Apparatus and method for forming and 3d printing double network hydrogels using temperature-controlled projection stereolithography
US-2024309196-A1 · Sep 19, 2024 · US
US11014299B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11014299-B2 |
| Application number | US-201716080819-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 30, 2017 |
| Priority date | Jul 1, 2016 |
| Publication date | May 25, 2021 |
| Grant date | May 25, 2021 |
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A method and an apparatus of forming a three-dimensional object, wherein the method includes providing a carrier and an optically transparent member having a build surface, said carrier and said build surface defining a build region therebetween; filling said build region with a polymerizable liquid, continuously or intermittently irradiating said build region with light through said optically transparent member to form a solid polymer from said polymerizable liquid, continuously or intermittently advancing (e.g., sequentially or concurrently with said irradiating step) said carrier away from said build surface to form said three-dimensional object from said solid polymer, said optically transparent member comprising a build plate for a three-dimensional printer comprising: an optically transparent first channel layer; an optically transparent, gas permeable second channel layer on the first channel layer; and a flexible, optically transparent, gas-permeable sheet having an upper and lower surface, the sheet upper surface comprising a build surface for forming a three-dimensional object, the sheet lower surface being positioned on the second channel layer.
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That which is claimed is: 1. A method of forming a three-dimensional object, comprising: providing a carrier and an optically transparent member having a build surface, said carrier and said build surface defining a build region therebetween; filling said build region with a polymerizable liquid, continuously or intermittently irradiating said build region with light through said optically transparent member to form a solid polymer from said polymerizable liquid, continuously or intermittently advancing said carrier away from said build surface to form said three-dimensional object from said solid polymer, wherein said optically transparent member comprises a build plate comprising: an optically transparent first channel layer; an optically transparent second channel layer on the first channel layer; and a flexible, optically transparent sheet having an upper and lower surface, the sheet upper surface comprising a build surface for forming a three-dimensional object, the sheet lower surface being positioned on the second channel layer. 2. The method of claim 1 , further comprising fluidly connecting the channels of the first channel layer to a reduced pressure source. 3. The method of claim 2 , further comprising increasing and/or decreasing a pressure in the channels of the first channel layer to thereby bias the build plate in a lateral direction upward for increasing pressure and downward for decreasing pressure. 4. The method of claim 3 , further comprising oscillating a pressure in the channels of the first channel layer to oscillate the build plate and thereby increase a flow of polymerizable liquid to the build surface. 5. The method of claim 1 , further comprising flowing a gas through at least one side of the second channel layer to thereby increase a polymerization inhibitor flow to the build surface. 6. The method of claim 5 , wherein flowing a gas comprises fluidly connecting the at least one side of the second channel layer to a gas source and fluidly connecting another at least one side of the second channel layer to a reduced pressure chamber to thereby increase a flow of the gas through the second channel layer. 7. The method of claim 5 , wherein the gas comprises oxygen, and said oxygen comprises an inhibitor of polymerization. 8. The method of claim 5 , wherein said filling, irradiating, and/or advancing steps are carried out while also concurrently continuously maintaining a dead zone of polymerizable liquid in contact with both said build surface, and said solid polymer, optionally through a gradient of polymerization zone, said gradient of polymerization zone comprising said polymerizable liquid in partially cured form. 9. The method of claim 8 , wherein the carrier with said polymerized region adhered thereto is unidirectionally advanced away from said build surface on said stationary build plate. 10. The method of claim 9 , said filling step further comprising vertically reciprocating said carrier with respect to said build surface, to enhance or speed the refilling of said build region with said polymerizable liquid. 11. The method of claim 1 , wherein the second channel layer is gas permeable. 12. The method of claim 1 , wherein the sheet is gas permeable. 13. The method of claim 1 , further comprising applying a reduced pressure and/or polymer inhibitor-enriched gas to the polymerizable liquid through the second channel layer and the optically transparent member to thereby reduce a gas content of the polymerizable liquid. 14. The method of claim 13 , wherein applying a reduced pressure and/or polymer inhibitor-enriched gas comprising supplying a polymerization inhibitor gas to the polymerizable liquid at a substantially constant pressure. 15. The method of claim 14 , wherein supplying a polymerization inhibitor gas to the polymerization liquid comprises supplying an oxygen-enriched gas at a pressure less than atmospheric pressure. 16. The method of claim 15 , wherein the pressure of the oxygen is substantial equal to a partial pressure of oxygen in air at atmospheric pressure. 17. The method of claim 13 , wherein the step of applying a reduced pressure and/or polymer inhibitor-enriched gas comprises intermittently applying a reduced pressure.
Materials specially adapted for additive manufacturing · CPC title
using multiple radiation means, e.g. micromirrors or multiple light-emitting diodes [LED] · CPC title
Using vibrations during moulding · CPC title
Degassing moulding material or draining off gas during moulding (venting means in moulds B29C33/10) · CPC title
characterised by the energy source therefor, e.g. by global irradiation combined with a mask · CPC title
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