Supercritical water gasification with decoupled pressure and heat transfer modules

Patent metadata

Field	Value
Publication number	US-11015136-B2
Application number	US-201716078692-A
Country	US
Kind code	B2
Filing date	Mar 10, 2017
Priority date	Mar 11, 2016
Publication date	May 25, 2021
Grant date	May 25, 2021

Abstract

The present invention discloses a system and method for supercritical water gasification (SCWG) of biomass materials wherein the system includes a SCWG reactor and a plurality of heat exchangers located within a shared pressurized vessel, which decouples the function of containing high pressure from the high temperature function. The present invention allows the heat transfer function to be conducted independently from the pressure transfer function such that the system equipment can be designed and fabricated in manner that would support commercial scaled-up SCWG operations. By using heat exchangers coupled to the reactor in a series configuration, significant efficiencies are achieved by the present invention SCWG system over prior known SCWG systems.

First claim

What is claimed is:

1. An apparatus for supercritical water gasification, the apparatus comprising:
a pressure vessel having a wall separating an interior of the pressure vessel and an exterior of the pressure vessel;
a reactor positioned within the interior of the pressure vessel, wherein the reactor is configured for super-critical water gasification of mixed reactants to yield products;
an inlet routed through the wall of the pressure vessel to supply a buffer gas to the interior of the pressure vessel, but outside the reactor;
a supply pipe routed through the wall of the pressure vessel and extending to and entering the reactor for providing the mixed reactants to the reactor, from the exterior of the pressure vessel;
an output pipe routed from the reactor and through the wall of the pressure vessel for providing products of super-critical water gasification from the reactor to the exterior of the pressure vessel; and
one or more heat exchangers located within the interior of the pressure vessel and fluidly connected to the supply pipe and to the output pipe, the one or more heat exchangers arranged and configured for transferring heat to the mixed reactants in the supply pipe from the products in the output pipe, whereby the heat is recycled from the products and supplied to the mixed reactants en route to the reactor for super-critical water gasification processes,
the apparatus configured to allow high temperature control to be decoupled from high pressure containment control,
wherein the supply pipe, the output pipe and the one or more exchangers are configured to confine the mixed reactants and the products away from a space defined by the wall of the pressure vessel and a wall of the reactor so that only the buffer gas fills the space.

2. The apparatus of claim 1 , further comprising:
insulation positioned within the pressure vessel and outside the reactor, the insulation capable of maintaining an exterior of the pressure vessel at or near room temperature.

3. The apparatus of claim 1 , further comprising:
a reactant pump located along the supply pipe capable of increasing pressure of the reactants in the supply pipe from a pressure of 1 bar up to a pressure equal to or more than 220 bars.

4. The apparatus of claim 1 , wherein the buffer gas is a pressurized buffer gas.

5. The apparatus of claim 1 , further comprising:
an inlet routed through the wall of the pressure vessel to supply pressurized oxygen or air to the reactor inside the pressure vessel.

6. The apparatus of claim 1 , further comprising:
a plurality of reactors, heat exchangers or both reactors and heat exchangers positioned in parallel with one another.

7. The apparatus of claim 6 , wherein the heat exchangers are plate-type heat exchangers, shell-and-tube-type heat exchangers, or spiral-type heat exchangers, or combinations thereof.

8. The apparatus of claim 1 , wherein the reactor is a commercial-sized reactor capable of producing industrial amounts of H 2 and CO 2 gases.

9. The apparatus of claim 1 , the pressure vessel further comprising a moveable flange in the vessel wall that provides access to the pressure vessel interior.

10. An apparatus for supercritical water gasification, the apparatus comprising:
a pressure vessel having a wall separating an interior of the pressure vessel and an exterior of the pressure vessel;
a reactor positioned within the interior of the pressure vessel, wherein the reactor is configured for super-critical water gasification of mixed reactants to yield products;
an inlet routed through the wall of the pressure vessel to supply a buffer gas to the interior of the pressure vessel, but outside the reactor;
a supply pipe routed through the wall of the pressure vessel and extending to and entering the reactor for providing the mixed reactants to the reactor, from the exterior of the pressure vessel;
an output pipe routed from the reactor and through the wall of the pressure vessel for providing products of super-critical water gasification from the reactor to the exterior of the pressure vessel; and
one or more heat exchangers located within the interior of the pressure vessel, the one or more heat exchangers fluidly connected to the supply pipe and the output pipe and arranged and configured for transferring heat to the mixed reactants in the supply pipe from the products in the output pipe,
wherein the supply pipe, the output pipe and the one or more exchangers are configured to confine the mixed reactants and the products away from a space defined by the wall of the pressure vessel and a wall of the reactor so that only the buffer gas fills the space.

11. The apparatus of claim 10 , further comprising:
insulation positioned within the pressure vessel and outside the reactor, the insulation capable of maintaining an exterior of the pressure vessel at or near room temperature.

12. The apparatus of claim 10 , wherein the buffer gas is a pressurized buffer gas.

13. The apparatus of claim 10 , further comprising:
an inlet routed through the wall of the pressure vessel to supply pressurized oxygen or air to the reactor inside the pressure vessel.

14. The apparatus of claim 10 , the pressure vessel further comprising a moveable flange in the vessel wall that provides access to the pressure vessel interior.

Assignees

• Univ King Abdullah Sci & Tech

Inventors

• Dibble Robert
• Ng Kim Choon
• Sarathy Subram Maniam

Classifications

• Y02P20/54

  using solvents, e.g. supercritical solvents or ionic liquids · CPC title

• C10J2300/0979

  as supercritical steam · CPC title

• C10J3/86

  combined with waste-heat boilers · CPC title

• C10J3/78 Primary

  High-pressure apparatus · CPC title