Methods and apparatus for additively manufacturing structures using in situ formed additive manufacturing materials

Patent metadata

Field	Value
Publication number	US-11014265-B2
Application number	US-201815909505-A
Country	US
Kind code	B2
Filing date	Mar 1, 2018
Priority date	Mar 20, 2017
Publication date	May 25, 2021
Grant date	May 25, 2021

Abstract

A method of additively manufacturing a structure comprises nuclear reactor comprises disposing a feed material on a surface of a substrate in a reaction vessel, disposing at least one material formulated and configured to react with the feed material in the reaction vessel, and exposing the feed material and the at least one material to energy from an energy source to react the feed material and the at least one material to form an additive manufacturing material and reaction by-products. The additive manufacturing material is separated from the reaction by-products and exposed to energy from the energy source to form inter-granular bonds between particles of the additive manufacturing material and form a layer of a structure comprising the additive manufacturing material. Related apparatuses and methods are disclosed.

First claim

What is claimed is:

1. A method of additively manufacturing a structure, the method comprising:
disposing a feed material comprising uranium tetrafluoride on a surface of a substrate in a reaction vessel;
disposing a silicon-containing compound formulated and configured to react with the uranium tetrafluoride in the reaction vessel;
exposing the uranium tetrafluoride and the silicon-containing compound to energy from an energy source to react the uranium tetrafluoride and the silicon-containing compound to form an additive manufacturing material comprising uranium silicide and reaction by-products;
separating the uranium silicide from the reaction by-products; and
exposing the uranium silicide to energy from the energy source to form inter-granular bonds between particles of the uranium silicide and form a layer of a structure comprising the uranium silicide.

2. A method of additively manufacturing a uranium-containing nuclear fuel material from a uranium material, the method comprising:
disposing at least one uranium-containing material selected from the group consisting of uranium tetrafluoride, uranium hexafluoride, depleted uranium, uranium dioxide, and uranium oxide (U 3 O 8 ) in a reaction vessel to form a first layer of the at least one uranium-containing material in the reaction vessel;
disposing at least one reactant material selected from the group consisting of an alkali metal, silicon, a silicon-containing compound, carbon monoxide, water, a lanthanide, an actinide, or a semimetal proximate the at least one uranium-containing material;
exposing the at least one uranium-containing material and the at least one reactant material to energy from an energy source to form uranium metal, uranium silicide, or uranium oxide;
exposing the uranium metal, uranium silicide, or uranium oxide to energy from the energy source to form a first layer of a structure;
disposing the at least one uranium-containing material on the first layer of the structure;
disposing the at least one reactant material proximate the at least one uranium-containing material on the first layer to form a second layer of the at least one uranium-containing material and the at least one reactant material;
exposing the second layer of the at least one uranium-containing material and the at least one reactant material to energy from the energy source to form uranium metal, uranium silicide, or uranium oxide; and
exposing the uranium metal, uranium silicide, or uranium oxide to energy from the energy source to form a second layer of the structure over the first layer of the structure and form inter-granular bonds between the first layer and the second layer of the structure,
wherein exposing the uranium metal, uranium silicide, or uranium oxide to energy from the energy source to form the first layer of the structure comprises providing a greater power from the energy source than a power provided to expose the second layer of the at least one uranium-containing material and the at least one reactant material to energy.

3. The method of claim 2 , further comprising:
selecting the at least one uranium-containing material to comprise uranium tetrafluoride or uranium hexafluoride; and
selecting the at least one reactant material to comprise an alkali metal.

4. The method of claim 2 , further comprising:
selecting the at least one uranium-containing material to comprise uranium tetrafluoride or uranium hexafluoride; and
selecting the at least one reactant material to comprise a silicon boride, a silicon lanthanide, or a silicon-cerium material.

5. The method of claim 2 , further comprising:
selecting the at least one uranium-containing material to comprise uranium tetrafluoride or uranium hexafluoride; and
selecting the at least one reactant material to comprise water.

6. The method of claim 2 , further comprising:
selecting the at least one uranium-containing material to comprise uranium oxide or uranium dioxide; and
selecting the at least one reactant material to comprise carbon monoxide.

7. The method of claim 2 , further comprising:
selecting the at least one uranium-containing material to comprise uranium tetrafluoride or uranium hexafluoride; and
selecting the at least one reactant material to comprise at least one of a lanthanide, a semimetal, and an actinide.

8. A method of additively manufacturing a structure with an in situ formed additive manufacturing material, the method comprising:
providing carbon monoxide and a feed material comprising at least one of uranium oxide or uranium dioxide in a reaction vessel;
exposing the carbon monoxide and the at least one of uranium oxide or uranium dioxide to energy from an energy source to form an additive manufacturing material comprising uranium metal to be used in an additive manufacturing process;
providing a layer of the uranium metal and at least one reactant material on a substrate; and
exposing the layer of the uranium metal and the at least one reactant material to energy from the energy source to form a layer of a structure.

9. The method of claim 8 , further comprising exposing the uranium metal and one of silicon, molybdenum, aluminum, or a carbon-containing material to energy from the energy source to form uranium silicide, uranium-molybdenum, uranium-aluminum, or uranium carbide.

10. A method of additively manufacturing a structure, the method comprising:
disposing a feed material comprising uranium oxide on a surface of a substrate in a reaction vessel;
introducing carbon monoxide to the reaction vessel;
exposing the uranium oxide and the carbon monoxide to energy from an energy source to react the uranium oxide and the carbon monoxide to form uranium metal and carbon dioxide;
separating the uranium metal from the carbon dioxide; and
exposing the uranium metal to energy from the energy source to form inter-granular bonds between particles of the uranium metal and form a layer of a structure comprising the uranium metal.

11. A method of additively manufacturing a structure, the method comprising:
disposing a spent nuclear fuel on a surface of a substrate in a reaction vessel;
disposing at least one material formulated and configured to react with the spent nuclear fuel in the reaction vessel;
exposing the spent nuclear fuel and the at least one material to energy from an energy source to react the spent nuclear fuel and the at least one material to form an additive manufacturing material and reaction by-products;
separating the additive manufacturing material from the reaction by-products; and
exposing the additive manufacturing material to energy from the energy source to form inter-granular bonds between particles of the additive manufacturing material and form a layer of a structure comprising the additive manufacturing material.

12. A method of additively manufacturing a uranium-containing nuclear fuel material from a uranium material, the method comprising:
disposing at least one uranium-containing material selected from the group consisting of uranium tetrafluoride and uranium hexafluoride in a reaction vessel to form a first layer of the at least one uranium-containing material in the reaction vessel;
disposing at least one reactant material selected from the group consisting of a silicon boride, a silicon lanthanide, and a silicon-cerium material proximate at least one uranium-containing material;
exposing the at least one uranium-containing material and the at least one reactant material to energy from an energy source to form uranium silicide; and
exposing uranium silicide to energy from the energy source to form a first layer of a structure.

13. A method of additi

Assignees

• Battelle Energy Alliance Llc

Inventors

• Van Rooyen Isabella J
• Parga Clemente J

Classifications

• B22F12/45

  Two or more · CPC title

• B22F10/66

  by mechanical means · CPC title

• B22F10/64

  by thermal means (control of energy beam parameters for post heating B22F10/364) · CPC title

• B22F10/25

  Direct deposition of metal particles, e.g. direct metal deposition [DMD] or laser engineered net shaping [LENS] · CPC title

• B33Y70/10

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title