Cluster supported catalyst and method for producing same

Patent metadata

Field	Value
Publication number	US-11014073-B2
Application number	US-201816018497-A
Country	US
Kind code	B2
Filing date	Jun 26, 2018
Priority date	Jun 27, 2017
Publication date	May 25, 2021
Grant date	May 25, 2021

Abstract

An improved cluster-supporting catalyst has heteroatom-removed zeolite particles, and catalyst metal clusters supported within the pores of the heteroatom-removed zeolite particles. A method for producing a cluster-supporting catalyst includes the following steps: providing a dispersion liquid containing a dispersion medium and the heteroatom-removed zeolite particles dispersed in the dispersion medium; and in the dispersion liquid, forming catalyst metal clusters having a positive charge, and supporting the catalyst metal clusters within the pores of the heteroatom-removed zeolite particles through an electrostatic interaction.

First claim

The invention claimed is:

1. A cluster-supporting catalyst, comprising heteroatom-removed zeolite particles, and catalyst metal clusters supported within the pores of the heteroatom-removed zeolite particles, wherein the catalyst metal clusters have a positive charge, and are supported on acid sites within the pores of the heteroatom-removed zeolite particles through an electrostatic interaction.

2. The cluster-supporting catalyst according to claim 1 , wherein the heteroatom-removed zeolite particles are aluminum-removed zeolite particles.

3. The cluster-supporting catalyst according to claim 1 , wherein the catalyst metal clusters are selected from the group consisting of clusters of platinum, palladium, rhodium, iridium, ruthenium, silver, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, molybdenum, tungsten, rhenium, silicon and germanium, and a combinations thereof.

4. The cluster-supporting catalyst according to claim 3 , wherein the catalyst metal clusters are selected from the group consisting of clusters of copper and iron, and a combinations thereof.

5. An exhaust gas purification method, wherein an exhaust gas is purified by the cluster-supporting catalyst according to claim 1 .

6. A liquid-phase synthesis reaction method, gas-phase synthesis reaction method, fuel cell reaction method, or air cell reaction method, wherein a liquid-phase synthesis reaction, gas-phase synthesis reaction, fuel cell reaction, or air cell reaction is catalyzed by the cluster-supporting catalyst according to claim 1 .

7. A catalyst device, comprising the cluster-supporting catalyst according to claim 1 , and a substrate supporting the catalyst.

8. A method for producing the cluster-supporting catalyst according to claim 1 ,
wherein the cluster-supporting catalyst comprises heteroatom-removed zeolite particles, and catalyst metal clusters supported within the pores of the heteroatom-removed zeolite particles; and
wherein the method comprises the followings steps:
providing a dispersion liquid containing a dispersion medium and the heteroatom-removed zeolite particles dispersed in the dispersion medium, and
forming, in the dispersion liquid, catalyst metal clusters having a positive charge, and supporting the catalyst metal clusters within the pores of the heteroatom-removed zeolite particles through an electrostatic interaction.

9. The method according to claim 8 , wherein the dispersion liquid is provided by pulverizing the heteroatom-removed zeolite particles, and dispersing the pulverized heteroatom-removed zeolite particles in the dispersion medium.

10. The method according to claim 8 , wherein the clusters are formed in the dispersion liquid by any of the following methods:
a method of laser ablation in liquid,
a method of microwave ablation in liquid,
a method of plasma ablation in liquid,
a positive-negative inversion method, and
a method of reduction in liquid.

11. The method according to claim 10 , wherein metal ions constituting the catalyst metal clusters are reduced by a reducing agent through the method of reduction in liquid to form the cluster in the dispersion liquid, and the dispersion liquid is irradiated with plasma and/or microwave to promote the reduction by the reducing agent.

12. The method according to claim 8 , wherein the dispersion medium of the dispersion liquid is an organic solvent.

13. The cluster-supporting catalyst according to claim 1 , wherein the catalyst metal clusters comprise 4 or more metal atoms.

14. The cluster-supporting catalyst according to claim 1 , wherein the catalyst metal clusters have a particle diameter of 1 nm or less.

Assignees

• Toyota Motor Co Ltd
• Genesis Res Institute Inc

Inventors

• Egashira Kazuhiro
• Takeda Yoshihiro
• Toyama Namiki
• Tanaka Toshiaki
• Ito Seitoku
• Ichihashi Masahiko

Classifications

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/393

  Metal or metal oxide crystallite size · CPC title

• B01J23/44

  Palladium · CPC title

• B01J2523/42

  Germanium · CPC title