Antifouling structure precursor, antifouling structure, and surface modification method

Patent metadata

Field	Value
Publication number	US-11015064-B2
Application number	US-202016747799-A
Country	US
Kind code	B2
Filing date	Jan 21, 2020
Priority date	Jul 15, 2016
Publication date	May 25, 2021
Grant date	May 25, 2021

Abstract

An antifouling structure precursor, comprising: a modification layer that contains a modifier having a perfluoropolyether chain; and an oxide layer that has a surface entirely covered with the modification layer, wherein the modification layer has an uneven film thickness and comprises a comparatively thick area and a comparatively thin area that is dispersed in the comparatively thick area, and a coverage rate of covering the oxide layer with the comparatively thick area is equal to or greater than 10%. An antifouling structure, comprising: an antifouling structure precursor; and a lubricant oil on a surface of the antifouling structure precursor.

First claim

The invention claimed is:

1. A surface modification method for modifying a surface of an oxide, the method comprising:
producing a surface modification composition; and
applying the surface modification composition onto a surface of an oxide layer,
wherein in producing the surface modification composition, a modifier having a perfluoropolyether chain is mixed with:
a first modification accelerator containing a phosphoric acid; and
a second modification accelerator containing an organic platinum catalyst.

2. The surface modification method according to claim 1 , wherein the surface modification composition is applied onto the surface of the oxide layer after an elapse of predetermined time from production of the surface modification composition.

3. The surface modification method according to claim 1 , wherein in producing the surface modification composition, the modifier having a perfluoropolyether chain is further mixed with water at the same time.

4. The surface modification method according to claim 1 , further comprising: adding water to the surface modification composition after producing the surface modification composition and before applying the surface modification composition onto the surface of the oxide layer.

5. The surface modification method according to claim 1 , wherein applying the surface modification composition onto the surface of the oxide layer comprises applying a silazane coating onto the surface of the oxide layer.

6. An antifouling structure precursor, comprising:
a modification layer that contains a modifier having a perfluoropolyether chain; and
an oxide layer that has a surface entirely covered with the modification layer,
wherein the modification layer is derived from a surface modification composition simultaneously including:
a modifier having a perfluoropolyether chain;
a first modification accelerator containing an inorganic acid; and
a second modification accelerator containing at least one selected from the group consisting of a metal, a metal salt or an organometallic compound,

the modification layer has an uneven film thickness and comprises a comparatively thick area and a comparatively thin area that is dispersed in the comparatively thick area,
a coverage rate of covering the oxide layer with the comparatively thick area is equal to or greater than 10%,
the comparatively thick area is an area having a cohesion of 3.11 nN or more, and
the cohesion is measured by vertically moving a scanner of an atomic force microscope (AFM) on a surface of the antifouling structure precursor to obtain a force curve and quantitatively evaluating cohesion acting between a probe and a specimen from the force curve.

7. The antifouling structure precursor according to claim 6 ,
wherein the comparatively thick area has the coverage rate within a range from 24.7% to 85.3%.

8. The antifouling structure precursor according to claim 6 comprising a lubricant oil on the surface of the antifouling structure precursor.

Assignees

• Nissan Motor

Inventors

• Akaishi Shinichi
• Tsukada Yoshiko
• Sugimoto Masanobu
• Sakurai Daijirou
• Noguchi Yuji
• Kobayashi Ryota

Classifications

• C09D5/16 Primary

  Antifouling paints; Underwater paints · CPC title

• B05D7/24

  for applying particular liquids or other fluent materials · CPC title

• B32B3/00

  Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form · CPC title

• B05D5/00

  Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures · CPC title

• C09D5/00 Primary

  Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title