-bis[(4,6-di-anilino-s-triazin-2-yl)-amino]-2,2′-stilbenedisulfonate; disodium 4,4′-bis {[4-anilino-6-[bis(2-hydroxyethyl)amino-s-triazin-2-yl]-amino}-2,2′-stilbenedisulfonate; disodium 2,2′-([1,1′-biphenyl]-4,4′-diyldi-2,1-ethenediyl)bis-benzenesulfonate; and combinations thereof.

11. The unitary laundry detergent structure according to claim 1 , wherein each of said two or more non-fibrous sheets comprises: from 30% to 90%, of said first surfactant by total weight of said each non-fibrous sheet, and from 10% to 40% of said at least one film former by total weight of said each non-fibrous sheet, and wherein preferably the first surfactant is present as the main surfactant in each of said two or more non-fibrous sheets.

12. The unitary laundry detergent structure according to claim 1 , wherein said first surfactant in said two or more non-fibrous sheets is characterized by a Hydrophilic Index (HI) of no more than 7.5.

13. The unitary laundry detergent structure according to claim 1 , wherein said at least one film former in each of said two or more non-fibrous sheets is a water-soluble polymer selected from the group consisting of polyvinyl alcohols, polyalkylene glycols, starch or modified starch, cellulose or modified cellulose, polyacrylates, polymethacrylates, polyacrylamides, polyvinylpyrrolidones, and combinations thereof.

14. The unitary laundry detergent structure according to claim 1 , wherein said at least one film former in each of said two or more non-fibrous sheets is a polyvinyl alcohol characterized by a weight average molecular weight ranging from 15,000 to 120,000 Daltons; and a degree of hydrolysis ranging from 70% to 92%.

Assignees

• Procter & Gamble

Inventors

• Tan Hongsing
• Sivik Mark Robert
• Denome Frank William
• Hou Na
• Mao Min

Classifications

• C11D17/06

  Powder; Flakes; Free-flowing mixtures; Sheets · CPC title

• C11D3/3753

  Polyvinylalcohol; Ethers or esters thereof · CPC title

• C11D3/3707

  Polyethers, e.g. polyalkyleneoxides · CPC title

• C11D3/40

  Dyes {; Pigments} · CPC title

• C11D1/22

  derived from aromatic compounds · CPC title